Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.     

Molybdenum in icelandic geothermal waters

Molybdenum concentrations in Icelandic geothermal waters lie in the range 1–70 ppb. Warm waters and dilute high-temperature waters which contain high concentrations of sulphide are lowest in molybdenum. No correlation is otherwise observed between molybdenum concentrations and temperature. Surface waters and cold ground waters do not contain detectable molybdenum (<1 ppb). It seems likely that leaching rate is the prime factor in limiting molybdenum levels in these waters. Within individual geothermal fields molybdenum concentrations are either approximately constant or they vary regularly across the field. This regular variation may often be correlated with variations in other solute concentrations and subsurface temperatures and is taken to indicate a control of molybdenum mobility by a temperature dependent equilibrium. The evidence suggests that the solubility of molybdenite is responsible. Molybdenite has not been found in active geothermal systems in Iceland but is known to occur in some New Zealand geothermal systems and it has been identified in hydrothermally altered Tertiary basalt formations at Reydarártindur in southeast Iceland. Boiling and mixing with cold water leads to molybdenite undersaturation and thus these processes favour leaching of molybdenum from the rock. On the other hand, conductive cooling leads to supersaturation which favours removal of molybdenum from solution.     

Germanium in Icelandic geothermal systems

Germanium concentrations in geothermal waters in Iceland lie mostly in the range 2–30 ppb. There is an overall positive relation between the germanium content of the water and its temperature. Most of the germanium occurs as Ge(OH)^?₅in solution but Ge(OH)₄ may also be present in significant amounts in saline waters when above 200°C. Evidence indicates that aqueous germanium concentrations are controlled by exchange reactions where it substitutes for silica in silicates and iron in sulphides. It is the rate of dissolution and the relative abundance of the alteration minerals which take up germanium to a variable extent that ultimately fix Ge(OH)₄ concentrations in the water. This, together with water pH, fixes total dissolved germanium. It is mostly the primary rock composition that dictates the relative abundance of the alteration minerals. Conductive cooling in upflow zones favours removal of germanium from solution. During the initial stages of boiling of rising hot water dissolution is enhanced but precipitation at later stages.Thermodynamic data of various aqueous germanium species and several minerals are summarized and dissociation constants and solubilities estimated at elevated temperatures using available predictive methods.     

Description and interpretation of the composition of fluid and alteration mineralogy in the geothermal system,at Svartsengi,Iceland

The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm³ is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO₂, 10 gm H₂S and 4 gm Na₂O and a release of 57 gm SiO₂, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K₂O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous.     

A detailed study of the duality relation for the least squares adjustment in euclidean spaces

The Euclidean spaces with their inner products are used to describe methods of least squares adjustment as orthogonal projections on finite-dimensional subspaces. A unified Euclidean space approach to the least squares adjustment methods “observation equations” and “condition equations” is suggested. Hence not only the two adjustment solutions are treated from the view-point of Euclidean space theory in a unified frame but also the existing duality relation between the methods of “observation equations” and “condition equations” is discussed in full detail. Another purpose of this paper is to contribute to the development of some familiarity with Euclidean and Hilbert space concepts. We are convinced that Euclidean and Hilbert space techniques in least squares adjustment are elegant and powerful geodetic methods.     

The chemistry of geothermal waters in Iceland. III. Chemical geothermometry in geothermal investigations

New data from geothermal wells in Iceland have permitted empirical calibration of the chalcedony and $\text{Na}\text{K}$ geothermometers in the range of 25–180°C and 25–250°C respectively. The temperature functions are:

$\text{t°C=}\text{1112}\text{4.91?}\text{log SiO}{}_2\text{?273.15}$

$\text{t°C=}\text{933}\text{0.993+}\text{log Na/K}\text{?273.15}$

Concentrations are expressed in ppm. These temperature functions correspond well with the chalcedony solubility data of Fournier (1973) and the thermodynamic data for low-albite/microcline/solution equilibria of Heloeson (1969).A new CO₂ geothermometer is proposed which is considered to be useful in estimating underground temperatures in fumarolic geothermal fields. Its application involves analysis of CO₂ concentrations in the fumarole steam. The temperature function which applies in the range 180?300°C is: logCO₂ = 37.43 + 73192/T- 11829· 10₃/T² + 0.18923T- 86.187·logT where T is in °K and CO₂ in moles per kg of steam.     

Oceanographic Change and Terrestrial Human Impacts in a Post A.D. 1400 Sediment Record from the Southwest Iceland Shelf

Environmental proxies of soil erosion on Iceland, and oceanographic conditions on the adjacent shelf, were measured on a 50 cm box core taken from the southwest Iceland shelf in 1993 during cruise 93030 of the Canadian ship, CSS Hudson. These data, covering the last several centuries, are compared with the documentary record of sea-ice changes around Iceland since A.D. 1600. The site is under the influence of the Irminger Current, which carries warm, saline, Atlantic water northward along the shelf. Because of the relative warmth of this current, sea ice rarely occurs off southwest Iceland, even during the most severe sea-ice intervals of the historical record. In severe sea-ice years, however, the ice drifts clockwise around Iceland from the northeast and east and, in rare cases, reaches the southern coasts (Ogilvie, 1992). The chronology of the core was established by converting the basal radiocarbon date to calendar years and assuming a linear sedimentation rate from the base of the core to the year of collection, 1993. Organic carbon, stable C and O isotope ratios, planktonic foraminiferal assemblages, and sediment magnetic parameters were measured on samples from the core, plotted against calendar years and compared to the Icelandic sea-ice index. The environmental proxies suggest that increased soil erosion, reduced salinity, and, possibly, decreased marine productivity prevailed during the severe sea-ice interval lasting from the last quarter of the eighteenth century to around 1920. Such a situation could develop with climatic cooling, increased storminess, and loss of vegetation cover to stabilise the soil. Although the core site generally lies outside the sea-ice limits, the evidence clearly shows the influence of sea ice and fresh water, and is sensitive to the overall climatic deterioration manifested by the sea-ice record.     

Surface Soil Effects Study Using Short-period Microtremor Observations in Almería City, Southern Spain

—?In Almería city large earthquakes occurred and many buildings were completely destroyed in these historical earthquakes. The actual population of Almería city is about 200,000 people. This population is rapidly increasing and new urbanizing areas are growing to the eastern part of the city where they are located in softer soil conditions. Consequently, the evaluation of surface soil conditions is very important from a standpoint of earthquake disaster mitigation. We have obtained a landform classification map developed by analysing aerial photos, large-scale topographic maps and 80 borehole data. Eleven unit areas, which have different soil conditions, were inferred from this research. Also, S-wave velocity prospecting tests were carried out at several sites within the city. The shear-velocity values of the ground vary from 1689?m/s in hard rock to 298?m/s in soft soil. These results are useful for understanding the uppermost soil characteristics and are used for soil classification. Finally, short-period microtremor observations were densely carried out in the research area and NAKAMURA's method (1989) was applied for determining predominant periods. Microtremors were observed at about 173 sites with mainly 400?m interval in rock sites and 200?m interval in relatively soft soil sites. From the result of these microtremor measurements, the predominant period determined at rock site, in the western part of the city and historic area, is very short, about 0.1?s, and very stable. However at soft soil sites, in the center of the city, near Zapillo Beach and in the newly developed urban area, the predominant period is about 1.0?s and even larger in concordance with the geological conditions. Finally, at medium soil sites, in the eastern part of the city, the predominant period is about 0.4?s and it appears very stable in the whole region. The difference of predominant periods between hard rock and soft soil sites is very clear and it has been observed that the distribution of predominant periods depends heavily on the surface soil conditions.