Acidic compounds in biodegraded petroleum

Twelve oil samples have been characterised by titration, FT-IR and chromatographic analysis to determine the differences between the organic acid composition of biodegraded and non-biodegraded oils. The biodegraded oils have higher total acid and total base contents, both by titration and extraction. The molecular weight ranges of the extracted acids are lowest in the biodegraded oils, and the equivalent weight calculations indicate a dominance of multi-functional molecules. Gel permeation chromatography gives a molecular weight range with most of the molecules between 300 and 500 g/mol. FT-IR shows that the extracted acids from biodegraded oils are more carboxylic and aliphatic while the non-degraded oils are more phenolic. Molecular analysis of the derivatised extracts give UCM envelopes for biodegraded oils, and no molecular identification. The results indicate that the acidic constituents in biodegraded oils are a product of the biodegradation, as the composition is very different from the non-biodegraded oils.     

Early Holocene history of the Baltic Sea, as reflected in coastal sediments in Blekinge, southeastern Sweden

Integrated palaeoecological studies of two fiord sediment sequences in the province of Blekinge, SE Sweden, covering the time span 11,000–5000 cal BP, reveal the timing and the environment for the Ancylus Lake/Littorina Sea transition 9800–8500 cal BP. The first ingression of saline water into the Baltic Sea through the Danish Straits occurred earlier than formerly assumed. New evidence, particularly mineral magnetic and palaeobotanical analyses, demonstrate that on the general trend of the eustatically caused Littorina transgression several minor fluctuations of the water level can be identified between 8500 and 5000 cal years BP. A distinct regression phase around 8100 cal BP is correlated with the Greenland ice-core cold event dated to 8200 ice-core years BP. This is described as a regional climatic catastrophe for the Baltic Sea region. The coastal stratigraphy is compared with the offshore stratigraphy earlier studied. A tentative shore displacement curve for Early and Middle Holocene is presented.     

Thallium isotope composition of the upper continental crust and rivers—An investigation of the continental sources of dissolved marine thallium

The thallium (Tl) concentrations and isotope compositions of various river and estuarine waters, suspended riverine particulates and loess have been determined. These data are used to evaluate whether weathering reactions are associated with significant Tl isotope fractionation and to estimate the average Tl isotope composition of the upper continental crust as well as the mean Tl concentration and isotope composition of river water. Such parameters provide key constraints on the dissolved Tl fluxes to the oceans from rivers and mineral aerosols.The Tl isotope data for loess and suspended riverine detritus are relatively uniform with a mean of ε²⁰⁵Tl = −2.0 ± 0.3 (ε²⁰⁵Tl represents the deviation of the ²⁰⁵Tl/²⁰³Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 10⁴). For waters from four major and eight smaller rivers, the majority were found to have Tl concentrations between 1 and 7 ng/kg. Most have Tl isotope compositions very similar (within ±1.5 ε²⁰⁵Tl) to that deduced for the upper continental crust, which indicates that no significant Tl isotope fractionation occurs during weathering. Based on these results, it is estimated that rivers have a mean natural Tl concentration and isotope composition of 6 ± 4 ng/kg and ε²⁰⁵Tl = −2.5 ± 1.0, respectively.In the Amazon estuary, both additions and losses of Tl were observed, and these correlate with variations in Fe and Mn contents. The changes in Tl concentrations have much lower amplitudes, however, and are not associated with significant Tl isotope effects. In the Kalix estuary, the Tl concentrations and isotope compositions can be explained by two-component mixing between river water and a high-salinity end member that is enriched in Tl relative to seawater. These results indicate that Tl can display variable behavior in estuarine systems but large additions and losses of Tl were not observed in the present study.     

Fourier-transform Infrared Spectroscopy (FTIRS), a New Method to Infer Past Changes in Tree-line Position and TOC using Lake Sediment

This study tests the hypothesis that Fourier-transform infrared spectroscopy (FTIRS) of lake sediments can be used to infer past changes in tree-line position and total organic carbon (TOC) content of lake water. A training set of 100 lakes from northern Sweden spanning a broad altitudinal and TOC gradient from 0.7 to 14.9 mg/l was used to assess whether vegetation zones and TOC can be modelled from FTIR spectra of surface sediments (0–1 cm) using principal component analysis (PCA) and partial least squares (PLS) regression. Preliminary results show that FTIRS of lake sediments can be used to reconstruct past changes in tree line and the TOC content of lake water, which is hardly surprising since FTIRS registers the properties of organic and minerogenic material derived from the water mass and the drainage area. The FTIRS model for TOC gives a root mean squared error (RMSECV) of calibration of 1.4 mg/l (10% of the gradient) assessed by internal cross-validation (CV) yielding an R_cv² of 0.64. This should be compared with a near-infrared spectroscopy (NIRS) and diatom transfer function for TOC from the same set of lakes, which have a R_cv² of 0.61 and 0.31, and RMSECV of 1.6 and 2.3 mg/l, respectively. The FTIRS-TOC model was applied to a Holocene sediment core from a tree-line lake and the results show similar trends as inferences from NIRS and pollen from the same core. Overall, the results indicate that changes in FTIR spectra from lake sediments reflect differences in catchment vegetation and TOC, and that FTIRS-models based on surface-sediment samples can be applied to sediment cores for retrospective analysis.     

Performance of the In Situ Microcosm Technique for Measuring the Degradation of Organic Chemicals in Aquifers

An in situ microcosm (ISM) consists of a stainless steel cylinder isolating about 2 L of the aquifer and is equipped with valves allowing for loading and sampling from the ground surface. During the last five years, this technique has been used frequently to study the degradation of organic chemicals in polluted and pristine aquifers representing different redox environments. The ISM technique has great potential for providing field-relevant degradation potentials and rate constants, but care must be taken in using the equipment and interpreting the results. This paper provides details concerning the installation and operation of an ISM and presents experiences concerning data interpretation and monitoring of redox conditions.     

Gold in the volcanogenic mercury-rich sulfide deposit Långsele,Skellefte ore district,northern Sweden

The mineralogy of gold from a volcanogenic sulfide deposit in northern Sweden (Långsele) was studied. The enrichment of gold and silver in massive ore occurs associated with an intrusive metadolerite vein which can be traced across the ore. The emplacement of this vein mobilized the precious metals together with galena and Pb-Sb sulfosalts into fractures and low pressure zones. A high mercury content at L»ngsele (average 250 ppm) has influenced the gold mineralogy. Thus, gold occurs as Au-Ag amalgam, native gold and rarely as aurostibite (AuSb₂). The results of microprobe analyses of amalgam cluster around Au_0.45Ag_0.45Hg_0.10. The composition of ternary amalgam is discussed in connection with the synthetic Au-Ag-Hg system. Furthermore, native gold was found myrmekitically integrown with stibnite which has been interpreted as a breakdown product of aurostibite at low temperature.     

Upper lithospheric seismic velocity structure across the Pripyat Trough and the Ukrainian Shield along the EUROBRIDGE'97 profile

We present new results on the structure resulting from Palaeoproterozoic terrane accretion and later formation of one of the aulacogens in the East European Platform. Seismic data has been acquired along the 530-km-long, N–S-striking EUROBRIDGE'97 traverse across Sarmatia, a major crustal segment of the East European Craton. The profile extends across the Ukrainian Shield from the Devonian Pripyat Trough, across the Palaeoproterozoic Volyn Block and the Korosten Pluton, into the Archaean Podolian Block. Seismic waves from chemical explosions at 18 shot points at approximately 30-km intervals were recorded in two deployments by 120 mobile three-component seismographs at 3–4 km nominal station spacing. The data has been interpreted by use of two-dimensional tomographic travel time inversion and ray trace modelling. The high data quality allows modelling of the P- and S-wave velocity structure along the profile. There are pronounced differences in seismic velocity structure of the crust and uppermost mantle between the three main tectonic provinces traversed by the profile: (i) the Pripyat Trough is a ca. 4-km-deep sedimentary basin, fully located in the Osnitsk–Mikashevichi Igneous Belt in the northern part of the profile. The velocity structure is typical for a Precambrian craton, but is underlain by a ca. 5-km-thick lowest crustal layer of high velocity. The development of the Pripyat Trough appears to have only affected the upper crust without noticeable thinning of the whole crust; this may be explained by a rheologically strong lithosphere at the time of formation of the trough. (ii) Very high seismic velocity and Vp/Vs ratio characterise the Volyn Block and Korosten Pluton to a depth of 15 km and probably also the lowest crust. The values are consistent with an intrusive body of mafic composition in the upper crust that formed from bimodal melts derived from the mantle and the lower crust. (iii) The Podolian Block is close to a typical cratonic velocity structure, although it is characterised by relatively low seismic velocity and Vp/Vs ratio. A pronounced SW-dipping mantle reflector from Moho to at least 70 km depth may represent the Proterozoic suture between Sarmatia and Volgo–Uralia, the structure from terrane accretion, or a later shear zone in the upper mantle. The sub-Moho P-wave seismic velocity is high everywhere along the profile, with the exception of the area above the dipping reflector. This velocity change further supports a plate tectonic origin of the dipping mantle reflector. The profile demonstrates that structure from Palaeoproterozoic plate tectonic processes are still identifiable in the lithosphere, even where younger metamorphic equilibration of the crust has taken place.     

Sorption and anaerobic biodegradation of soluble aromatic compounds during groundwater transport. 2. Computer modeling

. The natural attenuation of a binary mixture of toluene and 1,2,4-trimethylbenzene, which was previously experimentally demonstrated in anaerobic column experiments, was simulated with the newly-developed PHREEQC model to reveal the biogeochemical processes involved. The processes considered in this model include advection, diffusion, sorption, redox reactions (e.g., oxidation of toluene and 1,2,4-trimethylbenzene coupled to the reduction of microbial ferric iron), precipitation of secondary minerals such as siderite and magnetite, and dissolution of hydrous ferric oxides, as well as other thermodynamic equilibrium reactions. The functions of advection and diffusion built into the PHREEQC were conventionally simulated. The sorption was kinetically simulated based on a bicontinuum model, whereas biodegradation was described using a multiple-term Monod model. The processes mentioned above were coupled with a geochemical equilibrium model. The consistency between the experimental and modeling results indicates that the processes defined and the controlling parameters chosen could describe the coupled interactions between transport and biogeochemical reactions for the studied system. The discrepancy between modeling and experimental observations, however, also revealed the limitation of the modeling approach. In general, the model approach, which incorporates simplified mathematical representations of the true physico-chemical dynamics of the sorption and biodegradation processes of toluene and 1,2,4-trimethylbenzene under anaerobic conditions is a very efficient and good predictive tool in management and remediation of contaminant groundwater aquifers.     

Snow research in Svalbard–an overview

This paper summarizes the most significant snow-related research that has been conducted in Svalbard. Most of the research has been performed during the 1990s and includes investigations of snow distribution, snow-melt, snow pack characteristics, remote sensing of snow and biological studies where snow conditions play an important role. For example, studies have shown regional trends with about 50% higher amounts of snow accumulation at the east coast of Spitsbergen compared to the west coast. Further, the accumulation rates are about twice as high in the south compared to the north. On average, the increase in accumulation with elevation is 97 mm water equivalents per 100 m increase in elevation. Several researchers reported melt rates, which are primarily driven by incoming short-wave radiation, in the range of 10-20 mm/day during spring. Maximum melt rates close to 70 mm/day have been measured. In addition to presenting an overview of research activities, we discuss new, unpublished results in areas where considerable progress is being made. These are i) modelling of snow distribution, ii) modelling of snowmelt runoff and iii) monitoring of snow coverage by satellite imagery. We also identify some weaknesses in current research activities. They are lacks of i) integration between various studies, ii) comparative studies with other Arctic regions, iii) applying local field studies in models that can be used to study larger areas of Svalbard and, finally, iv) using satellite remote sensing data for operational monitoring purposes.     

Holocene glacial history and sea-level changes on James Ross Island,Antarctic Peninsula

A reconstruction of deglaciation and associated sea-level changes on northern James Ross Island, Antarctic Peninsula, based on lithostratigraphical and geomorphological studies, shows that the initial deglaciation of presently ice-free areas occurred slightly before 7400 ¹⁴C yr BP. Sea-level in connection with the deglaciation was around 30 m a.s.l. A glacier readvance in Brandy Bay, of at least 7 km, with the initial 3 km over land, reached a position off the present coast at ca. 4600 yr BP. The culmination of the advance was of short duration, and by 4300 yr BP the coastal lowlands again were ice-free. A distinct marine level at 16–18 m a.s.l. was contemporaneous with or slightly post-dates the Brandy Bay advance, thus indicating the relative sea-level around 4600–4500 yr BP. Our results from James Ross Island confirm that over large areas in this part of Antarctica the last deglaciation occurred late. © 1997 John Wiley & Sons, Ltd.