Using 87Sr/86Sr, δ18O and δ2H isotopes along with major chemical composition to assess groundwater salinization in lower Shire valley,Malawi

Groundwater resources in some parts of the lower section of Shire River valley, Malawi, are not useable for rural domestic water supply due to high salinity. In this study, a combined assessment of isotopic (⁸⁷Sr/⁸⁶Sr, δ¹⁸O and δ²H) and major ion composition was conducted in order to identify the hydro-geochemical evolution of the groundwater and thereby the causes of salinity. Three major end-members (representing fresh- and saline groundwater, and evaporated recharge) were identified based on major ion and isotopic composition. The saline groundwater is inferred to result from dissolution of evaporitic salts (halite) and the fresh groundwater shows influence of silicate weathering. Conservative mixing models show that brackish groundwater samples result from a three component mixture comprising the identified end-members. Hence their salinity is interpreted to result from mixing of fresh groundwater with evaporated recharge and saline groundwater. On the other hand, the groundwater with low TDS, found at some distance from areas of high salinity, is influenced by mixing of evaporated recharge and fresh groundwater only. Close to the Shire marshes, where there is shallow groundwater, composition of stable isotopes of water indicates that evaporation may also be an important factor.     

Managing organizational change in an international scientific network: A study of ICES reform processes

Organizations involved in the governance of natural resources are challenged to adjust to the call for more holistic management approaches. This often necessitates organizational change. Here change processes in the International Council for the Exploration of the Sea (ICES) during the years 1998–2009 are investigated using semi-structured interviews combined with observations and review of documents. Several organizational reforms were implemented during the time period studied. The major drivers were the need to improve efficiency and a striving for better integration between different components within the organization. The reform processes were driven forward by individuals who navigated between opportunities and constrains embedded in the network structure of ICES. This required good leadership and communication skills. Broad consultations were important to ensure support within the ICES community. By increasing the understanding of the dynamics of change in organizations, which operate at the science–policy interface developments in desired directions can be facilitated.     

Pre-Cambrian atmosphere:evidence from the Pre-Cambrian of Sweden

Sedimentary haematite ores of central Sweden give evidence of the existence of an oxidizing atmosphere about 2000 × 10⁶ years ago. This is not consistent with Rankama's conclusions from the unoxidized condition of a diorite conglomerate in Finland. Therefore a (later) Pre-Cambrian conglomerate in northern Sweden has been examined for comparison. Where it is made up of dioritic material no proofs of oxidation can be found, but where the material is mainly iron-ore pebbles, magnetite ore is found to have been completely oxidized to haematite (martite) before being embedded as pebbles in the conglomerate.     

Using the pseudospectral technique on curved grids for 2D acoustic forward modelling1

The Fourier pseudospectral method has been widely accepted for seismic forward modelling because of its high accuracy compared to other numerical techniques. Conventionally, the modelling is performed on Cartesian grids. This means that curved interfaces are represented in a ‘staircase fashion‘causing spurious diffractions. It is the aim of this work to eliminate these non-physical diffractions by using curved grids that generally follow the interfaces. A further advantage of using curved grids is that the local grid density can be adjusted according to the velocity of the individual layers, i.e. the overall grid density is not restricted by the lowest velocity in the subsurface. This means that considerable savings in computer storage can be obtained and thus larger computational models can be handled. One of the major problems in using the curved grid approach has been the generation of a suitable grid that fits all the interfaces. However, as a new approach, we adopt techniques originally developed for computational fluid dynamics (CFD) applications. This allows us to put the curved grid technique into a general framework, enabling the grid to follow all interfaces. In principle, a separate grid is generated for each geological layer, patching the grid lines across the interfaces to obtain a globally continuous grid (the so-called multiblock strategy). The curved grid is taken to constitute a generalised curvilinear coordinate system, where each grid line corresponds to a constant value of one of the curvilinear coordinates. That means that the forward modelling equations have to be written in curvilinear coordinates, resulting in additional terms in the equations. However, the subsurface geometry is much simpler in the curvilinear space. The advantages of the curved grid technique are demonstrated for the 2D acoustic wave equation. This includes a verification of the method against an analytic reference solution for wedge diffraction and a comparison with the pseudospectral method on Cartesian grids. The results demonstrate that high accuracies are obtained with few grid points and without extra computational costs as compared with Cartesian methods.     

Land degradation,natural resources and local knowledge in the sahel zone of Burkina Faso

This paper proposes a conceptual model that integrates physical and ecological aspects with human aspects of land degradation through a multidisciplinary approach. The model was applied at the local level in a case study in northern Burkina Faso. Assessments of the degradation of the vegetation cover from aerial photographs and a satellite image were analysed in the framework of the model. Another input to the model was results from interviews and field visits with peasants living in the area.The local knowledge of the physical symptoms of land degradation and of the physical variables, eg rainfall and wind, is very close to the scientific logic. However, people do not generally see the links between these variables and the symptoms. Likewise, they do not perceive land degradation to be influenced in any way by human actions. Instead, the cause of land degradation is attributed to God, Allah. Thus, an important field of intervention for governments and development agencies should be to make people aware of their role in land management.     

Acidic compounds in biodegraded petroleum

Twelve oil samples have been characterised by titration, FT-IR and chromatographic analysis to determine the differences between the organic acid composition of biodegraded and non-biodegraded oils. The biodegraded oils have higher total acid and total base contents, both by titration and extraction. The molecular weight ranges of the extracted acids are lowest in the biodegraded oils, and the equivalent weight calculations indicate a dominance of multi-functional molecules. Gel permeation chromatography gives a molecular weight range with most of the molecules between 300 and 500 g/mol. FT-IR shows that the extracted acids from biodegraded oils are more carboxylic and aliphatic while the non-degraded oils are more phenolic. Molecular analysis of the derivatised extracts give UCM envelopes for biodegraded oils, and no molecular identification. The results indicate that the acidic constituents in biodegraded oils are a product of the biodegradation, as the composition is very different from the non-biodegraded oils.     

Early Holocene history of the Baltic Sea, as reflected in coastal sediments in Blekinge, southeastern Sweden

Integrated palaeoecological studies of two fiord sediment sequences in the province of Blekinge, SE Sweden, covering the time span 11,000–5000 cal BP, reveal the timing and the environment for the Ancylus Lake/Littorina Sea transition 9800–8500 cal BP. The first ingression of saline water into the Baltic Sea through the Danish Straits occurred earlier than formerly assumed. New evidence, particularly mineral magnetic and palaeobotanical analyses, demonstrate that on the general trend of the eustatically caused Littorina transgression several minor fluctuations of the water level can be identified between 8500 and 5000 cal years BP. A distinct regression phase around 8100 cal BP is correlated with the Greenland ice-core cold event dated to 8200 ice-core years BP. This is described as a regional climatic catastrophe for the Baltic Sea region. The coastal stratigraphy is compared with the offshore stratigraphy earlier studied. A tentative shore displacement curve for Early and Middle Holocene is presented.     

Thallium isotope composition of the upper continental crust and rivers—An investigation of the continental sources of dissolved marine thallium

The thallium (Tl) concentrations and isotope compositions of various river and estuarine waters, suspended riverine particulates and loess have been determined. These data are used to evaluate whether weathering reactions are associated with significant Tl isotope fractionation and to estimate the average Tl isotope composition of the upper continental crust as well as the mean Tl concentration and isotope composition of river water. Such parameters provide key constraints on the dissolved Tl fluxes to the oceans from rivers and mineral aerosols.The Tl isotope data for loess and suspended riverine detritus are relatively uniform with a mean of ε²⁰⁵Tl = −2.0 ± 0.3 (ε²⁰⁵Tl represents the deviation of the ²⁰⁵Tl/²⁰³Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 10⁴). For waters from four major and eight smaller rivers, the majority were found to have Tl concentrations between 1 and 7 ng/kg. Most have Tl isotope compositions very similar (within ±1.5 ε²⁰⁵Tl) to that deduced for the upper continental crust, which indicates that no significant Tl isotope fractionation occurs during weathering. Based on these results, it is estimated that rivers have a mean natural Tl concentration and isotope composition of 6 ± 4 ng/kg and ε²⁰⁵Tl = −2.5 ± 1.0, respectively.In the Amazon estuary, both additions and losses of Tl were observed, and these correlate with variations in Fe and Mn contents. The changes in Tl concentrations have much lower amplitudes, however, and are not associated with significant Tl isotope effects. In the Kalix estuary, the Tl concentrations and isotope compositions can be explained by two-component mixing between river water and a high-salinity end member that is enriched in Tl relative to seawater. These results indicate that Tl can display variable behavior in estuarine systems but large additions and losses of Tl were not observed in the present study.     

Fourier-transform Infrared Spectroscopy (FTIRS), a New Method to Infer Past Changes in Tree-line Position and TOC using Lake Sediment

This study tests the hypothesis that Fourier-transform infrared spectroscopy (FTIRS) of lake sediments can be used to infer past changes in tree-line position and total organic carbon (TOC) content of lake water. A training set of 100 lakes from northern Sweden spanning a broad altitudinal and TOC gradient from 0.7 to 14.9 mg/l was used to assess whether vegetation zones and TOC can be modelled from FTIR spectra of surface sediments (0–1 cm) using principal component analysis (PCA) and partial least squares (PLS) regression. Preliminary results show that FTIRS of lake sediments can be used to reconstruct past changes in tree line and the TOC content of lake water, which is hardly surprising since FTIRS registers the properties of organic and minerogenic material derived from the water mass and the drainage area. The FTIRS model for TOC gives a root mean squared error (RMSECV) of calibration of 1.4 mg/l (10% of the gradient) assessed by internal cross-validation (CV) yielding an R_cv² of 0.64. This should be compared with a near-infrared spectroscopy (NIRS) and diatom transfer function for TOC from the same set of lakes, which have a R_cv² of 0.61 and 0.31, and RMSECV of 1.6 and 2.3 mg/l, respectively. The FTIRS-TOC model was applied to a Holocene sediment core from a tree-line lake and the results show similar trends as inferences from NIRS and pollen from the same core. Overall, the results indicate that changes in FTIR spectra from lake sediments reflect differences in catchment vegetation and TOC, and that FTIRS-models based on surface-sediment samples can be applied to sediment cores for retrospective analysis.