Intrinsic biodegradation of toluene coupled to the microbial reduction of ferric iron: laboratory column experiments

Intrinsic biodegradation of toluene coupled with the microbial reduction of ferric iron (Fe(III)) as the terminal electron acceptor was studied by using laboratory column experiments under continuous flow conditions. Columns were packed with contaminated aquifer sediment and N₂-purged groundwater taken from the western part of the Gardermoen aquifer. The columns were operated anaerobically at 8 °C (in-situ temperature). Chloride was initially used to characterize flow properties of the columns. Intrinsic biodegradation of toluene, including abiotic loss and biological loss, was estimated by comparing breakthrough curves of toluene for live columns and sterilized control columns based on mass balance in steady-state conditions. The column experiments were run at two different flow velocities. The estimated average intrinsic rate was -0.73 and -0.53 mM day^-1 for pore-water velocities of 1.75 and 2.68 cm h^-1, respectively, corresponding to -0.27 and -0.22 mM day^-1 in biological loss rate. The results indicate that intrinsic biodegradation of toluene could be used as an efficient remediation approach for contaminated groundwater at the Gardermoen fire-fighting training site.     

Time dependence of organic matter decay and mixing processes in Framvaren, a permanently anoxic fjord in South Norway

Three different layers have been identified in Framvaren, which has a maximum water depth of 184 m. One oxic layer above the redoxcline at 18–20 m. One anoxic layer from 20 to 100 m which is occasionally ventilated by a flow over the sill (which has a depth of 2.5 m), and finally a stagnant layer below 100 m. Using the release rate of silica from the bottom and measurements of the concentration of HTO it is possible to make some calculations on the annual volume of interleaving in the layers 25–50 m, 50–75 m, and 75–100 m together with the advective flows. Reliable values of the sulfide concentration were obtained by precipitating and weighing HgS together with careful protection of all anoxic water samples with argon. The light yellow color of the precipitate in the depth range 25 to 80 m indicates that the occasional ventilation will cause such reactions as 0.50₂ + H₂S S(colloidal) + H₂O. The elemental sulfur, being stabilized with HS^–, is set free upon the precipitation of HgS. The new data for the concentration of sulfide give an acceptable stoichiometry for the decay reaction of organic matter. This is not the case with the data of Yao and Millero. The mean values for the concentrations of ammonium and phosphate agree with the new data of Yao and Millero. The mol/mol C/N ratio of 10.1 found in trapped material by Naess and coworkers (1988) agrees with the stoichiometry of the dissolved constituents, i.e. C/N = 9.92 ± 0.45. A denitrification reaction is suggested to explain the high values of C/N. The vertical diffusion coefficient at 100 m calculated from the depth profile of silica was 0.92 × 10^–6 m² s^–1 which lies in the range of values given by Fröyland. Finally, the ¹⁴C age of the total dissolved inorganic carbon (Ct) in the water below 90 m was about 1600 years indicating a bioproduction in the period 8000 years B.P. to A.D. 1853 when a channel was opened between the fjord outside (Helvikfjord) and Framvaren.     

Magnetic susceptibility in sediment records of Lake Ådran,eastern Sweden: correlation among cores and interpretation

Magnetic susceptibility was used to test the representativity of the lithostratigraphy of a master sediment sequence from Lake Ådran, eastern Sweden. Five further sediment cores from the same lake were correlated and compared with the master sequence using magnetic susceptibility records. Mineral magnetic correlations are generally based on matching prominent susceptibility features but may be significantly improved by using slot sequence analyses. The result of these analyses show that the sediment in the Lake Ådran master sequence can be considered representative for the basin. The variations in the magnetic susceptibility in relation to pollen and diatom analyses also seem to reflect water level changes and shore displacement in the Baltic between 9900 ¹⁴C years B.P. and the isolation at 5900 ¹⁴C years B.P. The first emergence of scattered non-vegetated islands is characterised by high susceptibility values. Along with a continuous water lowering and the development of the vegetation during the Ancylus fresh water stage, susceptibility values gradually decrease. A rapid phase of the Ancylus regression between 9200 and 9000 ¹⁴C years B.P. is seen as an increase in magnetic susceptibility. During the following Baltic brackish water stage, the Litorina stage, susceptibility values are at their lowest, followed by higher values at the isolation from the Baltic with a maximum around 5000 ¹⁴C years B.P.Shore displacement between 9900 and 5900 ¹⁴C years B.P. is discussed based on the magnetic susceptibility measurements and their relationship to the pollen and diatom analyses.     

The radio–optical correlation in steep-spectrum quasars

Using complete samples of steep-spectrum quasars, we present evidence for a correlation between radio and optical luminosity which is not caused by selection effects, nor caused by an orientation dependence (such as relativistic beaming), nor a by-product of cosmic evolution. We argue that this rules out models of jet formation in which there are no parameters in common with the production of the optical continuum. This is arguably the most direct evidence to date for a close link between accretion on to a black hole and the fuelling of relativistic jets. The correlation also provides a natural explanation for the presence of aligned optical/radio structures in only the most radio-luminous high-redshift galaxies.     

Estimation of sea surface topography in the Norwegian sea using gravimetry and Geosat altimetry

An analysis of the quasi-stationary sea surface topography (QSST) is carried out in the Norwegian Sea region (54°<ø<72°, -25°<<20°) using marine gravimetry and one year of Geosat ERM altimetry. As reference models the geopotential model OSU91A and the QSST model OSU89D were used. Two procedures to extract the QSST from mean sea surface heights and gravity anomalies were tested. Spherical FFT techniques were applied in both procedures. The results show that QSST associated with wavelength shorter than 4000 km exists. Relative to the OSU89D model the QSST was found to have a variance of (0.219 m)² and a correlation length of 1.105°. The circulation pattern recovered in this paper agree with results of oceanographic analysis.     

The stabilisation of wet sediment cores by means of a polyethylene glycol/freeze-drying treatment for display and permanent storage

A reversible method is presented to transform waterlogged sediment cores into dry and stable specimens which can go on exhibition or into permanent storage, needing no special precautions. Wet sediment core segments are bath-impregnated with polyethylene glycol of molecular weight 3,350 (PEG 3,350) dissolved in water. The samples are then subjected to a freeze-drying process, during which the PEG forms a stabilising and bonding porous network structure in the capillary system of the sediment. Standard sediment cores at least 1 m long become strong enough to stand upright. Sediment types ranging from muddy deep-sea sediments to very coarse littoral Halimeda sand were successfully stabilised. For standard cores of 10-cm diameters split length-wise, impregnation times vary from 2 weeks for coarse sand to 6–10 weeks for more compacted sediments. With regard to the stability of the samples and the visual clarity of detail, best results were obtained by impregnation with 25 to 60% solutions of PEG 3,350, coarse sediments needing more PEG than finer ones. Colour changes are systematic – the processed samples are lighter in appearance and the contrasts are enhanced, but there is no serious shift in colour tones. The PEG can easily be re-dissolved and washed out of the sediments. Display specimens can thus be made available for research again.     

Multi-satellite ocean tide modelling—the K1 constituent

All major ocean tide constituents are aliased into signals with periods less than 90 days from TOPEX/POSEIDON altimetry, except the K₁ constituent. The aliased K₁ has a period of 173 days. Consequently, it might be confounded with height variations caused by the semiannual cycle having a period of 183 days.The correlation between K₁ and the semiannual signal has been investigated both locally and globally using combinations of T/P, ERS-1 and GEOSAT observations. Subsequently, two empirical methods have been investigated to improve the mapping of K₁ from multiple satellites.At high latitudes, where the presence of crossing tracks cannot separate K₁ from the semiannual signal from TOPEX/POSEIDON, the importance of including ERS-1 and GEOSAT observations was demonstrated. A comparison with 29 pelagic and coastal tide gauges in the Southern Ocean south of 50°S gave 5.59 (M₂), 2.27 (S₂) and 5.04 (K₁) cm RMS agreement for FES95.1 ocean tide model. The same comparison for the best empirical estimated constituents based on TOPEX/POSEIDON + ERS-1 + GEOSAT gave 4.32, 2.21, and 4.29 cm for M₂, S₂ and K₁, respectively.