Sputtering in the outflows of cool stars

Radiation pressure acts to accelerate dust grains and, by transfer of momentum through collisions with the gas, drives the outflows of late-type stars. Some of these dust–gas collisions may be energetic enough to remove atoms from the dust grains. From an assumed initial size distribution for the dust grains, the method of Krüger et al. is used to study the evolution of a sample of spherical amorphous carbon grains under conditions typical of a late-type star. The size distribution of dust grains is presented for various sets of model parameters. One set of models assumes an initial Mathis, Rumpl & Nordsieck (MRN) distribution for the dust grains. The high-luminosity ( L ∗), high-effective temperature ( T _eff) set of parameters has a terminal velocity ( v _term) that is near, but above , the upper limit of observed outflow velocities for carbon stars (∼30 km s⁻¹ for the assumed ̇ of 5×10⁻⁶ M_⊙ yr⁻¹). The low L ∗, T _eff model has a v _term that lies near, but below , the upper limit of observed velocities. A significant amount of sputtering occurs in the high L ∗, T _eff model with ∼40 per cent of the grain mass sputtered. About ∼1 per cent of the dust mass is sputtered in the low L ∗, T _eff. Another set of models assumes that the dust forms with a log-normal distribution. Here, v _term is nearly the same for the high L ∗, T _eff model as for the low L ∗, T _eff model. This is a result of the large amount of dust mass loss (∼75 per cent) by sputtering in the high L ∗, T _eff model.     

A New Enantiornithes (Aves) from the Early Cretaceous of China

A new bird from the early Cretaceous Yixian Formation of Liaoning, China is described. This new species, Grabauornis lingyuanensis, shares several synapomorphies with the Enantiornithes. The specimen is relatively well preserved. The skeletal morphology of Grabauornis bears close resemblance to that of other Chinese members of this clade. The brachial index （the ratio between the lengths of humerus and ulna） is 0.95, which is close to the average for enantiornithine birds. It indicates that Grabauornis was a rather good flyer, and the presence of an alula in the wing further testifies to this.     

Rare Earth Element and yttrium compositions of Archean and Paleoproterozoic Fe formations revisited: New perspectives on the significance and mechanisms of deposition

The ocean and atmosphere were largely anoxic in the early Precambrian, resulting in an Fe cycle that was dramatically different than today’s. Extremely Fe-rich sedimentary deposits—i.e., Fe formations—are the most conspicuous manifestation of this distinct Fe cycle. Rare Earth Element (REE) systematics have long been used as a tool to understand the origin of Fe formations and the corresponding chemistry of the ancient ocean. However, many earlier REE studies of Fe formations have drawn ambiguous conclusions, partially due to analytical limitations and sampling from severely altered units. Here, we present new chemical analyses of Fe formation samples from 18 units, ranging in age from ca. 3.0 to 1.8 billion years old (Ga), which allow a reevaluation of the depositional mechanisms and significance of Precambrian Fe formations. There are several temporal trends in our REE and Y dataset that reflect shifts in marine redox conditions. In general, Archean Fe formations do not display significant shale-normalized negative Ce anomalies, and only Fe formations younger than 1.9 Ga display prominent positive Ce anomalies. Low Y/Ho ratios and high shale-normalized light to heavy REE (LREE/HREE) ratios are also present in ca. 1.9 Ga and younger Fe formations but are essentially absent in their Archean counterparts. These marked differences in Paleoproterozoic versus Archean REE + Y patterns can be explained in terms of varying REE cycling in the water column.Similar to modern redox-stratified basins, the REE + Y patterns in late Paleoproterozoic Fe formations record evidence of a shuttle of metal and Ce oxides across the redoxcline from oxic shallow seawater to deeper anoxic waters. Oxide dissolution—mainly of Mn oxides—in an anoxic water column lowers the dissolved Y/Ho ratio, raises the light to heavy REE ratio, and increases the concentration of Ce relative to the neighboring REE (La and Pr). Fe oxides precipitating at or near the chemocline will capture these REE anomalies and thus evidence for this oxide shuttle. In contrast, Archean Fe formations do not display REE + Y patterns indicative of an oxide shuttle, which implies an absence of a distinct Mn redoxcline prior to the rise of atmospheric oxygen in the early Paleoproterozoic. As further evidence for reducing conditions in shallow-water environments of the Archean ocean, REE data for carbonates deposited on shallow-water Archean carbonate platforms that stratigraphically underlie Fe formations also lack negative Ce anomalies. These results question classical models for deposition of Archean Fe formations that invoke oxidation by free oxygen at or above a redoxcline. In contrast, we add to growing evidence that metabolic Fe oxidation is a more likely oxidative mechanism for these Fe formations, implying that the Fe distribution in Archean oceans could have been controlled by microbial Fe uptake rather than the oxidative potential of shallow-marine environments.     

Gridded Croatian climatology for 1961–1990

In climatology, one of the most important pieces of information about the climate of a place or a region is information about the Climatological Normals (CLINO)—the average values of meteorological elements for a 30-year period. This kind of information usually comes in tables and is available for different observation sites from national meteorological services or from World Meteorological Organisation publications. The key issue, then, becomes how to interpolate these values over the entire area of interest to get reliable and accurate estimates (maps) of climatic elements. Here, the regression kriging framework has been applied for mapping of 20 climatological parameters for the 1961–1990 period for the 56,594 km² of Croatian territory, with a resolution of 1 km. In total, 152 main and climatological and 567 precipitation-measuring stations have been used in the analysis. Extensive pre-processing of metadata on station co-ordinates has been done, as well as completion of missing monthly averages. The final results are 20 climatological maps available in high resolution together with error maps and accuracy assessment measures.     

Predicting Soil-Water and Soil-Air Transport Properties and Their Effects on Soil-Vapor Extraction Efficiency

Accurate prediction of water and air Iran sport parameters in variably saturated soil is necessary for modeling of soil-vapor extraction (SVE) at soil sites contaminated with volatile organic chemicals (VOCs). An expression for predicting saturated water permeability (k_l,s) in undisturbed soils from the soil total porosity and the field capacity soil-water content was developed by fitting a tortuous-tube fluid flow model to measured water permeability and gas diffusivity data. The new k_l,s expression gave accurate predictions when tested against independent k_l,s data. The k_l,s expression was implemented in the Campbell relative water permeability model to yield a predictive model for water permeability in variably saturated, undisturbed soil. The water permeability model, together with recently developed predictive equations for gas permeability and gas diffusivity, was used in a two-dimensional numerical SVE model that also included non-equilibrium mass transfer of VOC from a separate phase (nonaqueous phase liquid [NAPL]) to the air phase. SVE: calculations showed that gas permeability is likely the most important factor controlling VOC migration and vapor extraction efficiency. Water permeability and gas diffusivity effects became significant at water contents near and above field capacity. The NAPL-air mass transfer coefficient also had large impacts on simulated vapor extraction efficiency. The calculations suggest that realistic SVE models need to include predictive expressions for both conveciive, diffusive. and phase-partitioning processes in natural, undisturbed soils.     

Sediment-chemistry response to land-use change and pollutant loading in a hypertrophic lake, southern Sweden

Responses to recent land-use changes and pollutant loading in the sediment of a hypertrophic lake in southern Sweden were studied by comparison of geochemical, pollen and magnetic records with historical land-use data. A chronology was constructed for the last two centuries by correlating changes in the pollen diagram to major events in the land-use history. Sediment accumulation was low (mean c. 0.2 g cm^-2 yr^-1) prior to 1800 AD, when less than 25% of the catchment was arable land. Reorganization of the agrarian system during the 19th century increased the annually tilled area by 300%, which accelerated soil erosion and substantially increased the accumulation of allochtonous matter in the lake. Since the turn of the century 90% of the catchment has been ploughed every year. The deposition of clastic matter in the lake has, however, decreased due to a gradual rerouting of the drainage system, which has reduced the effective catchment area by c. 85%.Authigenic vivianite (Fe3(PO4)2.8H2O) is a major P phase in the preindustrial non-sulphidic sediments, which suggests that the sediments at that time served as a fairly efficient sink for P. The arable expansion, increased manuring and, eventually, the introduction of artificial fertilizers during the 19th century led to a massive influx of nutrients, which elevated primary production in the lake. Subsequent development of bottom water anoxia around 1900, in combination with an additional pollutant burden of sulphate within the lake basin, led to major alterations of the biogeochemical cycles. The most critical change in the post-1900 sediments involved the cycling of Fe and P. The linkage between the lacustrine P and Fe cycles can explain that FeS formation was paralleled by a release of P from the sedimentary pool. This supply of P to the lake basin must have supplemented the nutrient supply by modern agriculture and contributed to recent hypertrophication. The bacterial sulphate reduction also affected the generation of alkalinity which supported a significant calcite precipitation in the post-1900 sediments.S is enriched 10-fold in the post-1900 sediments compared to preindustrial values. Along with the rise in S, soot particles derived from fossil fuel combustion appear in the sediments for the first time. Therefore, Bussj¨osj¨on is thought to be a good example of how a well-buffered, highly productive lake may respond to the pollution by sulphur from acid rain.     

Late Holocene tephrochronology of the northern Antarctic Peninsula

Andesitic and basaltic andesitic tephra layers are abundant in Holocene deposits from the Antarctic Peninsula. Visually discernible tephra horizons occur in three lakes on Livingston Island. Tephra in two other lakes and in a moss bank on Elephant Island, with very low ash concentrations, were detected magnetically. Deception Island is the most likely volcanic source for the tephra. With direct ¹⁴C dating, age/depth curves, and cross-correlations at least 14 tephra horizons dating to between ca. 4700 and 250 yr B.P. were identified and now form the basis for a preliminary regional tephrochronology that will be a valuable dating tool for investigating the Holocene climatic history of Antarctica.     

Mineral magnetic characteristics of podzolic soils developed on sand dunes in the Lake Gosciaz catchment, central Poland

A number of samples from the A₀, A₂, B and C horizons have been collected from podzolic soils in the Lake Gosciaz catchment in central Poland. The catchment is very uniform consisting of 2–6-m-high sand dunes with sparse stands of pine and a grass undervegetation. Radiocarbon dates of fossil soils covered by dune sand, within the same type of environment as the Lake Gosciaz catchment, indicate that the main dune-forming phase is of Older Dryas age. Magnetic measurements have been carried out on bulk samples and on particle size fractions from the different soil horizons. With respect to our mineral magnetic study it can be concluded that the soils are very uniform over the entire catchment. Relatively high concentrations of magnetic grains are found in the humus layer, particularly in the <4 μm size fraction, as indicated by the highest X, X_fd, SIRM and HIRM values. The most likely mechanism for the magnetic enhancement in these podzolic top soils is continued burning processes. Low magnetic concentrations in the A₂ horizon are due to eluviation and chelation. Local conditions can lead to a range of magnetic minerals precipitating in the B horizon.