A magnetostratigraphic comparison between 14C years and varve years during the Late Weichselian,indicating significant differences between the time-scales

A ¹⁴C-dated magnetostratigraphy of absolute declination and inclination between 12500 and 10000 ¹⁴C yr BP was recently developed for southern Sweden. Recently also the Swedish geochronological time-scale, based on c. 11 500 annually deposited clay-varves, was connected with the present. It should therefore be possible to compare the two chronologies with a reliable magnetostratigraphic record in an appropriate clay-varve section. We have found such a site within the Middle Swedish end-moraine zone. Statistical correlations between the two independently dated time-scales suggest that at 10500–10200 ¹⁴Cy r BP the varve chronology exceeds the ¹⁴C chronology by the order of 500-600 varve yr. Other correlations indicate that the difference between the two chronologies was less at 11000 ¹⁴C yr BP, and further correlations between the time-scales at 12000 ¹⁴C yr BP suggest that the difference between the chronologies increased steadily from 12000 to 10000 ¹⁴C yr BP. If these correlations are correct they imply that the ¹⁴C production rate increased steadily during the Late Weichselian.     

Partitioning of semi-soluble organic compounds between the water phase and oil droplets in produced water

When selecting produced water treatment technologies, one should focus on reducing the major contributors to the total environmental impact. These are dispersed oil and semi-soluble hydrocarbons, alkylated phenols, and added chemicals. Experiments with produced water have been performed offshore on the Statoil operated platforms Gullfaks C and Statfjord B. These experiments were designed to find how much of the environmentally relevant compounds were dissolved in the water phase and not associated to the dispersed oil in the produced water. Results show that the distribution between the dispersed oil and the water phase varies highly for the different components groups. For example the concentration of PAHs and the C6-C9 alkylated phenols is strongly correlated to the content of dispersed oil. Therefore, the technologies enhancing the removal of dispersed oil have a higher potential for reducing the environmental impact of the produced water than previously considered.     

APEX and ATCA observations of the southern hot core G327.3-0.6 and its environs

There is no generally accepted evolutionary scheme for high mass star formation yet. A simple approach to address this problem is to cover several of the known stages during the formation of massive stars in the same cloud and then investigate their properties trying to construct an evolutionary sequence. Here we present such a project conducted with complementary APEX and ATCA observations. These observations show a compact and bright single hot core in the G327.3-0.6 region on a 0.03 pc scale with a mass of 500 M_⊙ and 0.5–1.5 10⁵ L_⊙. Additionally a clumpy filament is seen in N₂H⁺. Together with cm continuum observations, the data reveal like pearls on a string several stages of massive star formation, with likely the youngest stages hiding in the cold N₂H⁺ cores analysed with a multilevel study of the APEX and ATCA observations.     

High‐resolution bathymetric mapping reveals subaqueous glacial landforms in the Arctic alpine lake Tarfala,Sweden

In Arctic alpine regions, glacio‐lacustrine environments respond sensitively to variations in climate conditions, impacting, for example,glacier extent and rendering former ice‐contact lakes into ice distal lakes and vice versa. Lakefloors may hold morphological records of past glacier extent, but remoteness and long periods of ice cover on such lakes make acquisition of high‐resolution bathymetric datasets challenging. Lake Tarfala and Kebnepakte Glacier, located in the Kebnekaise mountains, northern Sweden, comprise a small, dynamic glacio‐lacustrine system holding a climate archive that is not well studied. Using an autonomous surface vessel, a high‐resolution bathymetric dataset for Lake Tarfala was acquired in 2016, from which previously undiscovered end moraines and a potential grounding line feature were identified. For Kebnepakte Glacier, structure‐from‐motion photogrammetry was used to reconstruct its shape from photographs taken in 1910 and 1945. Combining these methods connects the glacial landform record identified at the lakefloor with the centennial‐scale dynamic behaviour of Kebnepakte Glacier. During its maximum 20^th century extent, attained c. 1910, Kebnepakte Glacier reached far into Lake Tarfala, but had retreated onto land by 1945, at an average of 7.9 m year^–1. Copyright © 2019 John Wiley & Sons, Ltd.     

In search of an elusive Antarctic circumpolar wave in sea ice extents: 1978–1996

For ease in discerning an Antarctic circumpolar wave in the perimeter of the ice pack, we construct a time series of the sea ice extents (essentially the area within the ice perimeter) in 1-degree longitudinal sectors for the period 1978–1996, as observed with the multichannel microwave imagers on board the NASA Nimbus 7 and the DOD (Dept. of Defense) DMSP (Defense Meteorological Satellite Program) F8. F11, and F13 satellites. After converting the time series into complex numbers by means of a Hilbert transform, we decompose the time series of the 360 sectors into its complex principal components (CPCs), effectively separating the spatial and temporal values. Then we decompose the real and imaginary parts of the temporal portions of the first three CPCs (complex principal compenents) by Empirical Mode Decomposition into their intrinsic modes, each representing a narrow frequency band, resulting in a collection of three CPCs for each intrinsic mode. Finally, we reconstruct the data in two different ways. First, we low-pass filter the data by combining all of the intrinsic modes of each CPC with periods longer than two years, which we designate as low-pass filtered. Next, we select the intrinsic mode of each CPC with periods of approximately four years, which we designate the quasiquadrennial (QQ) modes. The low-pass filtered time series shows eastward propagating azimuthal motion in the Ross and Weddell Seas, but no clearly circumpolar motion. The QQ time series, on the other hand, clearly shows castward propagating circumpolar waves, but with occasional retrograde motion to the west.     

Ice fracturing during jökulhlaups: implications for englacial floodwater routing and outlet development

Theoretical studies of glacial outburst floods (jökulhlaups) assume that: (i) intraglacial floodwater is transported efficiently in isolated conduits; (ii) intraglacial conduit enlargement operates proportionally to increasing discharge; (iii) floodwater exits glaciers through pre‐existing ice‐marginal outlets; and (iv) the morphology and positioning of outlets remains fixed during flooding. Direct field observations, together with historical jökulhlaup accounts, confirm that these theoretical assumptions are not always correct. This paper presents new evidence for spatial and temporal changes in intraglacial floodwater routing during jökulhlaups; secondly, it identifies and explains the mechanisms controlling the position and morphology of supraglacial jökulhlaup outlets; and finally, it presents a conceptual model of the controls on supraglacial outbursts. Field observations are presented from two Icelandic glaciers, Skeiðarárjökull and Sólheimajökull. Video footage and aerial photographs, taken before, during and after the Skeiðarárjökull jökulhlaup and immediately after the Sólheimajökull jökulhlaup, reveal changes in floodwater routing and the positioning and morphology of outlets. Field observations confirm that glaciers cannot transmit floodwater as efficiently as previously assumed. Rapid increases in jökulhlaup discharge generate basal hydraulic pressures in excess of ice overburden. Under these circumstances, floodwater can be forced through the surface of glaciers, leading to the development of a range of supraglacial outlets. The rate of increase in hydraulic pressure strongly influences the type of supraglacial outlet that can develop. Steady increases in basal hydraulic pressure can retro‐feed pre‐existing englacial drainage, whereas transient increases in pressure can generate hydraulic fracturing. The position and morphology of supraglacial outlets provide important controls on the spatial and temporal impact of flooding. The development of supraglacial jökulhlaup outlets provides a new mechanism for rapid englacial debris entrainment. Copyright © 2000 John Wiley & Sons, Ltd.     

Chronology of late Holocene climatic events in the northern North Atlantic based on AMS 14C dates and tephra markers from the volcano Hekla,Iceland

A combination of AMS¹⁴C dating and tephrochronology has been used to date late Holocene oceanographic events in a 335 cm marine record, covering about 4600 cal. yr with sedimentation rates exceeding 80 cm 1000 yr⁻¹. The core site is located 50 km offshore on the northern Icelandic shelf. Tephra markers from Iceland serve to correlate the marine and terrestrial records. Especially notable is the presence of three geochemically correlated tephra markers from the Icelandic volcano Hekla (Hekla 4, Hekla 3 and Hekla 1104). Benthic and planktonic foraminiferal abundance and distribution as well as the petrography of the sand fraction of the muddy shelf sediments are used as palaeoceanographic proxies. The foraminiferal assemblages reflect a general cooling trend during the last 4600 yr. A marked drop in sea‐surface temperatures is registered at about 3000 cal. yr BP, corresponding to the level of the Hekla 3 tephra. There is faunal indication of temperature amelioration during the Medieval Warm Period and a cooling again during the Little Ice Age. Periods of ice rafting events are indicated by ice rafted debris (IRD) concentrations, e.g. at around 3000 cal. yr BP and during the Little Ice Age. The former event occurred just prior to the deposition of the Hekla 3 tephra marker, the largest Holocene Hekla eruption. A correlation with terrestrial climatic events in Iceland is presented. A standard marine reservoir correction of 400 ¹⁴C yr appears to be reasonable, at least during periods with high influence of water masses from the Irminger Current on the northern Icelandic shelf. An increase to ca. 530 ¹⁴C yr may have occurred, however, when water masses derived from the East Greenland Current were dominant in the area. Copyright © 2000 John Wiley & Sons, Ltd.     

Molecular analysis of petroleum derived compounds that adsorb onto gas hydrate surfaces

Field observations have shown that some streams of water, gas and crude oil do not form gas hydrate plugs during petroleum production even when operating within thermodynamic conditions for hydrate formation. Also, when studied under controlled laboratory conditions, some oils are found to form hydrate dispersed systems whereas others form plugs. Oils with low tendency to form hydrate plugs are believed to contain natural hydrate plug inhibiting components (NICs) that adsorb onto the hydrate surface, making them less water-wet and preventing the particles from agglomerating into large hydrate clusters. The molecular structure of the NICs is currently unknown. In this work, hydrate adsorbing components were extracted from crude oils using freon hydrates as an extraction phase. The fractions were found to be enriched in polar material, and more polar material is associated with hydrates generated in biodegraded crude oils than in non-biodegraded oils. Various fractionation schemes and analytical techniques have been applied in the search for molecular characterisation. The average molecular weights were found to be approximately 500 g/mole. GC–MS chromatograms show a large UCM (Unresolved Complex Mixture). Thus, GC–MS has a limited potential for identification of compounds. A commercial biosurfactant was used as a model compound in the search for similar structures in the extracts. The results from analysis of the hydrate adsorbing components suggest that the type and structure are more important for hydrate morphology than the amount of material adsorbed.     

Improving the Coastal Mean Dynamic Topography by Geodetic Combination of Tide Gauge and Satellite Altimetry

Abstract

The ocean mean dynamic topography (MDT) is the surface representation of the ocean circulation. The MDT may be determined by the ocean approach, which involves temporal averaging of numerical ocean circulation model information, or by the geodetic approach, wherein the MDT is derived using the ellipsoidal height of the mean sea surface (MSS), or mean sea level (MSL) minus the geoid as the geoid. The ellipsoidal height of the MSS might be estimated either by satellite or coastal tide gauges by connecting the tide gauge datum to the Earth-centred reference frame. In this article we present a novel approach to improve the coastal MDT, where the solution is based on both satellite altimetry and tide gauge data using new set of 302 tide gauges with ellipsoidal heights through the SONEL network. The approach was evaluated for the Northeast Atlantic coast where a dense network of GNSS-surveyed tide gauges is available. The typical misfit between tide gauge and satellite or oceanographic MDT was found to be around 9?cm. This misfit was found to be mainly due to small scale geoid errors. Similarly, we found, that a single tide gauge places only weak constraints on the coastal dynamic topography.