II. Combined numerical model of ion and neutral composition above 120 km

A coupled neutral-ionic photochemical model has been used to interpret the ionic composition of the Venusian dayside ionosphere measured by the orbiter retarding potential analyser (ORPA) experiment on board the NASA Pioneer-Venus orbiter spacecraft. The electron and ion temperatures also measured by the ORPA are used for calculating the plasma-diffusion coefficients and scale heights for ions. The neutral temperature profiles and the densities of neutral constituents, particularly CO₂ and O, play key roles in the determination of the height profiles of the ionic constituents. All these quantities vary substantially in the Venusian thermosphere near the terminator; the models presented are representatives of the solar zenith angle ～65°. The predicted O₂⁺ densities below ～200km agree particularly well with observations by the ORPA, but the model values are significantly less than those measured by the orbiter ion mass spectrometer (OIMS). Models predict much smaller densities than observed values for all molecular ions above ～200km. The reason for the turn-up trend of the concentration gradient of molecular ions observed at these heights by both ORPA and OIMS is unknown. One of the models can predict O⁺ ion densities above ～200km compatible with observations, if an effective vertical escape flux (φ10⁸cm^?2sec^?1) is assumed at the ionopause. The neutral air density required to explain the observed ion composition is about 1.4 times larger than the values measured by the orbiter neutral mass spectrometer (ONMS).     

Supradetachment to rift basin transition recorded in continental to marine deposition; Paleogene Bandar Jissah Basin,NE Oman

A transition from supradetachment to rift basin signature is recorded in the ~1,500 m thick succession of continental to shallow marine conglomerates, mixed carbonate‐siliciclastic shallow marine sediments and carbonate ramp deposits preserved in the Bandar Jissah Basin, located southeast of Muscat in the Sultanate of Oman. During deposition, isostatically‐driven uplift rotated the underlying Banurama Detachment and basin fill ~45° before both were cut by the steep Wadi Kabir Fault as the basin progressed to a rift‐style bathymetry that controlled sedimentary facies belts and growth packages. The upper Paleocene to lower Eocene Jafnayn Formation was deposited in a supradetachment basin controlled by the Banurama Detachment. Alluvial fan conglomerates sourced from the Semail Ophiolite and the Saih Hatat window overlie the ophiolitic substrate and display sedimentary transport directions parallel to tectonic transport in the Banurama Detachment. The continental strata grade into braidplain, mouth bar, shoreface and carbonate ramp deposits. Subsequent detachment‐related folding of the basin during deposition of the Eocene Rusayl and lower Seeb formations marks the early transition towards a rift‐style basin setting. The folding, which caused drainage diversion and is affiliated with sedimentary growth packages, coincided with uplift‐isostasy as the Banurama Detachment was abandoned and the steeper Marina, Yiti Beach and Wadi Kabir faults were activated. The upper Seeb Formation records the late transition to rift‐style basin phase, with fault‐controlled sedimentary growth packages and facies distributions. A predominance of carbonates over siliciclastic sediments resulted from increasing near‐fault accommodation, complemented by reduced sedimentary input from upland catchments. Hence, facies distributions in the Bandar Jissah Basin reflect the progression from detachment to rift‐style tectonics, adding to the understanding of post‐orogenic extensional basin systems.     

Statistical EOF analysis of spatiotemporal glacier mass-balance variability: a case study of Mittivakkat Gletscher,SE Greenland

An Empirical Orthogonal Function (EOF) variance analysis was performed to map in detail the spatiotemporal variability in individual stake mass-balances (ba) on Mittivakkat Gletscher (MG) – in a region where at present five out of ~20.000 glaciers have mass-balance observations. The EOF analysis suggested that observed ba was summarized by two modes: EOF1 and EOF2 represented 80% (significant) and 6% (insignificant) of the explained variance, respectively. EOF1 captured a decline in ba that was uniformly distributed in space at all stakes. The decline was correlated with albedo observations and air temperature observations from nearby stations. EOF2, however, described variations in ba that were heterogeneously distributed among stakes and associated with local slope and aspect. Low elevation stakes (~<400 m a.s.l.) showed relatively negative (out of phase) correlation and higher elevated stakes relatively positive (in phase) eigenvector correlation values with EOF2. Such relatively negative and positive eigenvector correlation values were present where the constituted of exposed glacier ice or snow cover, respectively. The results from this study show how EOF analyses can provide information on spatiotemporal patterns of glacier mass-balance. Understanding such detailed variabilities in mass-balance on a Greenlandic glacier is of interest because a fifth of the Arctic contribution from glaciers and ice caps to sea-level rise originates from Greenland.     

A 10Be‐based reconstruction of the last deglaciation in southern Sweden

We present 23 cosmogenic surface exposure ages from 10 localities in southern Sweden. The new ¹⁰Be ages allow a direct correlation between the east and west coasts of southern Sweden, based on the same dating technique, and provide new information about the deglaciation of the Fennoscandian Ice Sheet in the circum‐Baltic area. In western Skåne, southernmost Sweden, a single cosmogenic surface exposure sample gave an age of 16.8±1.0 ka, whereas two samples from the central part of Skåne gave ages of 17.0±0.9 and 14.1±0.8 ka. Further northeast, in southern Småland, two localities gave ages ranging from 15.2±0.8 to 16.9±0.9 ka (n=5) indicating a somewhat earlier deglaciation of the area than has previously been suggested. Our third locality, in S Småland, gave ages ranging from 10.2±0.5 to 18.4±1.6 ka (n=3), which are probably not representative of the timing of deglaciation. In central Småland one locality was dated to 14.5±0.8 ka (n=3), whereas our northernmost locality, situated in northern Småland, was dated to 13.8±0.8 ka (n=3). Samples from the island of Gotland suggest deglaciation before 13 ka ago. We combined the new ¹⁰Be ages with previously published deglaciation ages to constrain the deglaciation chronology of southern Sweden. The combined deglaciation chronology suggests a rather steady deglaciation in southern Sweden starting at c. 17.9 cal. ka BP in NW Skåne and reaching northern Småland, ～200 km further north, c. 13.8 ka ago. Overall the new deglaciation ages agree reasonably well with existing deglaciation chronologies, but suggest a somewhat earlier deglaciation in Småland.     

A MODIS-based modeling scheme for the estimation of downward surface shortwave radiation under cloud-free conditions

Atmospheric aerosol optical depth (AOD) plays an important role in radiation modeling and partly determines the accuracy of estimated downward surface shortwave radiation (DSSR). In this study, Iqbal’s model C was used to estimate DSSR under cloud-free conditions over the Koohin and Chitgar sites in Tehran, Iran; the estimated DSSR was based on (1) our proposed hybrid modeling scheme where the AOD is retrieved using the Simplified Aerosol Retrieval Algorithm (SARA), ground-based measurements at the AERONET site in Zanjan and (2) the AOD from the Terra MODerate-resolution Imaging Spectroradiometer (MODIS) sensor. Several other Terra MODIS land and atmospheric products were also used as input data, including geolocation properties, water vapor, total ozone, surface reflectance, and top-of-atmosphere (TOA) radiance. SARA-based DSSR and MODIS-based DSSR were evaluated with ground-based DSSR measurements at the Koohin and Chitgar sites in 2011 and 2013, respectively; the averaged statistics for SARA-based DSSR [R ² ≈ 0.95, RMSE ≈ 22 W/m² (2.5% mean value), and bias ≈ 3 W/m²] were stronger than those for MODIS-based DSSR [R ² ≈ 0.79, RMSE ≈ 51 W/m² (5.8% mean value), and bias ≈ 34 W/m²]. These results show that the proposed hybrid scheme can be used at regional to global scales under the assumption of future access to spatially distributed AERONET sites. Additionally, the robustness of this modeling scheme was exemplified by estimating the aerosol radiative forcing (ARF) during a dust storm in Southwest Asia. The results were comparable to those of previous studies and showed the strength of our modeling scheme.     

Iron isotope variations in Holocene sediments of the Gotland Deep, Baltic Sea

Holocene sediments from the Gotland Deep basin in the Baltic Sea were investigated for their Fe isotopic composition in order to assess the impact of changes in redox conditions and a transition from freshwater to brackish water on the isotope signature of iron. The sediments display variations in δ⁵⁶Fe (differences in the ⁵⁶Fe/⁵⁴Fe ratio relative to the IRMM-14 standard) from −0.27 ± 0.09‰ to +0.21 ± 0.08‰. Samples deposited in a mainly limnic environment with oxygenated bottom water have a mean δ⁵⁶Fe of +0.08 ± 0.13‰, which is identical to the mean Fe isotopic composition of igneous rocks and oxic marine sediments. In contrast, sediments that formed in brackish water under periodically euxinic conditions display significantly lighter Fe isotope signatures with a mean δ⁵⁶Fe of −0.14 ± 0.19‰. Negative correlations of the δ⁵⁶Fe values with the Fe/Al ratio and S content of the samples suggest that the isotopically light Fe in the periodically euxinic samples is associated with reactive Fe enrichments and sulfides. This is supported by analyses of pyrite separates from this unit that have a mean Fe isotopic composition of −1.06 ± 0.20‰ for δ⁵⁶Fe. The supply of additional Fe with a light Fe isotopic signature can be explained with the shelf to basin Fe shuttle model. According to the Fe shuttle model, oxides and benthic ferrous Fe that is derived from dissimilatory iron reduction from shelves is transported and accumulated in euxinic basins. The data furthermore suggest that the euxinic water has a negative dissolved δ⁵⁶Fe value of about −1.4‰ to −0.9‰. If negative Fe isotopic signatures are characteristic for euxinic sediment formation, widespread euxinia in the past might have shifted the Fe isotopic composition of dissolved Fe in the ocean towards more positive δ⁵⁶Fe values.