Magnetic Susceptibility Screening of Anthropogenic Impact on the Danube River Sediments in Northwestern Bulgaria - Preliminary Results

Several events of anthropogenic impacts on the floodplain river sediments of the Danube along a section near the town of Oryakhovo (NW Bulgaria) have been detected using magnetic technique. In the field, magnetic susceptibility was measured using three susceptibility meters – MS2D, KT-5 and SM30. The differences in the surface susceptibility values measured with the different instruments are ascribed to the various penetration depths which depend on several parameters like sensor diameter, frequency and field strength. This is supported by the detailed laboratory study on penetration depth and sensitivity of the new SM30 susceptibility meter and the comparison with the already existing data for the other two sensors. Boundaries between different flooding events are clearly linked with significant variability of the measured susceptibility values corresponding to one and the same level. Sediment cores, taken at different distances from the water level, show the history of depositional events and corresponding degree of anthropogenic pollution. Identification of the magnetic phases responsible for the signal was carried out by means of thermomagnetic (T) curves. The main carrier is magnetite with Tc of 580°C or oxidized magnetite with Tc of 600°C. A second kink at about 300°C is better expressed for samples with lower susceptibilities. It may correspond to several minerals, e.g. maghemite, pyrrothite, titanomagnetite, as well as different mineral transformations of paramagnetic minerals (decomposition, dehydroxilation, etc. for example siderite, lepidocrocite). The samples showing strong magnetic enhancement are characterized by the predominance of magnetite. Optical microscopy on magnetic extracts shows the presence of small spherical particles, typical for the anthropogenic magnetic phases from high-temperature technological processes. Well expressed susceptibility variations along the cores suggest the presence of several stages of different degree of pollution, covering an estimated period of about 30 years.     

Cyanobacteria as a trigger for increased primary productivity during sapropel formation in the Baltic Sea—a study of the Ancylus/Litorina transition

A sediment sequence from the Gotland Basin, representing the Ancylus Lake/Litorina Sea transition, was analysed for pigments, stable isotopes (δ¹³C and δ¹⁵N), diatoms and carbon and nitrogen content. The negative correlation between the cyanobacterial specific pigment zeaxanthin and δ¹⁵N supports the hypothesis that cyanobacteria in the early Litorina Sea indeed were nitrogen fixers. Their incorporation of nitrogen could have acted as a trigger for eutrophication during the Litorina Sea stage of the Baltic Sea. As cyanobacteria normally flourish in eutrophicated waters, the increasing concentrations of zeaxanthin during early Litorina Sea also corroborate that high primary production was an important part of the formation of organic rich (sapropel) sediments in the Baltic Sea. The first occurrence pre-dates the formation of laminated sediments, but the peaks of both zeaxanthin and organic carbon are within laminated sequences. This implies that the oxygen conditions of the bottom water also play a major role in the formation of sapropel sediments.     

Beach scraping — Is it damaging to beach stability?

Beach scraping is removal of material from the lower part of the beach for deposition on the higher part of the beach or at the dune toe. Beach scraping has become a controversial subject, as it is sometimes claimed that it does little good to the beach in question, and is harmful to adjacent beaches. This brief article is a discussion on the subject. The conclusion is that undertaken in a practical and modest manner, scraping is not harmful but rather it is beneficial in protecting dunes and dykes against erosion on a short-term basis.     

Field Experimental Investigations on the Fe(II)- and Fe(III)-Content in Cloudwater Samples

The Fe(II)/Fe(III)-partition in cloudwater samples collected during two field campaigns is evaluated. It turned out that the simultaneous occurrence of complexing and reducing substances in the atmosphere and the cloud processing increase the solubility of iron compounds present in aerosol particles. A correlation between the concentration of iron(II) in the liquid phase and the intensity of the solar irradiation was observed for most of the cloudwater samples. This could be due to the fact that both the photochemical reduction of the iron(III) complexes and the photochemical reductive dissolution of iron(III)(hydr)oxides are depending on the pH-value. Iron(II) seems to be oxidised back to iron(III) preferably by hydrogen peroxide during the night. Positive correlations were received e.g. between the concentration of dissolved iron and the concentration of oxalate and between the percentage of iron(III) and the concentration of hydrogen peroxide. A negative correlation was found e.g. between the concentration of dissolved iron and the pH-value. The uncertainty of the whole process of sampling and analysis was investigated and the conformity of the results was satisfying considering the sometimes difficult conditions during a field campaign.     

Till mélange at Amsdorf, central Germany: sediment erosion, transport and deposition in a complex, soft-bedded subglacial system

Glacial mélange in the open-cast mine at Amsdorf, central Germany, consists of several square meters of large, sorted sediment blocks embedded in till. The blocks are composed of largely intact to slightly deformed glaciofluvial and glaciolacustrine sand, silt and clay, initially deposited in a proglacial lake (2–3 km up-ice) and subsequently overridden by a glacier. The blocks typically have cuboid to subrounded outlines, are randomly distributed in the till, and the contacts with the surrounding till are distinctly sharp. Underneath the mélange are varved clays which exhibit strong deformations occasionally intervening with entirely undisturbed areas. It is suggested that the blocks were entrained into debris-rich basal-ice by bulk freeze-on when the glacier sole was lowered onto the bottom of an overridden lake. After entrainment the blocks were transported englacially and re-deposited (with far-traveled till matrix) as a melt-out till from stagnant ice. The glacier moved mainly by sliding enhanced by low-permeability varved clays in the substratum. The glacier is believed to have been of a polythermal type. These results show that bulk freeze-on can lead to entrainment of soft sediment blocks at least 20 m² in size, and that these blocks can be englacially transported with little or no deformation for several kilometers and more. The occurrence of deformed and undeformed clays under the till mélange indicates a possible mosaic of coupled and decoupled ice, the latter caused by a thin, transient subglacial water film separating the bed from the glacier.     

On the influence of kriging parameters on the cartographic output—A study in mapping subglacial topography

Geostatistics provides a suite of methods, summarized as kriging, to analyze a finite data set to describe a continuous property of the Earth. Kriging methods consist of moving window optimum estimation techniques, which are based on a least-squares principle and use a spatial structure function, usually the variogram. Applications of kriging techniques have become increasingly wide-spread, with ordinary kriging and universal kriging being the most popular ones. The dependence of the final map or model on the input, however, is not generally understood. Herein we demonstrate how changes in the kriging parameters and the neighborhood search affect the cartographic result. Principles are illustrated through a glaciological study. The objective is to map ice thickness and subglacial topography of Storglaciären, Kebnekaise Massif, northern Sweden, from several sets of radio-echo soundings and hot water drillings. New maps are presented.     

Separation of residual ocean tide signals in a collinear analysis of Geosat altimetry

The effects of residual ocean tide signals on altimetric mesoscale variability estimates are analyzed in the north east Atlantic region using one year of Geosat Exact Repeat Mission data. The variability is evaluated along collinear tracks and covariance functions are determined. Initial results show that the average variability is about 10 cm. Variability values of 15–20 cm are found between Iceland and the Faeroe Islands and values up to 1/2 m are found near the coast of the UK. Then a procedure for estimation of ocean tide signals combined with the collinear analyses was tested. A separation of the estimated tide residuals associated with M₂, S₂, and N₂ resulted in a significant reduction of the variability. The average variability decreased to 5 cm and the temporal correlations vanished. A reduction of the large variability values from 15–50 cm to 5–10 cm demonstrates that significant residual ocean tide signals can be estimated and removed efficiently in a collinear analysis of the mesoscale ocean variability.     

Greigite (Fe3S4): magnetic properties and first domain observations

Recently the ferrimagnetic iron sulphide greigite (Fe₃S₄) has been recognized as an important carrier of magnetic remanence in young sediments. New magnetic measurements and properties of this rare mineral are presented. Magnetic domain observations were made using the Bitter method and the magneto-optical Kerr effect. In most cases the domain structures observed are very complicated and their interpretation is rather difficult. The cause of this domain structure is very likely high magnetostriction. A first attempt to establish a relationship between grain size and domain state is made.