The use of 210Pb as a heavy metal tracer in the Susquehanna River system

Analysis of soil profiles and shallow ground water in the Susquehanna River basin, northeastern U.S.A., indicates that the atmospheric flux of ²¹⁰Pb is efficiently scavenged by the organic-rich horizons of the soils. This atmospherically supplied ²¹⁰Pb in soil profiles can only be lost from the system by soil erosion. Based on the annual sediment yield of the Susquehanna River and the excess ²¹⁰Pb concentration in particulate matter, a mean residence time of 2000 yr is calculated for metals similar to Pb in soil profiles.The West Branch of the Susquehanna River (WBSR) is strongly affected by acid mine drainage and is low in pH and high in dissolved ( <0.4 μm) ²¹⁰Pb, Fe and Mn. Along its course iron hydroxide is precipitating at a pH of between 4 and 4.5 and the ²¹⁰Pb supplied by the acid mine water is diminished by about 25% as a result of dilution. As the WBSR enters the Valley and Ridge Province of the Appalachians it has a ²¹⁰Pb concentration of ~ 0.2 dpm/l. At this juncture it receives a considerable influx of alkalinity from tributaries draining carbonate terranes, resulting in neutralization of the sulfuric acid and increase of the river pH to around 6.5–7. This pH adjustment is accompanied by the precipitation of Fe and Mn. Due to the slow rate of Mn removal from solution, the Mn precipitation extends a considerable distance down river from the point of acid neutralization. Analyses for ²¹⁰Pb in the river at points in or below the region of Mn precipitation show that ²¹⁰Pb is rapidly scavenged from solution onto suspended particles. From the data it is possible to calculate the removal rate of Pb from water in the presence of Fe and Mn hydroxides and other particles. At a pH of 4–4.5 Pb removal is nonexistent relative to the river flow rate, but at a pH of 6.5–7 the ²¹⁰Pb data indicate a residence time of <0.7 day for dissolved Pb.     

Variations in 24-μm morphologies among galaxies in the Spitzer Infrared Nearby Galaxies Survey: new insights into the Hubble sequence

To study the distribution of star formation and dust emission within nearby galaxies, we measured five morphological parameters in the 3.6- and 24-μm wavebands for 65 galaxies in the Spitzer Infrared Nearby Galaxies Survey (SINGS) and eight galaxies that were serendipitously observed by SINGS. The morphological parameters demonstrate strong variations along the Hubble sequence, including statistically significant differences between S0/a-Sab and Sc-Sd galaxies. Early-type galaxies are generally found to be compact, centralized, symmetric sources in the 24-μm band, while late-type galaxies are generally found to be extended, asymmetric sources. These results suggest that the processes that increase the real or apparent sizes of galaxies' bulges also lead to more centralized 24-μm dust emission. Several phenomena, such as strong nuclear star formation, Seyfert activity, or outer ring structures, may cause galaxies to deviate from the general morphological trends observed at 24 μm. We also note that the 24-μm morphologies of Sdm-Im galaxies are quite varied, with some objects appearing very compact and symmetric but others appearing diffuse and asymmetric. These variations reflect the wide variation in star formation in irregular galaxies as observed at other wavelengths. The variations in the 24-μm morphological parameters across the Hubble sequence mirror many of the morphological trends seen in other tracers of the ISM and in stellar emission. However, the 24-μm morphological parameters for the galaxies in this sample do not match the morphological parameters measured in the stellar wavebands. This implies that the distribution of dust emission is related to but not equivalent to the distribution of stellar emission.     

Filamentary structures in planetary nebulae

We have studied small-scale, filamentary features in 14 planetary nebulae and found that some structures are recurrent and shaped like the letters V and Y, with the apex or stem pointing toward the central parts of the nebula. Two such filaments containing dust, one in NGC 3132 and one in NGC 7293, were investigated in more detail. The mass and density of the filaments were obtained from extinction measurements, and their physical properties were derived. We propose that the structures are confined by magnetic fields, and derive magnetic field strengths of about 10⁻⁸ T, in line with earlier estimates. We also estimate the magnitude of the electric currents that we expect are generated in these dynamic systems. We propose a theory where the magnetic fields control the sculpting and evolution of small-scale filaments. This theory demonstrates how the substructures may form magnetized flux ropes that are twisted around each other, in the shape of double helices. Similar structures, and with similar origin, are found in many other astrophysical environments.     

Secular tidal changes in lunar orbit and Earth rotation

Small tidal forces in the Earth–Moon system cause detectable changes in the orbit. Tidal energy dissipation causes secular rates in the lunar mean motion n, semimajor axis a, and eccentricity e. Terrestrial dissipation causes most of the tidal change in n and a, but lunar dissipation decreases eccentricity rate. Terrestrial tidal dissipation also slows the rotation of the Earth and increases obliquity. A tidal acceleration model is used for integration of the lunar orbit. Analysis of lunar laser ranging (LLR) data provides two or three terrestrial and two lunar dissipation parameters. Additional parameters come from geophysical knowledge of terrestrial tides. When those parameters are converted to secular rates for orbit elements, one obtains dn/dt = \(-25.97\pm 0.05 ''/\)cent\(^{2}\), da/dt = 38.30 ± 0.08 mm/year, and di/dt = ?0.5 ± 0.1 \(\upmu \)as/year. Solving for two terrestrial time delays and an extra de/dt from unspecified causes gives \(\sim \) \(3\times 10^{-12}\)/year for the latter; solving for three LLR tidal time delays without the extra de/dt gives a larger phase lag of the N2 tide so that total de/dt = \((1.50 \pm 0.10)\times 10^{-11}\)/year. For total dn/dt, there is \(\le \)1 % difference between geophysical models of average tidal dissipation in oceans and solid Earth and LLR results, and most of that difference comes from diurnal tides. The geophysical model predicts that tidal deceleration of Earth rotation is \(-1316 ''\)/cent\(^{2}\) or 87.5 s/cent\(^{2}\) for UT1-AT, a 2.395 ms/cent increase in the length of day, and an obliquity rate of 9 \(\upmu \)as/year. For evolution during past times of slow recession, the eccentricity rate can be negative.     

Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

Pathways and regulation of carbon, sulfur and energy transfer in marine sediments overlying methane gas hydrates on the Opouawe Bank (New Zealand)

This study combines sediment geochemical analysis, in situ benthic lander deployments and numerical modeling to quantify the biogeochemical cycles of carbon and sulfur and the associated rates of Gibbs energy production at a novel methane seep. The benthic ecosystem is dominated by a dense population of tube-building ampharetid polychaetes and conspicuous microbial mats were unusually absent. A 1D numerical reaction-transport model, which allows for the explicit growth of sulfide and methane oxidizing microorganisms, was tuned to the geochemical data using a fluid advection velocity of 14 cm yr⁻¹. The fluids provide a deep source of dissolved hydrogen sulfide and methane to the sediment with fluxes equal to 4.1 and 18.2 mmol m⁻² d⁻¹, respectively. Chemosynthetic biomass production in the subsurface sediment is estimated to be 2.8 mmol m⁻² d⁻¹ of C biomass. However, carbon and oxygen budgets indicate that chemosynthetic organisms living directly above or on the surface sediment have the potential to produce 12.3 mmol m⁻² d⁻¹ of C biomass. This autochthonous carbon source meets the ampharetid respiratory carbon demand of 23.2 mmol m⁻² d⁻¹ to within a factor of 2. By contrast, the contribution of photosynthetically-fixed carbon sources to ampharetid nutrition is minor (3.3 mmol m⁻² d⁻¹ of C). The data strongly suggest that mixing of labile autochthonous microbial detritus below the oxic layer sustains high measured rates of sulfate reduction in the uppermost 2 cm of the sulfidic sediment (100-200 nmol cm⁻³ d⁻¹). Similar rates have been reported in the literature for other seeps, from which we conclude that autochthonous organic matter is an important substrate for sulfate reducing bacteria in these sediment layers. A system-scale energy budget based on the chemosynthetic reaction pathways reveals that up to 8.3 kJ m⁻² d⁻¹ or 96 mW m⁻² of catabolic (Gibbs) energy is dissipated at the seep through oxidation reactions. The microorganisms mediating sulfide oxidation and anaerobic oxidation of methane (AOM) produce 95% and 2% of this energy flux, respectively. The low power output by AOM is due to strong bioenergetic constraints imposed on the reaction rate by the composition of the chemical environment. These constraints provide a high potential for dissolved methane efflux from the sediment (12.0 mmol m⁻² d⁻¹) and indicates a much lower efficiency of (dissolved) methane sequestration by AOM at seeps than considered previously. Nonetheless, AOM is able to consume a third of the ascending methane flux (5.9 mmol m⁻² d⁻¹ of CH₄) with a high efficiency of energy expenditure (35 mmol CH₄ kJ⁻¹). It is further proposed that bioenergetic limitation of AOM provides an explanation for the non-zero sulfate concentrations below the AOM zone observed here and in other active and passive margin sediments.     

Evaluation of three harvest control rules for Bigeye Tuna (Thunnus obesus) fisheries in the Indian Ocean

The stock of Bigeye tuna(Thunnus obesus) in the Indian Ocean supports an important international fishery and is considered to be fully exploited. The responsible management agency, the Indian Ocean Tuna Commission(IOTC), does not have an explicit management decision-making framework in place to prevent over-fishing. In this study, we evaluated three harvest control rules, i) constant fishing mortality(CF), from 0.2 to 0.6, ii) constant catch(CC), from 60000 to 140000 t, and iii) constant escapement(CE), from 0.3 to 0.7. The population dynamics simulated by the operating model was based on the most recent stock assessment using Stock Synthesis version Ⅲ(SS3). Three simulation scenarios(low, medium and high productivity) were designed to cover possible uncertainty in the stock assessment and biological parameters. Performances of three harvest control rules were compared on the basis of three management objectives(over 3, 10 and 25 years): i) the probability of maintaining spawning stock biomass above a level that can sustain maximum sustainable yield(MSY) on average, ii) the probability of achieving average catches between 0.8 MSY and 1.0 MSY, and iii) inter-annual variability in catches. The constant escapement strategy(CE=0.5), constant fishing mortality strategy(F=0.4) and constant catch(CC=80000) were the most rational among the respective management scenarios. It is concluded that the short-term annual catch is suggested at 80000 t, and the potential total allowable catch for a stable yield could be set at 120000 t once the stock had recovered successfully. All the strategies considered in this study to achieve a ‘tolerable' balance between resource conservation and utilization have been based around the management objectives of the IOTC.     

Enhancing the relevance of Shared Socioeconomic Pathways for climate change impacts,adaptation and vulnerability research

This paper discusses the role and relevance of the shared socioeconomic pathways (SSPs) and the new scenarios that combine SSPs with representative concentration pathways (RCPs) for climate change impacts, adaptation, and vulnerability (IAV) research. It first provides an overview of uses of social–environmental scenarios in IAV studies and identifies the main shortcomings of earlier such scenarios. Second, the paper elaborates on two aspects of the SSPs and new scenarios that would improve their usefulness for IAV studies compared to earlier scenario sets: (i) enhancing their applicability while retaining coherence across spatial scales, and (ii) adding indicators of importance for projecting vulnerability. The paper therefore presents an agenda for future research, recommending that SSPs incorporate not only the standard variables of population and gross domestic product, but also indicators such as income distribution, spatial population, human health and governance.