A 10Be‐based reconstruction of the last deglaciation in southern Sweden

We present 23 cosmogenic surface exposure ages from 10 localities in southern Sweden. The new ¹⁰Be ages allow a direct correlation between the east and west coasts of southern Sweden, based on the same dating technique, and provide new information about the deglaciation of the Fennoscandian Ice Sheet in the circum‐Baltic area. In western Skåne, southernmost Sweden, a single cosmogenic surface exposure sample gave an age of 16.8±1.0 ka, whereas two samples from the central part of Skåne gave ages of 17.0±0.9 and 14.1±0.8 ka. Further northeast, in southern Småland, two localities gave ages ranging from 15.2±0.8 to 16.9±0.9 ka (n=5) indicating a somewhat earlier deglaciation of the area than has previously been suggested. Our third locality, in S Småland, gave ages ranging from 10.2±0.5 to 18.4±1.6 ka (n=3), which are probably not representative of the timing of deglaciation. In central Småland one locality was dated to 14.5±0.8 ka (n=3), whereas our northernmost locality, situated in northern Småland, was dated to 13.8±0.8 ka (n=3). Samples from the island of Gotland suggest deglaciation before 13 ka ago. We combined the new ¹⁰Be ages with previously published deglaciation ages to constrain the deglaciation chronology of southern Sweden. The combined deglaciation chronology suggests a rather steady deglaciation in southern Sweden starting at c. 17.9 cal. ka BP in NW Skåne and reaching northern Småland, ～200 km further north, c. 13.8 ka ago. Overall the new deglaciation ages agree reasonably well with existing deglaciation chronologies, but suggest a somewhat earlier deglaciation in Småland.     

An Improved 20-Year Arctic Ocean Altimetric Sea Level Data Record

For ocean and climate research, it is essential to get long-term altimetric sea level data that is as accurate as possible. However, the accuracy of the altimetric data is frequently degraded in the interior of the Arctic Ocean due to the presence of seasonal or permanent sea ice. We have reprocessed ERS-1/2/Envisat satellite altimetry to develop an improved 20-year sea level dataset for the Arctic Ocean. We have developed both an along-track dataset and three-day gridded sea level anomaly (SLA) maps from September 1992 to April 2012. A major improvement in data coverage was gained by tailoring the standard altimetric editing criteria to Arctic conditions. The new reprocessed data has significant increased data coverage with between 4 and 10 times the amount of data in regions such as the Beaufort Gyre region compared with AVISO and RADS datasets. This allows for a more accurate estimation of sea level changes from satellite altimetry in the Arctic Ocean. The reprocessed dataset exhibit a mean sea level trend of 2.1 ± 1.3 mm/year (without Glacial Isostatic Adjustment correction) covering the Arctic Ocean between 66°N and 82°N with significant higher spatial coherency in the ice-covered regions than the RADS and DUACS datasets.     

Coordination chemistry and hydrolysis of Fe(III) in a peat humic acid studied by X-ray absorption spectroscopy

The speciation of iron (Fe) in soils, sediments and surface waters is highly dependent on chemical interactions with natural organic matter (NOM). However, the molecular structure and hydrolysis of the Fe species formed in association with NOM is still poorly described. In this study extended X-ray absorption fine structure (EXAFS) spectroscopy was used to determine the coordination chemistry and hydrolysis of Fe(III) in solution of a peat humic acid (5010-49,200 μg Fe g⁻¹ dry weight, pH 3.0-7.2). Data were analyzed by both conventional EXAFS data fitting and by wavelet transforms in order to facilitate the identification of the nature of backscattering atoms. Our results show that Fe occurs predominantly in the oxidized form as ferric ions and that the speciation varies with pH and Fe concentration. At low Fe concentrations (5010-9920 μg g⁻¹; pH 3.0-7.2) mononuclear Fe(III)-NOM complexes completely dominates the speciation. The determined bond distances for the Fe(III)-NOM complexes are similar to distances obtained for Fe(III) complexed by desferrioxamine B and oxalate indicating the formation of a five-membered chelate ring structure. At higher Fe concentrations (49,200 μg g⁻¹; pH 4.2-6.9) we detect a mixture of mononuclear Fe(III)-NOM complexes and polymeric Fe(III) (hydr)oxides with an increasing amount of Fe(III) (hydr)oxides at higher pH. However, even at pH 6.9 and a Fe concentration of 49,200 μg g⁻¹ our data indicates that a substantial amount of the total Fe (>50%) is in the form of organic complexes. Thus, in environments with significant amounts of organic matter organic Fe complexes will be of great importance for the geochemistry of Fe. Furthermore, the formation of five-membered chelate ring structures is in line with the strong complexation and limited hydrolytic polymerization of Fe(III) in our samples and also agrees with EXAFS derived structures of Fe(III) in organic soils.     

Estimating <Emphasis Type="Italic">probable maximum loss</Emphasis> from a Cascadia tsunami

The Cascadia margin is capable of generating large magnitude seismic-tsunami. We use a 1:500 year tsunami hazard flood layer produced during a probabilistic tsunami hazard assessment as the input to a pilot study of the vulnerability of residential and commercial buildings in Seaside, OR, USA. We map building exposure, apply the Papathoma Tsunami Vulnerability Assessment Model to calculate building vulnerability and estimate probable maximum loss (PML) associated with a 1:500 year tsunami flood. Almost US$0.5 billion worth of buildings would be inundated, 95% of single story residential and 23% of commercial buildings would be destroyed with PML’s exceeding US$0.5 billion worth of buildings would be inundated, 95% of single story residential and 23% of commercial buildings would be destroyed with PML’s exceeding US116 million. These figures only represent a tiny fraction of the total values of exposed assets and loss that would be associated with a Cascadia tsunami impacting the NW Pacific coast. Not withstanding the various issues associated with our approach, this study represents the first time that PML’s have ever been calculated for a Cascadia type tsunami, and these results have serious implications for tsunami disaster risk management in the region. This method has the potential to be rolled out across the United States and elsewhere for estimating building vulnerability and loss to tsunami.     

In a PICL: The sedimentary deposits and facies of perennially ice‐covered lakes

Perennially ice‐covered lakes can have significantly different facies than open‐water lakes because sediment is transported onto the ice, where it accumulates, and sand grains preferentially melt through to be deposited on the lake floor. To characterize the facies in these lakes, sedimentary deposits from five Antarctic perennially ice‐covered lakes were described using lake‐bottom observations, underwater video and images, and sediment cores. One lake was dominated by laminated microbial mats and mud (derived from an abutting glacier), with disseminated sand and rare gravel. The other four lakes were dominated by laminated microbial mats and moderately well to moderately sorted medium to very coarse sand with sparse granules and pebbles; they contained minor interstitial or laminated mud (derived from streams and abutting glaciers). The sand was disseminated or localized in mounds and 1 m to more than 10 m long elongate ridges. Mounds were centimetres to metres in diameter; conical, elongate or round in shape; and isolated or deposited near or on top of one another. Sand layers in the mounds had normal, inverse, or no grading. Nine mixed mud and sand facies were defined for perennially ice‐covered lakes based on the relative proportion of mud to sand and the style of sand deposition. While perennially ice‐covered lake facies overlap with other ice‐influenced lakes and glaciomarine facies, they are characterized by a paucity of grains coarser than granules, a narrow range in sand grain sizes, and inverse grading in the sand mounds. These facies can be used to infer changes in ice cover through time and to identify perennially ice‐covered lakes in the rock record. Ancient perennially ice‐covered lakes are expected on Earth and Mars, and their characterization will provide new insights into past climatic conditions and habitability.     

Turbulence Structure Within and Above a Canopy of Bluff Elements

Measurements of turbulence structure in a wind-tunnel model canopy of bluff elements show many of the features associated with vegetation canopies and roughness sublayers but also display features more characteristic of the inertial sublayer (ISL). Points of similarity include the existence of an inflexion point in the space-time averaged streamwise velocity at the canopy top, the variation with height of turbulent second moments and the departure of the turbulent kinetic energy budget from local equilibrium in and just above the canopy. Quadrant analysis shows characteristic dominance of sweep over ejection events within the canopy although sweeps are more frequent than usually seen in vegetation canopies. Points of difference are a u′, w′ correlation coefficient that is closer to the ISL value than to most canopy data, and a turbulent Prandtl number midway between canopy and ISL values. Within the canopy there is distinct spatial partitioning into two flow regimes, the wake and non-wake regions. Both time-mean and conditional statistics take different values in these different regions of the canopy flow. We explain many of these features by appealing to a modified version of the mixing-layer hypothesis that links the dominant turbulent eddies to the instability of the inflexion point at canopy top. However, it is evident that these eddies are perturbed by the quasi-coherent wakes of the bluff canopy elements. Based upon an equation for the instantaneous velocity perturbation, we propose a criterion for deciding when the eddies linked to the inflexion point will dominate flow structure and when that structure will be replaced by an array of superimposed element wakes. In particular, we show that the resemblance of some features of the flow to the ISL does not mean that ISL dynamics operate within bluff-body canopies in any sense.     

Role of advection and penetrative convection in affecting the mixing-height variations over an idealized metropolitan area

This study deals with the variability of mixing height during daylight hours in the summer months for weak wind regimes. A two-dimensional model was employed using simulated input variables which are quite representative of conditions found over the midwestern United States in late summer and early fall. With the aid of this model and various analytical techniques, the dependence of the urban mixing height on such factors as horizontal advection, downward heat flux across the stable mixing-layer interface, lapse rate in the stable layer, etc., was delineated and compared with actual mixing height variations observed in St. Louis, Missouri during selected days for August, 1972.The experiment indicated the following: (1) A spatially symmetric surface heating profile over a city is accompanied by a similarly symmetric mixing-height profile in the absence of vertical wind shear; (2) When the same heating assumption is invoked and vertically variable wind profiles are introduced, the model-generated mixing-height contours become increasingly asymmetric with vertical wind shear; (3) The modelled mixing heights are more sensitive to temperature fluctuations than to those of wind over the range of speeds studied (wind speeds 4ms^–1); (4) Present operational methods of predicting the time of erosion of an inversion (based upon forecast surface temperature ranges and adiabatic diagram considerations) underestimate breakup time by a factor which is proportional to the amount of available downward heat flux from the stable layer into the mixed layer below.     

Validating a Tsunami Vulnerability Assessment Model (the PTVA Model) Using Field Data from the 2004 Indian Ocean Tsunami

The “PTVAM” tsunami vulnerability assessment model [Papathoma and Dominey-Howes: 2003, Nat. Hazards Earth Syst. Sci. 3, 733–744; Papathoma et al.: 2003, Nat. Hazards Earth Syst. Sci. 3, 377–389], like all models, requires validation. We use the results from post-tsunami surveys in the Maldives following the December 26, 2004 Indian Ocean tsunami to ‘evaluate’ the appropriateness of the PTVAM attributes to understanding spatial and temporal vulnerability to tsunami damage and loss. We find that some of the PTVAM attributes are significantly important and others moderately important to understanding and assessing vulnerability. Some attributes require further investigation. Based upon the ground-truth data, we make several modifications to the model framework and propose a revised version of the PTVAM (PTVAM 2).     

Iron isotope variations in Holocene sediments of the Gotland Deep, Baltic Sea

Holocene sediments from the Gotland Deep basin in the Baltic Sea were investigated for their Fe isotopic composition in order to assess the impact of changes in redox conditions and a transition from freshwater to brackish water on the isotope signature of iron. The sediments display variations in δ⁵⁶Fe (differences in the ⁵⁶Fe/⁵⁴Fe ratio relative to the IRMM-14 standard) from −0.27 ± 0.09‰ to +0.21 ± 0.08‰. Samples deposited in a mainly limnic environment with oxygenated bottom water have a mean δ⁵⁶Fe of +0.08 ± 0.13‰, which is identical to the mean Fe isotopic composition of igneous rocks and oxic marine sediments. In contrast, sediments that formed in brackish water under periodically euxinic conditions display significantly lighter Fe isotope signatures with a mean δ⁵⁶Fe of −0.14 ± 0.19‰. Negative correlations of the δ⁵⁶Fe values with the Fe/Al ratio and S content of the samples suggest that the isotopically light Fe in the periodically euxinic samples is associated with reactive Fe enrichments and sulfides. This is supported by analyses of pyrite separates from this unit that have a mean Fe isotopic composition of −1.06 ± 0.20‰ for δ⁵⁶Fe. The supply of additional Fe with a light Fe isotopic signature can be explained with the shelf to basin Fe shuttle model. According to the Fe shuttle model, oxides and benthic ferrous Fe that is derived from dissimilatory iron reduction from shelves is transported and accumulated in euxinic basins. The data furthermore suggest that the euxinic water has a negative dissolved δ⁵⁶Fe value of about −1.4‰ to −0.9‰. If negative Fe isotopic signatures are characteristic for euxinic sediment formation, widespread euxinia in the past might have shifted the Fe isotopic composition of dissolved Fe in the ocean towards more positive δ⁵⁶Fe values.