Measuring ignitability for in situ burning of oil spills weathered under Arctic conditions: from laboratory studies to large-scale field experiments

This paper compares the ignitability of Troll B crude oil weathered under simulated Arctic conditions (0%, 50% and 90% ice cover). The experiments were performed in different scales at SINTEF’s laboratories in Trondheim, field research station on Svalbard and in broken ice (70-90% ice cover) in the Barents Sea. Samples from the weathering experiments were tested for ignitability using the same laboratory burning cell. The measured ignitability from the experiments in these different scales showed a good agreement for samples with similar weathering. The ice conditions clearly affected the weathering process, and 70% ice or more reduces the weathering and allows a longer time window for in situ burning. The results from the Barents Sea revealed that weathering and ignitability can vary within an oil slick. This field use of the burning cell demonstrated that it can be used as an operational tool to monitor the ignitability of oil spills.     

Opal‐A in the Nakhla meteorite: A tracer of ephemeral liquid water in the Amazonian crust of Mars

The nakhlite meteorites are clinopyroxenites that are derived from a ~1300 million year old sill or lava flow on Mars. Most members of the group contain veins of iddingsite whose main component is a fine‐grained and hydrous Fe‐ and Mg‐rich silicate. Siderite is present in the majority of veins, where it straddles or cross‐cuts the Fe‐Mg silicate. This carbonate also contains patches of ferric (oxy)hydroxide. Despite 40 years of investigation, the mineralogy and origins of the Fe‐Mg silicate is poorly understood, as is the paragenesis of the iddingsite veins. Nanometer‐scale analysis of Fe‐Mg silicate in the Nakhla meteorite by electron and X‐ray imaging and spectroscopy reveals that its principal constituents are nanoparticles of opal‐A. This hydrous and amorphous phase precipitated from acidic solutions that had become supersaturated with respect to silica by dissolution of olivine. Each opal‐A nanoparticle is enclosed within a ferrihydrite shell that formed by oxidation of iron that had also been liberated from the olivine. Siderite crystallized subsequently and from solutions that were alkaline and reducing, and replaced both the nanoparticles and olivine. The fluids that formed both the opal‐A/ferrihydrite and the siderite were sourced from one or more reservoirs in contact with the Martian atmosphere. The last event recorded by the veins was alteration of the carbonate to a ferric (oxy)hydroxide that probably took place on Mars, although a terrestrial origin remains possible. These results support findings from orbiter‐ and rover‐based spectroscopy that opaline silica was a common product of aqueous alteration of the Martian crust.     

U–Pb TIMS age constraints on the evolution of the Neoproterozoic Meatiq Gneiss Dome,Eastern Desert,Egypt

Ages are used to constrain the temporal evolution of the Meatiq Gneiss Dome, Eastern Desert, Egypt, by dating (ID-TIMS) pre-, syn-, and post-tectonic igneous rocks in and around the dome. The Um Ba’anib Orthogneiss, comprising the deepest exposed structural levels of the dome, has a crystallization age of 630.8 ± 2 Ma. The overlying mylonites are interpreted to be a thrust sheet/complex (Abu Fannani Thrust Sheet) of highly mylonitized metasediments (?), migmatitic amphibolites, and orthogneisses with large and small tectonic lenses of less-deformed intrusives. Two syn-tectonic diorite lenses in this complex have crystallization ages of 609.0 ± 1.0 and 605.8 ± 0.9 Ma, respectively. The syn-tectonic Abu Ziran diorite, cutting across the tectonic contact between mylonite gneisses of the Abu Fannani Thrust Sheet and a structurally overlying thrust sheet of eugeoclinal rocks (“Pan-African nappe”), has a magmatic emplacement age of 606.4 ± 1.0 Ma. Zircons from a gabbro (Fawakhir ophiolite) within the eugeoclinal thrust sheet yielded a crystallization age of 736.5 ± 1.2 Ma. The post-tectonic Fawakhir monzodiorite intrudes the ophiolitic rocks and has an emplacement age of 597.8 ± 2.9 Ma. Two other post-tectonic granites, the Arieki granite that intrudes the foliated Um Ba’anib Orthogneiss, and the Um Had granite that cuts the deformed Hammamat sediments, have emplacement ages of 590 ± 3.1 and 596.3 ± 1.7 Ma, respectively. We consider formation of the Meatiq Gneiss Dome to be a young structural feature (<631 Ma), and our preferred tectonic interpretation is that it formed as a result of NE–SW shortening contemporaneous with folding of the nearby Hammamat sediments around 605–600 Ma, during oblique collision of East and West Gondwana.     

Mafic plutonic rocks in a continental‐arc setting: geochemistry of 1.87–1.78 Ga rocks from south‐central Sweden and models of their palaeotectonic setting

Mafic intrusive rocks (1.79–1.78 Ga) of the Transscandinavian Igneous Belt (TIB) and the c. 1.87 Ga Hedesunda Igneous Complex in the Fennoscandian Shield of south‐central Sweden were studied using whole‐rock and isotope geochemistry. Rock types vary from gabbros/norites (and leucogabbros) to quartz diorites, with Mg# between 76 and 49, and wt% SiO₂ between 43.6 and 59.7, indicating some variation in evolutionary levels and variable cumulus components. Geochemical signatures are calc‐alkaline to shoshonitic, large ion lithophile elements and light rare earth elements enriched and high‐field strength elements depleted of continental‐arc type. ε_Nd(t) ranges between +1.0 and +2.7, and ⁸⁷Sr/⁸⁶Sr(t) between 0.7020 and 0.7038. There is no systematic correlation between chemical parameters and isotope ratios. These isotopic data overlap with other mafic plutonic TIB rocks; samples from the Dala Province (DP) tend to overlap with the c. 1.7 Ga basic Dala lavas of TIB at slightly elevated relative Sr/Nd ratios. With two exceptions, the ε_Nd(t) of +1 to +2 conform to an isotopically ‘mildly depleted’ source, typical for mafic TIB rocks and many Svecofennian rocks in the region. Reported values above ε_Nd(t) +2.0 are scarce in the TIB. Mantle sources represent depleted mantle wedge material that was enriched by fluids/melts not long before (T_DM c. 2.0 Ga), that is during subduction in the preceding Svecofennian (2.0–1.87 Ga) and/or during the TIB‐0&1 event (1.85–1.78 Ga). The palaeotectonic settings inferred are active continental margins; N–S‐directed convergence at 1.87 Ga and E–W‐directed at 1.79–1.78 Ga. Copyright © 2008 John Wiley & Sons, Ltd.     

National forest carbon inventories: policy needs and assessment capacity

Previous research has identified the importance of the role of land cover in the global carbon cycle. In particular, forests have been identified as a significant carbon sink that can mitigate the rate of global climate change. Policy makers are faced with complex and difficult challenges in getting timely and useful information in monitoring global forest resources. Recent advances in the tools and methods of forest carbon accounting have produced new, innovative approaches to forest-based carbon inventories. But it is important as new tools are developed that scientists understand the needs of policy makers and that policy makers understand the capabilities and limitations of forest inventory methods. This paper explores four different policy applications that rely, or could benefit from, national carbon inventories. The goal is to help build a bridge between the communities of climate policy makers and scientists specialized in forest carbon inventories. To this end, we pursue three specific objectives: First we provide an overview for policy makers about approaches to forest carbon inventories, paying particular attention to the contributions of remote sensing technologies. Second, we outline the issues particularly relevant to forest inventory scientists who are interested in responding to public policy needs. We then discuss the tradeoffs between information cost, accuracy, precision, transparency and timeliness that need to be balanced in long-term monitoring of forest carbon. Finally, the article concludes with a series of observations and recommendations for the implementation of forest carbon inventories as increasingly central components of global climate change policy.     

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)

Detections and upper limits to the continuum emission (1 ≤ λ ≤6 cm) and spectral line emission (OH, CO, CS, HCN, HCO⁺, CN, CH₃CN, CH₃C₂H, NH₃, H₂O, HC₃N, CH₃CH₂CN) are reported from radio observations of Comets 1983d and 1983e. Comparison is made with observations of CN at optical wavelengths. These results may be useful in planning future cometary observations.     

Coastal Ocean Last Glacial Maximum to 2100 CO2-Carbonic Acid-Carbonate System: A Modeling Approach

Using coupled terrestrial and coastal zone models, we investigated the impacts of deglaciation and anthropogenic inputs on the CO₂–H₂O–CaCO₃ system in global coastal ocean waters from the Last Glacial Maximum (LGM: 18,000 year BP) to the year 2100. With rising sea level and atmospheric CO₂, the carbonate system of coastal ocean water changed significantly. We find that 6 × 10¹² metric tons of carbon were emitted from the coastal ocean, growing due to the sea level rise, from the LGM to late preindustrial time (1700 AD) because of net heterotrophy and calcification processes. This carbon came to reside in the atmosphere and in the growing vegetation on land and in uptake of atmospheric CO₂ through the weathering of rocks on land. It appears that carbonate accumulation, mainly, but not exclusively, in coral reefs from the LGM to late preindustrial time could account for about 24 ppmv of the 100 ppmv rise in atmospheric CO₂, lending some support to the “coral reef hypothesis”. In addition, the global coastal ocean is now, or soon will be, a sink of atmospheric CO₂. The temperature rise of 4–5°C since the LGM led to increased weathering rates of inorganic and organic materials on land and enhanced riverine fluxes of total C, N, and P to the coastal ocean of 68%, 108%, and 97%, respectively, from the LGM to late preindustrial time. During the Anthropocene, these trends have been exacerbated owing to rising atmospheric CO₂, due to fossil fuel combustion and land-use practices, other human activities, and rising global temperatures. River fluxes of total reactive C, N, and P are projected to increase from late preindustrial time to the year 2100 by 150%, 380%, and 257%, respectively, modifying significantly the behavior of these element cycles in the coastal ocean, particularly in proximal environments. Despite the fact that the global shoal water carbonate mass has grown extensively since the LGM, the pH_T (pH values on the total proton scale) of global coastal waters has decreased from ~8.35 to ~8.18 and the carbonate ion concentration declined by ~19% from the LGM to late preindustrial time. The latter represents a rate of decline of about 0.028 μmol CO₃ ^2? per decade. In comparison, the decrease in coastal water pH_T from the year 1900 to 2000 was about 8.18–8.08 and is projected to decrease further from about 8.08 to 7.85 between 2000 and 2100, according to the IS92a business-as-usual scenario of CO₂ emissions. Over these 200 years, the carbonate ion concentration will fall by ~120 μmol kg^?1 or 6 μmol kg^?1 per decade. This decadal rate of decline of the carbonate ion concentration in the Anthropocene is 214 times the average rate of decline for the entire Holocene. Hence, when viewed against the millennial to several millennial timescale of geologic change in the coastal ocean marine carbon system, one can easily appreciate why ocean acidification is the “other CO₂ problem”.     

Using the pseudospectral method on curved grids for 2D elastic forward modelling1

When applying the conventional Fourier pseudospectral method (FSM) on a Cartesian grid that has a sufficient size to propagate a pulse, spurious diffractions from the staircase representation of the curved interfaces appear in the wavefield. It is demonstrated that these non-physical diffractions can be eliminated by using curved grids that conform to all the interfaces of the subsurface. Methods for solving the 2D acoustic wave equation using such curved grids have been published previously by the authors. Here the extensions to the full 2D elastic wave equations are presented. The curved grids are generated by using the so-called multiblock strategy which is a well-known concept in computational fluid dynamics. In principle the sub-surface is divided into a number of contiguous subdomains. A separate grid is generated for each subdomain patching the grid lines across domain boundaries to obtain a globally continuous grid. Using this approach, even configurations with pinch outs can be handled. The curved grid is taken to constitute a generalized curvilinear coordinate system. Thus, the elastic equations have to be written in a curvilinear frame before applying the numerical scheme. The method implies that twice the number of spatial derivatives have to be evaluated compared to the conventional FSM on a Cartesian grid. However, it is demonstrated that the extra terms are more than compensated for by the fewer grid points needed in the curved approach.     

PCBs and chlorinated pesticides in the atmosphere and aquatic organisms of Ross Island, Antarctica

PCBs, p,p′-DDT, p,p′-DDE and lindane (γ-hexachlorocyclohexane) were monitored in the lower atmosphere of Ross Island, in Antarctica for 2 yr. Geometrical means were 15.2 pg m⁻³ for PCBs, 2.0 pg m⁻³ for p,p′-DDT, 1.0 pg m⁻³ for p,p′-DDE and 25.8 pg m⁻³ for lindane. Atmospheric levels of lindane were positively correlated with temperature, and a significant difference was found between spring-summer and summer-winter concentrations. No season related differences were found for the other chlorinated hydrocarbons, possibly owing to their lower vapour pressure and the cold climate. Periods with increased atmospheric levels of PCBs and DDT compounds were recorded. Lindane, p,p′-DDE and PCBs were present in fish and zooplankton sampled close to Ross Island. Pollutant levels in the zooplankton (on an extractable fat basis) were highest during the Antarctic spring and autumn and were inversely correlated to their fat content.