Point defects and pre-dose requirements for sensitization of the 300°C TL peak in natural quartz

This paper discusses the structural features required to stimulate a strong thermoluminescence (TL) glow peak near 300°C in clear natural quartz. For that reason, fresh TL data taken from several specimens prepared from five single crystals with known impurity content are shown. The TL emission was measured with a test dose of 10 mGy of γ-rays in the readout intervals 50–160 and 160–320°C. The readings were carried out prior and after the administration of a pre-dose of 175 kGy of γ-rays followed by heat-treatments at 400°C. For each single specimen, the OH content and the population of inclusions were evaluated by infrared spectroscopy and optical microscopy, respectively. The darkening induced by high γ dose was evaluated by optical spectroscopy. It was observed that the absorption at 475 nm and TL responses decrease with increase of the OH. It was shown that both smoky darkening and TL signals were better explained in terms of Li/Al and Li/OH content ratios rather than the absolute values of aluminum and alkali concentrations. The sensitization with high γ dose and heating is essential to create and stabilize a class of defects sites with Li⁺ ions dislodged from [AlO₄/Li]⁰ and Li-dependent OH centers. It is suggested that the defect sites formed with Li⁺ act as electron traps during test dose irradiation, whereas electron-hole recombination occurs essentially at [AlO₄]⁰ centers during the TL output near 300°C.     

A geochemical approach to distinguishing competing tectono-magmatic processes preserved in small eruptive centres

Small eruptive centres (SECs) representing short-lived, isolated eruptions are effective samples of mantle heterogeneity over a given area, as they are generally of basaltic composition and show evidence of little magmatic processing. This is particularly powerful in volcanic arcs where the original melting process generating stratovolcanoes is often obscured by additions from the down-going slab (fluids and sediments) and the overlying crust. The Pucón area of southern Chile contains active and dormant stratovolcanoes, Holocene, basaltic SECs and an arc-scale strike-slip fault (the Liquiñe Ofqui Fault System: LOFS). The SECs show unexpected compositional heterogeneity considering their spatial proximity. We present a detailed study of these SECs combining whole rock major and trace element concentrations, U-Th isotopes and olivine-hosted melt inclusion major element and volatile contents to highlight the complex inter-relations in this small but active area. We show that heterogeneity preserved at individual SECs relates to different processes: some start in the melting region with the input of slab-derived fluids, whilst others occur later in a centre’s magmatic history with the influence of crustal contamination prior to olivine crystallisation. These signals are deduced through the combination of the different geochemical tools used in this study. We show that there is no correlation between composition and distance from the arc front, whilst the local tectonic regime has an effect on melt composition: SECs aligned along the LOFS have either equilibrium U-Th ratios or small Th-excesses instead of the large—fluid influenced—U-excesses displayed by SECs situated away from this feature. One of the SECs is modelled as being generated from fluid-enriched depleted mantle, a source which it may share with the stratovolcano Villarrica, whilst another SEC with abundant evidence of crustal contamination may share its plumbing system with its neighbouring stratovolcano Quetrupillán, showing that polygenetic–monogenetic connections are unpredictable. Such marked preservation of individual magmatic histories highlights the isolation of individual melting events even in complex and highly volcanically active areas.     

Combined hydrochemical,isotopic, and multivariate statistics techniques to assess the effects of discharges from a uranium mine on water quality in neighboring streams

The Caldas Uranium Mine (CUM), located on the Poços de Caldas Plateau in the southeastern region of Brazil, is presently undergoing a decommissioning process. The aim of the present investigation is to identify and characterize the effects of acid mine drainage (AMD) originating from the CUM on surface water quality. To achieve these aims, sampling stations were located at two AMD sources: the retention pond at the foot of waste rock pile#4 (WRP#4) and the settling pond that receives effluents from the tailings dam (TD). Ten additional sampling stations were located along watercourses in the vicinity, both downstream and upstream of the mine. Sampling was performed during the rainy and dry seasons in 2010 and 2011. The water analysis detected significant changes in pH, electrical conductivity, F^?, Cd, U, Zn, Al, Mn, As, Ca, SO₄ ^2?, Pb, ²³⁸U, ²²⁶Ra, ²¹⁰Pb, ²³²Th, ²²⁸Ra, and Mo in waters downstream of both pond discharge sites. It was demonstrated that the disequilibrium between ²²⁶Ra and ²³⁸U can be used to trace the extent of AMD impacts in nearby streams. Variations in ¹⁸O and ²H enabled the flow of mining-impacted water to be traced from the ponds to nearby streams. Multivariate analysis yielded a three-factor model: Factor 1 was interpreted as being associated with AMD (from WRP#4) and Factor 2 with a Ca–Mo relationship associated with the chemical constitution of the ore and with the treatment of tailings wastes in the area (from TD); Factor 3 was interpreted as being associated with the natural influence of geogenic processes on water quality in the area. The results of this study provide a scientific basis for recommending appropriate remedial actions during mine decommissioning.     

The role of the Río de la Plata bottom salinity front in accumulating debris

The Río de la Plata, one of the most important South American estuarine environments, is characterized by a bottom salinity front that generates an ecotone between the river and the estuary. Based on bottom trawls and costal sampling we describe the distribution, types, and amount of debris found in the bottom and shoreline across this front. Plastics and plastic bags were the main debris types in both areas. Concentrations of total debris upriver the front were always significantly higher than downriver the front showing that the front acts as a barrier accumulating debris. Moreover, a large part of debris end ups accumulated in the coastal area upriver the frontal position. This area is particularly sensitive because the coastline encompasses an UNESCO Man and the Biosphere Reserve and a Ramsar site, and due to the ecological significance of the front for many valuable species.     

Volume 49

Volume Contents

Volume 49     

Temporal variability of throughfall as a function of the canopy development stage: from seasonal to intra-event scale

ABSTRACT

The interception process impacts rainfall magnitude and intensity under the canopy. In this study, the effect of plant interception on throughfall characteristics was assessed in the deciduous Caatinga vegetation, at different canopy development stages and for temporal scales ranging from seasonal to the intra-event scale. Throughfall and stemflow percentages were slightly higher at the onset of the rainy season, when leaf area density is low, with resulting lower interception losses. However, there was no statistical difference among the variables at the seasonal scale. At the intra-event scale, average and maximum throughfall intensity at different time intervals showed statistical difference between the stages of canopy development. Regardless of leaf area density and rainfall depth, vegetation is able to retain all the water up to 2 min in the beginning of each rainfall event with accumulated rainfall smaller than 0.6 mm. Furthermore, the Caatinga vegetation attenuates the rainfall intensity by 30–40%.     

Post-fire management effects on sediment (dis)connectivity in Mediterranean forest ecosystems: Channel and catchment response

Forest fires and post-fire practices influence sediment connectivity (SC). In this study, we use the ‘aggregated index of connectivity’ (AIC) to assess SC in five Mediterranean catchments (198–1090 ha) affected by a wildfire in 2012 in south-eastern Spain. Two temporal scenarios were considered, immediately after the fire and before post-fire management, and 2 years after the fire including all practices (hillslope barriers, check-dams, afforestation, salvage logging and skid trails). One LiDAR (light detection and ranging)-derived digital elevation model (DEM, 2 m × 2 m resolution) was generated, per scenario. The five catchment outlets were established as the computation target (AIC_OUT), and structural and functional SC were calculated. Index outputs were normalized to make the results of the non-nested catchments comparable (AIC_N-OUT). The output analysis includes the SC distribution along the catchments and at local scale (929 sub-catchments, 677 in the burned area), the hillslope and channel measures' effect on SC, and a sedimentological analysis using observed area-specific sediment yield (SSY) at 10 new (built after post-fire practices) concrete check-dams located in the catchments (SSY = 1.94 Mg ha⁻¹ yr⁻¹; σ = 1.22). The catchments with more circular shapes and steeper slopes were those with higher AIC_N-OUT. The structural SC maps – removing the rainfall erosivity influence – allowed evaluating the actual role played by the post-fire practices that reduced SC ( $\overline{x}$= − 1.19%; σ = 0.41); while functional SC was linked to the actual change of SC ( $\overline{x}$= + 5.32%; σ = 0.62). Hillslope treatments resulted in significant changes on AIC_N-OUT at sub-catchment scale with certain disconnectivity. A good and positive correlation was found between the SSY and the changes of AIC_N-OUT. However, the coarse DEM resolution explained the lack of effect of the rock check-dams – located on the secondary channels – on AIC_N-OUT. AIC_N-OUT proved to be a useful tool for decision making in post-fire restoration, but an optimal input data is still necessary to refine calculations.