Dynamic response of road pavement resting on a layered poroelastic half‐space to a moving traffic load

This paper is dedicated to study the dynamic response of a thin‐plate resting on a layered poroelastic half‐space under a moving traffic load. Based on the dynamic poroelastic theory of Biot, the general solutions of the homogeneous poroelastic foundation are obtained by Fourier translation. By using the transmission and reflection matrices method in the frequency domain, the equivalent stiffness of the layered poroelastic half‐space is presented. Kirchhoff's hypotheses are applied to obtain the vertical displacement of the thin plate. By using the inverse Fourier transform, the time domain solution is obtained. As an example of three layers, the influences of the load velocity, the material properties of poroelastic layers, and the flexural rigidity of the plate on the response of the pavement system are examined. Analyses show that a soft intermediate layer results in the significant increase of vertical displacement of road pavement. Comparison with the existing work validates the present model. Copyright © 2013 John Wiley & Sons, Ltd.     

Analytical solution for transient groundwater flow during slug test in vertical cutoff walls

An analysis method for transient groundwater flow during slug tests performed in vertical cutoff walls is presented. The analytical solution for evaluating hydraulic conductivity of vertical cutoff walls is derived by applying the method of images to the previously developed analytical solution that is exclusively applicable to an infinite aquifer. Two distinct boundary conditions are considered to account for the configuration of the vertical cutoff wall: the wall‐soil formation interfaces with or without the existence of filter cakes, that is, constant‐head boundary and no‐flux boundary conditions. A series of type curves is constructed from the analytical solution and compared with those of a partially penetrated well within an aquifer. The constant‐head boundary condition provides faster hydraulic head recovery than the aquifer case. On the other hand, the no‐flux boundary condition leads to a delayed hydraulic head recovery. The greater the shape factor and well offset from the center of the cutoff wall, and the smaller the width of the cutoff wall, the greater the effect of the boundary condition observed in the type curves. This result shows the significance of considering proper boundary conditions at the vertical cutoff wall in analyzing slug tests. Copyright © 2014 John Wiley & Sons, Ltd.     

Raman spectroscopy of olivine in dunite experimentally shocked to pressures between 5 and 59 GPa

Abstract— Previous Raman investigations on experimentally shocked ingle‐crystal olivine indicated that the olivine Raman bands seemingly shift to a higher wave number with increasing shock pressure. If this effect could be confirmed, Raman analysis of natural shock‐metamorphosed minerals could potentially provide an important shock barometric tool. We carried out a Raman spectroscopic study on olivine in a series of natural dunite samples experimentally shocked to pressures between 5 and 59 GPa. In addition, we analyzed olivine grains in a sample of the Cold Bokkeveld C1 meteorite. We studied samples of several dunites with olivine of 90.64–92.00 mole% Fo to determine Raman effects in the region from 200 to 900 cm^?1. Several olivine grains per sample/shock pressure stage were analyzed. Raman analysis, however, showed little or no shift with increasing shock pressure. The shifts to higher or lower frequencies observed were not specific for a given pressure stage, with some grains within a sample showing more shift than others. This finding is unrelated to the crystallographic orientation of analyzed grains and cannot be related systematically to the different degrees of optically determined shock metamorphism of the analyzed grains. We identified an increase in full width at half maximum (FWHM) for the 824 cm^?1 band with increased shock pressure in the shocked Åheim samples above 45 GPa and, to a lesser extent, for the 856 cm^?1 band. Evaluation of band broadening of olivine in the Cold Bokkeveld meteorite showed FWHM values that were much greater (9–20 cm^?1) than those of olivine in the shocked dunite samples (7–12 cm^?1). We concluded that these differences in FWHM are due to differences in chemical composition between the meteoritic and the experimentally shocked olivine. Therefore, using Raman spectroscopy to detect small shifts in wave numbers to higher frequencies with increased shock pressure does not yield consistent effects for polycrystalline dunite. An extra band at 650 cm^?1 was identified in the Raman spectra of the unshocked Mooihoek dunite and the Åheim dunite samples shocked to 5, 29.3, and 59 GPa, as well as another at 696 cm^?1 in all the spectra of the 59 GPa Åheim sample. The cause of these extra bands is not known. Comparison of these results with Raman spectra of olivine from the Cold Bokkeveld C1 meteorite did not allow us to determine shock pressures for the meteoritic olivine.     

Sulfide mineralogy and redox conditions in some shergottites

Abstract— Magmatic sulfide mineralogy has been studied in 2 olivine‐phyric shergottites (DaG 476 and SaU 005) and 4 basaltic shergottites (Zagami, Shergotty, Los Angeles, and NWA 480). Modal abundances of magmatic sulfides, as estimated by image analysis on thin section, are high (0.16 to 0.53 area percent) and correlate positively with abundances of Fe‐Ti oxides. Sulfides are mesostasis minerals, being mostly interstitial grains or locally enclosed in post‐cumulus melt inclusions (e.g., SaU 005) in olivine. Sulfides in shergottites are composed of major pyrrhotite containing pentlandite exsolutions associated with minor amounts of Cu sulfides (chalcopyrite and/or cubanite). Hot desert finds (e.g., DaG 476) show abundant fracture‐filling iron (oxy)hydroxides of probable terrestrial origin. Unaltered sulfides show metal‐rich hexagonal pyrrhotite compositions with metal/sulfur (M/S) ratio ranging between 0.936 ± 0.005 and 0.962 ± 0.01. This compositional range corresponds to the two‐phase structural domain 2C + nC of the Fe‐S system; however, the high‐temperature disordered hexagonal 1C pyrrhotite structure would be in better agreement with magnetic properties of shergottites. Ni contents in pyrrhotite increase from Los Angeles (<0.05 at%) to Shergotty, Zagami, and NWA 480 (0.2–0.5 at%), and DaG 476 and SaU 005 (up to 3 at%). The higher Ni values of pyrrhotite in olivine‐phyric shergottites correlate with the abundance of pentlandite exsolutions, both reflecting more primitive Ni‐rich sulfide liquids where abundant olivine crystallized. This result and the strong correlation between sulfide abundances and Fe‐Ti oxides argue for a primary magmatic origin of these sulfides. Although they reproduce the trend of magmatic oxygen fugacity conditions determined from Fe‐Ti oxide pairs, observed pyrrhotite compositions are systematically more metal‐deficient compared to those calculated from the Fe‐S‐O system. This suggests post‐magmatic oxidation during cooling on Mars, followed by terrestrial weathering for hot desert finds.     

Weathering of meteorites from Oman: Correlation of chemical and mineralogical weathering proxies with 14C terrestrial ages and the influence of soil chemistry

Abstract— Fifty‐four fragments of ordinary chondrites from 50 finds representing all searched areas in central Oman and all weathering stages were selected to compare the physical, chemical, and mineralogical effect of terrestrial weathering with ¹⁴C terrestrial ages. ¹⁴C ages range from 2.0 to >49 kyr with a median value of 17.9 kyr. The peak of the age range, which is between 10–20 kyr, falls in an arid climate period. A comparison of the chemical composition of Omani chondrites with literature data for unweathered H and L chondrites demonstrates a strong enrichment in Sr and Ba, and depletion in S during weathering. Water contents in H chondrites increase with terrestrial age, whereas L chondrites show a rapid initial increase followed by nearly constant water content. Correlating Sr, Ba, and H₂O with age indicates two absorption trends: i) an initial alteration within the first 20 kyr dominated by H₂O uptake, mainly reflecting Fe‐Ni metal alteration, and ii) a second Ba‐and Sr‐dominated stage correlated with slower and less systematic weathering of troilite that starts after H₂O reaches ?2 wt%. Sulfur released from troilite partly combines with Ba and Sr to form sulfate minerals. Other parameters correlated with ¹⁴C age are degree of weathering, color of powdered meteorites, and the Ni/Fe ratio. Chemical analyses of 145 soils show a high degree of homogeneity over the entire interior Oman Desert, indicating large‐scale mixing by wind. Soil samples collected from beneath meteorite finds typically are enriched in Ni and Co, confirming mobilization from the meteorites. High Cr and Ni concentrations in reference soil samples, which decrease from NE to SW, are due to detrital material from ultramafic rocks of the Oman Mountains.     

Sedimentary provenance in the central Ribeira belt based on laser-ablation ICPMSPb/Pb zircon ages

²⁰⁷Pb/²⁰⁶Pb ages from 420 zircons from 9 upper amphibolite and granulite facies quartzites of the post-1.8 Ga metasedimentary cover from the Occidental and Oriental terranes from the Neoproterozoic central Ribeira belt, in eastern Brazil, are discussed. Ages from the Occidental terrane show that Proterozoic ages predominate with a modal class at 2.1–2.2 Ga and that Archean ages are less common and lie within the 2.5–3.6 Ga range. A wider dispersion on Proterozoic ages down to 1.1 Ga and youngest Neoproterozoic ages (550–700 Ma) were also observed and could be related to the Brasiliano/PanAfrican metamorphic events. The data show that detrital sediments of the Occidental terrane were derived predominantly from erosion of a 1.8–2.2 Ga Paleoproterozoic terrane with a small proportion of a 2.6–3.6 Ga Archean crust. Ages from the Oriental terrane are greatly dispersed, but show a significant proportion of ages between 1.7 and 2.1 Ga, although the great majority are between 0.5 and 1.6 Ga. Only 3 out of 144 grains yield Archean ages, between 2.5 and 2.9 Ga. Based on the greatest errors observed on the data from the Oriental Terrane (100–300 Ma), and a continuum of obtained ages between 2072 Ma (Paleoproterozoic) and 517 Ma (Cambrian), the more plausible interpretation is that the dispersion of ages results from partial resetting of the U–Pb system by Brasiliano metamorphism in Proterozoic–Archean zircons, although a Mesoproterozoic source could not be discarded.     

The Gash Breccias of the Pembroke Peninsula,SW Wales

The thickest development of Carboniferous Limestone in Great Britain (about 1200 m) is in the Pembroke Peninsula of SW Wales. In various places, the regularity of the normally well‐stratified limestone is broken by zones of disturbance, which are spectacularly displayed in magnificent near‐vertical cliff sections. The zones generally occupy the whole of the 50 m‐high cliffs and are up to 300 m wide. The chief component of these zones is a chaotic, clast‐supported breccia, composed of angular limestone fragments welded together with varying degrees of firmness by sparry calcite veining or a normally sparse, red‐pink sandy or silty matrix. The breccias are very easy to distinguish and form a striking contrast to the grey cliff scenery hereabouts ( Figs 1, 2 ), yet they have not been discussed much—until now.

Figure 1 Open in figure viewer PowerPoint Location map, showing localities mentioned in the text, the outcrop of the Carboniferous Limestone, the chief synclinal axes and the distribution envelope of the Gash Breccias (after Thomas 1971 ). 1. Flimston Bay; 2. Bullslaughter Bay (west); 3. Bullslaughter bay (east); 4. Trevallen; 5. Box Bay; 6. Draught; 7. Whitesheet Rock; 8. Lydstep Point; 9. St Margaret's Point; 10. Den Point; 11. Valleyfield Top; 12. Pembroke Castle.     

A genetic classification of sinkholes illustrated from evaporite paleokarst exposures in Spain

This contribution analyses the processes involved in the generation of sinkholes from the study of paleokarst features exposed in four Spanish Tertiary basins. Bedrock strata are subhorizontal evaporites, and in three of the basins they include halite and glauberite in the subsurface. Our studies suggest that formation of dolines in these areas results from a wider range of subsidence processes than those included in the most recently published sinkhole classifications; a new genetic classification of sinkholes applicable to both carbonate and evaporite karst areas is thus proposed. With the exception of solution dolines, it defines the main sinkhole types by use of two terms that refer to the material affected by downward gravitational movements (cover, bedrock or caprock) and the main type of process involved (collapse, suffosion or sagging). Sinkholes that result from the combination of several subsidence processes and affect more than one type of material are described by combinations of the different terms with the dominant material or process followed by the secondary one (e.g. bedrock sagging and collapse sinkhole). The mechanism of collapse includes any brittle gravitational deformation of cover and bedrock material, such as upward stoping of cavities by roof failure, development of well-defined failure planes and rock brecciation. Suffosion is the downward migration of cover deposits through dissolutional conduits accompanied with ductile settling. Sagging is the ductile flexure of sediments caused by differential corrosional lowering of the rockhead or interstratal karstification of the soluble bedrock. The paleokarsts we analysed suggest that the sagging mechanism (not included in previous genetic classifications) plays an important role in the generation of sinkholes in evaporites. Moreover, collapse processes are more significant in extent and rate in areas underlain by evaporites than in carbonate karst, primarily due to the greater solubility of the evaporites and the lower mechanical strength and ductile rheology of gypsum and salt rocks.