Electrodialytic remediation of CCA-treated waste wood in pilot scale

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Testing accretion mechanisms of the H chondrite parent body utilizing nucleosynthetic anomalies

Planetary bodies a few hundred kilometers in radii are the precursors to larger planets but it is unclear whether these bodies themselves formed very rapidly or accreted slowly over several millions of years. Ordinary H chondrite meteorites provide an opportunity to investigate the accretion time scale of a small planetary body given that variable degrees of thermal metamorphism present in H chondrites provide a proxy for their stratigraphic depth and, therefore, relative accretion times. We exploit this feature to search for nucleosynthetic isotope variability of ⁵⁴Cr, which is a sensitive tracer of spatial and temporal variations in the protoplanetary disk's solids, between 17 H chondrites covering all petrologic types to obtain clues about the parent body accretionary rate. We find no systematic variability in the mass‐biased corrected abundances of ⁵³Cr or ⁵⁴Cr outside of the analytical uncertainties, suggesting very rapid accretion of the H chondrite parent body consistent with turbulent accretion. By utilizing the μ⁵⁴Cr–planetary mass relationship observed between inner solar system planetary bodies, we calculate that the H chondrite accretion occurred at 1.1 ± 0.4 or 1.8 ± 0.2 Myr after the formation of calcium‐aluminum‐rich inclusions (CAIs), assuming either the initial ²⁶Al/²⁷Al abundance of inner solar system solids determined from angrite meteorites or CAIs from CV chondrites, respectively. Notably, these ages are in agreement with age estimates based on the parent bodies’ thermal evolution when correcting these calculations to the same initial ²⁶Al/²⁷Al abundance, reinforcing the idea of a secular evolution in the isotopic composition of inner disk solids.     

Sulfide intrusion in the tropical seagrasses Thalassia testudinum and Syringodium filiforme

Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations.     

Mapping fisheries in the German exclusive economic zone with special reference to offshore Natura 2000 sites

Large intensity and diversity of human activities result in an increase in complexity in the utilization of space. This paper describes the fisheries and a method to map fishing efforts and catches of different fleets by combining vessel monitoring system (VMS) data and logbook data. The method makes it possible to explore the spatial and temporal variability of fishing and the potential impacts of proposed management measures on the fisheries. The method is proposed to be used in the development of management plans for marine protected areas such as Natura 2000 sites, designated to protect vulnerable habitats and species.     

U/Pb ages of ophiolites and arc-related plutons of the Norwegian Caledonides: implications for the development of Iapetus

U/Pb zircon ages are reported for four ophiolites and three crosscutting arc-related plutons from the Norwegian Caledonides. Plagiogranite differentiated from gabbro of the Karmøy ophiolite is dated at 493+7/-4 Ma whereas arc-related trondhjemite cutting this ophiolite crystallized at 485+/–2 Ma. A crosscutting clinopyroxene-phyric gabbro intrusion is dated at 470+9/–5 Ma by near concordant magmatic titanite (sphene) and discordant U-rich (2903–6677 ppm) zircon. Lower intercepts of 247+/–68 and 191+/–70 Ma defined by the plagiogranite and clinopyroxene-phyric gabbro best-fit lines may reflect a real low-T alteration/rift-related event.A plagiogranite differentiate of the Gullfjellet ophiolite complex is dated at 489+/–3 Ma and a crosscutting arc-related tonalite is 482+6/–4 Ma. Both of these ages overlap with those of the correlative rocks at Karmøy suggesting that they are parts of one ophiolitic terrane with a common history.Trondhjemite associated with the Leka ophiolite is dated at 497+/–2 Ma, indicating that supra-subduction zone magmatism there may be coeval with spreading which formed the Karmøy axis sequence.The U/Pb zircon ages of Norwegian ophiolites reported here, combined with ages of other Appalachian-Caledonian ophiolite complexes in Britain and Canada, indicate a narrow age range for the generation of at least two marginal basins in the Tremadoc-Arenig. Two spreading episodes documented at Karmøy are separated in time by intrusion of arc-related trondhjemite magmas at 485+/–2 Ma and may correlate with two separate spreading events documented in other ophiolites.The Solund/Stavfjorden ophiolite, at 443+/–3 Ma, is the only late Ordovician ophiolite yet documented in the entire Appalachian-Caledonian Orogen and it probably represents a small, short-lived marginal basin late in the history of the Iapetus Ocean. It is correlative with Caradocian ensialic marginal basin magmatism in Wales and the Trondheim region, and with tholeiitic gabbro-diorite plutons that intruded Newfoundland ophiolites in a tensional regime after emplacement of the ophiolites over the continental margin.     

Geology, magmatic affinity and geotectonic environment of some Caledonian ophiolites in Norway

Ophiolites within the Norwegian Caledonides were generated during at least two distinct periods, i.e. Tremadocian-Arenigian and Ashgillian. The older generation show a long-lived magmatic development (ca 500-470 Ma) with rocks that range from MORB, IAT, boninites, calc-alkaline to alkaline basalt in geochemical affinity. This development is compatible with generation in a subduction-influenced environment, and a plausible modern equivalent may be the ensimatic arc-basin evolution in the western Pacific.The metabasalts of the younger (Ashgill, 443±3 Ma) ophiolite occurrence are characterized by a dominance of N- to E-MORB compositions with subduction zone influence. The volvanics of the complex are intercalated with, and overlain by, continentally-derived sediments. Calc-alkaline as well as alkaline lavas and volcanic-lastics apparantly define late magmatic products. Associated with the youngest ophiolite is a sedimentary melange with olistoliths of mature island arc-derived volcanics, as well as clasts with MORB-IAT affinity, chert and sandstone, the latter probably derived from an accretionary prism. An Andaman Sea model appears most applicable to the youngest ophiolite/associated sediments assemblage.Contemporaneously with the renewed, Ashgillian spreading episode, widespread deposition of clastic sequences of Ashgillian age took place unconformably on the Lower Ordovician ophiolite complexes in fault controlled basins.