Lithotype discrimination within a gridded model by inverting gravity data

In this paper we present a method which allows delineation of geologic structures in a bi-modal lithotype setting. We propose to use gravity data in combination with a priori information about the density contrast between the two lithotypes. The iterative method uses an objective function with five tunable parameters which need to be set. Using an efficient parameter search, suitable ranges of these are investigated to determine their optimal values, respectively, which in turn, ensures good inversion results.
The approach produces structural images of the subsurface, without the need of an a priori density model; the depth to the top of the inhomogeneity is also retrieved.
Besides synthetic simulations, the methodology has also been applied to a small gravity data set, acquired by the industry over a basinal structure. A consistent, bi-modal image of the bedrock depression is obtained from the data, which, in this case, was the goal. Other potential areas of application include delineation of salt structures and ore deposits.     

Overview and significance of a 250 ka paleoclimate record from El’gygytgyn Crater Lake,NE Russia

Sediment piston cores from Lake El’gygytgyn (67°N, 172°E), a 3.6 million year old meteorite impact crater in northeastern Siberia, have been analyzed to extract a multi-proxy millennial-scale climate record extending to nearly 250 ka, with distinct fluctuations in sedimentological, physical, biochemical, and paleoecological parameters. Five major themes emerge from this research. First the pilot cores and seismic data show that El’gygytygn Crater Lake contains what is expected to be the longest, most continuous terrestrial record of past climate change in the entire Arctic back to the time of impact. Second, processes operating in the El’gygytygn basin lead to changes in the limnogeology and the biogeochemistry that reflect robust changes in the regional climate and paleoecology over a large part of the western Arctic. Third, the magnetic susceptibility and other proxies record numerous rapid change events. The recovered lake sediment contains both the best-resolved record of the last interglacial and the longest terrestrial record of millennial scale climate change in the Arctic, yielding a high fidelity multi-proxy record extending nearly 150,000 years beyond what has been obtained from the Greenland Ice Sheet. Fourth, the potential for evaluating teleconnections under different mean climate states is high. Despite the heterogeneous nature of recent Arctic climate change, millennial scale climate events in the North Atlantic/Greenland region are recorded in the most distal regions of the Arctic under variable boundary conditions. Finally, deep drilling of the complete depositional record in Lake El’gygytgyn will offer new insights and, perhaps, surprises into the late Cenozoic evolution of Arctic climate. This is the first in a series of eleven papers published in this special issue dedicated to initial studies of El'gygytgyn Crater Lake and its catchment in NE Russia. Julie Brigham-Grette, Martin Melles, Pavel Minyuk were guest editors of this special issue.     

Magnetotelluric studies of the East-European Craton and adjacent regions

Magnetotelluric method is widely applied to study the Russian part of the East-European Craton, as well as the Caucasus and the Urals: several thousand soundings were performed during the last few years. Their periods range is approximately from 0.003 to 3000 seconds, which allows to study the sedimentary cover and the consolidated crust. Resistivity cross-sections along several regional profiles which run across the tectonic structures of the East-European Craton and the adjacent folded systems were obtained, mainly using 1D and 2D interpretational tools. MT investigations provided important information about the structure and reservoir properties of sedimentary complexes, the state of active geodynamic regions, the graphitization and fluid regime of the consolidated crust, and the permeable and fluid-saturated crustal zones.     

Concentrations and Seasonal Trends of Extracellular Microcystins in Freshwaters of the Czech Republic – Results of the National Monitoring Program

The first outcomes of the national monitoring program on cyanobacteria and their toxins in the Czech Republic are reported. The concentrations of extracellular microcystins (MCs, analyzed by ELISA) in 206 water samples collected from 94 localities have been investigated. Observed MC concentrations were relatively high in comparison with the literature data, although weather conditions during the covered season (year 2004) were less favorable for the cyanobacterial water blooms. Detectable MCs (>0.125 μg/L) were found in 145 waters (70% of all samples) with a median concentration of 0.67 μg/L. The total median, including samples with no detectable MCs, was 0.26 μg/L. The seasonal trend showed an increase from July to September at most localities (maximum concentrations of about 8 μg/L and extremes up to 37 μg/L). However, a peak at the beginning of the season or continuously elevated MC concentrations were also observed at some localities. Positive correlations between increasing concentrations of MCs and the dominancy of Microcystis spp. have been observed. The survey provides the first large-scale study of the occurrence and seasonal variability of extracellular microcystins that are of particular interest for drinking water management.     

Alternative valorization of red mud waste as functional materials with catalytic activity for sulfide oxidation in wastewater

This work investigates the catalytic properties toward sulfide oxidation in wastewater for three composites which are functional materials obtained from red mud waste following its neutralization, chemical activation and functionalization of the iron by treatment with disodium salt of ethylenediaminetetraacetic acid, trisodium citrate or a combination of these two organic ligands. X-ray diffraction and diffuse reflectance Fourier transformed infrared spectroscopy characterizations indicated the coexistence of the corresponding iron chelates phases along with hematite the main crystallographic phase from red mud. The most active catalyst was the red mud-derived material obtained by functionalization with the mixture of ethylenediaminetetraacetate and citrate ligands. The results obtained after its testing in multiple reaction cycles showed that the decrease in conversion after 10 reaction cycles was less than 5%. Considering the results of diffuse reflectance ultraviolet visible narrow infrared spectroscopical analysis which revealed that this solid contains species with lower bond strength, it has been inferred that both the higher catalytic activity, as well as the enhanced stability, is directly related to the versatility of the active species.     

The upper Viséan–Serpukhovian in the type area for the Serpukhovian Stage (Moscow Basin,Russia): Part 1. Sequences,disconformities, and biostratigraphic summary

The upper Viséan–Serpukhovian strata in the type region for the Serpukhovian Stage is an epeiric‐sea succession ca. 90 m in thickness. The predominantly Viséan Oka Group (comprising the Aleksin, Mikhailov, and Venev formations) is dominated by photozoan packstones with fluvial siliciclastic wedges developed from the west. The Lower Serpukhovian Zaborie Group is composed of the Tarusa and Gurovo formations. The latter is a new name for the shale‐dominated unit of Steshevian Substage age in the studied area. The Zaborie Group is composed of limestones and marls in its lower (Tarusa and basal Gurovo) part and black smectitic to grey palygorskitic shales in the main part of the Gurovo Formation. The Gurovo Formation is capped by a thin limestone with oncoids and a palygorskitic–calcretic palaeosol. The Upper Serpukhovian is composed of a thin (3–12 m) Protva Limestone heavily karstified during a mid‐Carboniferous lowstand. The succession shows a number of unusual sedimentary features, such as a lack of high‐energy facies, shallow‐subtidal marine sediments penetrated by Stigmaria, the inferred atidal to microtidal regime, and palustrine beds composed of saponitic marls. The succession contains many subaerial disconformities characterized by profiles ranging from undercoal solution horizons to palaeokarsts. Incised fluvial channels are reported at two stratigraphic levels to the west of the study area. The deepest incisions developed from the Kholm Disconformity (top of the Mikhailov Formation). This disconformity also exhibits the deepest palaeokarst profile and represents the major hiatus in the Oka–Zaborie succession. The new sea‐level curve presented herein shows two major cycles separated by the Kholm Unconformity at the Mikhailov/Venev boundary. The Lower Serpukhovian transgression moved the base‐level away from falling below the seafloor so that the section becomes conformable above the Forino Disconformity (lower Tarusa). The maximum deepening is interpreted to occur in the lower dark‐shale part of the Gurovo Formation. The base of the Serpukhovian Stage is defined by FADs of the conodont Lochriea ziegleri and the foraminifer Janischewskina delicata in the middle of the sequence VN2. The Aleksinian–Mikhailovian interval is provisionally correlated with the Asbian (Lower–Middle Warnantian) in Western Europe. Based on FODs of Janischewskina typica and first representatives of Climacammina, the Venevian is correlated with the Brigantian in Western Europe. The Tarusian–Protvian interval contains diverse fusulinid and conodont assemblages, but few forms suitable for international correlation. FADs of the zonal conodont species Adetognathus unicornis and Gnathodus bollandensis at several metres above the Protvian base suggest correlation of the entire Zaborie Group and may be the basal Protvian to the Pendleian. Copyright © 2014 John Wiley & Sons, Ltd.     

Characterization of Mason Gully (H5): The second recovered fall from the Desert Fireball Network

Mason Gully, the second meteorite recovered using the Desert Fireball Network (DFN), is characterized using petrography, mineralogy, oxygen isotopes, bulk chemistry, and physical properties. Geochemical data are consistent with its classification as an H5 ordinary chondrite. Several properties distinguish it from most other H chondrites. Its 10.7% porosity is predominantly macroscopic, present as intergranular void spaces rather than microscopic cracks. Modal mineralogy (determined via PS‐XRD, element mapping via energy dispersive spectroscopy [EDS], and X‐ray tomography [for sulfide, metal, and porosity volume fractions]) consistently gives an unusually low olivine/orthopyroxene ratio (0.67?0.76 for Mason Gully versus ~1.3 for typical H5 ordinary chondrites). Widespread “silicate darkening” is observed. In addition, it contains a bright green crystalline object at the surface of the recovered stone (diameter ≈ 1.5 mm), which has a tridymite core with minor α‐quartz and a rim of both low‐ and high‐Ca pyroxene. The mineralogy allows the calculation of the temperatures and ?(O₂) characterizing thermal metamorphism on the parent body using both the two‐pyroxene and the olivine‐chromite geo‐oxybarometers. These indicate that MG experienced a peak metamorphic temperature of ~900 °C and had a similar ?(O₂) to Kernouvé (H6) that was buffered by the reaction between olivine, metal, and pyroxene. There is no evidence for shock, consistent with the observed porosity structure. Thus, while Mason Gully has some unique properties, its geochemistry indicates a similar thermal evolution to other H chondrites. The presence of tridymite, while rare, is seen in other OCs and likely exogenous; however, the green object itself may result from metamorphism.     

A method to determine warm and cool steppe biomes from pollen data; application to the Mediterranean and Kazakhstan regions

An objective method for the assignment of pollen spectra to appropriate biomes has been published recently. The aim of this paper is to improve the distinction between warm and cool steppes, thus refining vegetation and climate reconstruction, particularly during the Last Glacial Maximum. A set of modern pollen spectra from the Mediterranean and Kazakhstan regions, dominated today by open vegetation types, has been analysed statistically in order to relate pollen taxa abundances to warm and cool grass/shrub plant functional types (PFTs). A statistical test using modern pollen data shows that the method is able to distinguish between cool and warm steppe biomes with a high degree of confidence. The method has been applied to two fossil pollen records. The results of this exercise showed that cool steppe dominated in central Greece between 18 000 and 13 000 yr BP, while in western Iran the vegetation was at the boundary between cool and warm steppes. These vegetation types were replaced by warm mixed forest in Greece and warm steppe in Iran after that time span. © 1998 John Wiley & Sons, Ltd.     

Postglacial history of East European boreal forests in the mid-Kama region,pre-Urals,Russia

The Ural Mountains are an important climatic and biogeographical barrier between European and Siberian forests. In order to shed light on the postglacial formation and evolution of the boreal forests in the European pre-Urals, we obtained a peat sediment core, Chernaya, from the Paltinskoe bog located between the southern taiga and hemiboreal forest zone in the mid-Kama region. We carried out pollen analysis, non-pollen palynomorph analysis, loss-on-ignition tests and radiocarbon dating. Radiocarbon dated records provide centennial to decennial resolution of the vegetation and environmental history of the European pre-Urals for the last 8.8 ka. The postglacial formation of the pre-Uralian hemiboreal forests reveals four important phases: (i) the dominance of Siberian taiga and forest-steppe in the Early Holocene and beginning of the Middle Holocene (8.8–6.9 ka), indicating a dry climate; (ii) the spread of spruce and European broadleaved trees in the Middle Holocene (6.9–4 ka) under wetter climate conditions; (iii) the maximum extent of broadleaved trees coinciding with the arrival and spread of Siberian fir in the Late Holocene (4–2.3 ka); and (iv) the decline of broadleaved trees since the Early Iron Age (2.3 ka – present) possibly due to general climate cooling and logging. While temperate broadleaved trees possibly spread from local refugia in the Urals, fir arrived from Siberia and spread further west. The carbon accumulation rate of Paltinskoe bog (18.9±10.16 g C m⁻² a⁻¹) is close to the average value of carbon accumulation of northern peatlands. Local development of peat is characterized by non-gradual growth with a phase of intensive carbon accumulation between 3.5 and 2.3 ka. The vegetation was strongly influenced by fire in the Early Holocene and by humans since the Early Iron Age practicing deforestation, agriculture and pasture. Phases of increased anthropogenic activity correlate well with the local archaeological data.