Late Quaternary paleoclimate of western Alaska inferred from fossil chironomids and its relation to vegetation histories

Fossil Chironomidae assemblages (with a few Chaoboridae and Ceratopogonidae) from Zagoskin and Burial Lakes in western Alaska provide quantitative reconstructions of mean July air temperatures for periods of the late-middle Wisconsin (～39,000–34,000 cal yr B.P.) to the present. Inferred temperatures are compared with previously analyzed pollen data from each site summarized here by indirect ordination. Paleotemperature trends reveal substantial differences in the timing of climatic warming following the late Wisconsin at each site, although chronological uncertainty exists. Zagoskin Lake shows early warming beginning at about 21,000 cal yr B.P., whereas warming at Burial Lake begins ～4000 years later. Summer climates during the last glacial maximum (LGM) were on average ～3.5 °C below the modern temperatures at each site. Major shifts in vegetation occurred from ～19,000 to 10,000 cal yr B.P. at Zagoskin Lake and from ～17,000 to 10,000 cal yr B.P. at Burial Lake. Vegetation shifts followed climatic warming, when temperatures neared modern values. Both sites provide evidence of an early postglacial thermal maximum at ～12,300 cal yr B.P. These chironomid records, combined with other insect-based climatic reconstructions from Beringia, indicate that during the LGM: (1) greater continentality likely influenced regions adjacent to the Bering Land Bridge and (2) summer climates were, at times, not dominated by severe cold.     

Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Mapping of sound scattering objects in the northern part of the Barents Sea and their geological interpretation

On cruises 25 (2007) and 28 (2011) of the R/V Akademik Nikolai Strakhov in the northern part of the Barents Sea, the Geological Institute, Russian Academy of Sciences, conducted comprehensive research on the bottom relief and upper part of the sedimentary cover profile under the auspices of the International Polar Year program. One of the instrument components was the SeaBat 8111 shallow-water multibeam echo sounder, which can map the acoustic field similarly to a side scan sonar, which records the response both from the bottom and from the water column. In the operations area, intense sound scattering objects produced by the discharge of deep fluid flows are detected in the water column. The sound scattering objects and pockmarks in the bottom relief are related to anomalies in hydrocarbon gas concentrations in bottom sediments. The sound scattering objects are localized over Triassic sequences outcropping from the bottom. The most intense degassing processes manifest themselves near the contact of the Triassic sequences and Jurassic clay deposits, as well as over deep depressions in a field of Bouguer anomalies related to the basement of the Jurassic–Cretaceous rift system     

The Role of Forests in the Implementation of Russia’s Low-Carbon Development Strategy

Doklady Earth Sciences - The potential role of forests in achieving carbon neutrality in the Russian Federation by 2060 is analyzed. It is shown that the key rate in the Strategy for the...     

The impact of rural land management changes on soil hydraulic properties and runoff processes: results from experimental plots in upland UK

To develop an evidence base to help predict the impacts of land management change on flood generation, four experimental sites were established on improved grassland used for sheep grazing at the Pontbren catchment in upland Wales, UK. At each site, three plots were established where surface runoff was measured, supplemented by measurements of soil infiltration rates and soil and vegetation physical properties. Following baseline monitoring, treatments were applied to two of the plots: exclusion of sheep (ungrazed) and exclusion of sheep and planting with native broadleaf tree species (tree planted), with the third plot acting as a control (grazed pasture). Due to a particularly dry summer that occurred pre‐treatment, the soil hydrological responses were initially impacted by the effects of the climate on soil structure. Nevertheless, treatments did have a clear influence on soil hydrological response. On average, post‐treatment runoff volumes were reduced by 48% and 78% in ungrazed and tree‐planted plots relative to the control, although all results varied greatly over the sites. Five years following treatment application, near‐surface soil bulk density was reduced and median soil infiltration rates were 67 times greater in plots planted with trees compared to grazed pasture. The results illustrate the potential use of upland land management for ameliorating local‐scale flood generation but emphasise the need for long‐term monitoring to more clearly separate the effects of land management from those of climatic variability. Copyright © 2013 John Wiley & Sons, Ltd.     

On the sampling of airborne measurements of radiative properties of cloud fields: Results from International Cirrus Experiment (ICE), 1987

Summary During the first pilot phase of the International Cirrus Experiment (ICE) in September/October 1987 radiation measurements were carried out above and below broken cloud fields over the German Bight. Analyses of the measurements of 25.9.1987 (broken cumulus cloud field) showed an unexpected high absorption of solar radiation but not those of 28.9.1987 (stratocumulus/stratus cloud field). This might be explained by a partial negligence of cloud side factor under the viewing geometry of the pyranometer and other reasons. The light guide effect (leakage) within holes can account for the depletion of cloud reflectance and the enhancement of cloud transmittance at large cloud cover, as observed during the measurements on 28.9.1987. The fluctuation of the irradiances, which can be characterized by the intermittency parameter, has been related to the corresponding cloud cover by a regression equation. On the condition of similarity, this scaling parameter derived from sample measurements could be extrapolated to that of the whole cloud field. Thus, the estimation of the irradiance spectrum for the whole cloud field may be possible, from samples taken with aircraft and imaging data.With 5 Figures     

Deep structure of the Racha earthquake source zone from seismic tomography data

The Racha earthquake of 1991 was the strongest of the earthquakes recorded in the Caucasus. It was studied by an international epicentral expedition. Unique data gathered by this expedition included records of aftershocks whose swarm was very intense. A 3-D velocity model is obtained from analysis of these data by the method of local earthquake tomography. The ancient crystalline basement and the sedimentary-volcanic Mesozoic-Cenozoic cover could be identified from cross sections of the P wave field. The eastern and western boundaries of an uplift in the basement of the Dzirulskii Massif are delineated. Linear low velocity heterogeneities correlating with the active Kakheti-Lechkhumi fault zone and two Trans-Caucasian linear fault zones are discovered in the basement. The cloud of aftershock hypocenters is shown to correlate with a reflector coinciding with the cover-basement interface.     

Anaerobic Metabolism in Tidal Freshwater Wetlands: I. Plant Removal Effects on Iron Reduction and Methanogenesis

For energetic reasons, iron reduction suppresses methanogenesis in tidal freshwater wetlands; however, when iron reduction is limited by iron oxide availability, methanogenesis dominates anaerobic carbon mineralization. Plants can mediate this microbial competition by releasing oxygen into the rhizosphere and supplying oxidized iron for iron reducers. We utilized a plant removal experiment in two wetland sites to test the hypothesis that, in the absence of plants, rates of iron reduction would be diminished, allowing methanogenesis to dominate anaerobic metabolism. In both sites, methanogenesis was the primary anaerobic mineralization pathway, with iron reduction dominating only early and late in the growing season in the site with a less organic soil. These patterns were not influenced by the presence of plants, demonstrating that plants were not a key control of microbial metabolism. Instead, we suggest that site conditions, including soil chemistry, and temperature are important controls of the pathways of anaerobic metabolism.     

The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

Formation of iron sulfide nodules during anaerobic oxidation of methane

The biomarker compositions of iron sulfide nodules (ISNs; upper Pliocene Valle Ricca section near Rome, Italy) that contain the ferrimagnetic mineral greigite (Fe₃S₄) were examined. In addition to the presence of specific terrestrial and marine biomarkers, consistent with formation in coastal marine sediments, these ISNs contain compounds thought to originate from sulfate reducing bacteria (SRB). These compounds include a variety of low-molecular-weight and branched alkanols and several non-isoprenoidal dialkyl glycerol diethers (DGDs). In addition, archaeal biomarkers, including archaeol, macrocyclic isoprenoidal DGDs and isoprenoidal glycerol dialkyl glycerol tetraethers are also present. Both SRB and archaeal lipid δ¹³C values are depleted in ¹³C (δ¹³C values are typically less than −50‰), which suggests that the SRB and archaea consumed ¹³C depleted methane. These biomarker and isotopic signatures are similar to those found in cold seeps and marine sediments where anaerobic oxidation of methane (AOM) occurs with sulfate serving as the terminal electron acceptor. Association of AOM with formation of greigite-containing ISNs could provide an explanation for documented remagnetization of the Valle Ricca sediments. Upward migration of methane, subsequent AOM and associated authigenic greigite formation are widespread processes in the geological record that have considerable potential to compromise paleomagnetic records.