Surface Charge Concentrations on Silica in Different 1.0 M Metal-Chloride Background Electrolytes and Implications for Dissolution Rates

The empirical rate laws formulated to describe the dissolution rates of oxide minerals include the surface charge concentration that results from the protonation and deprotonation of surface functional groups. Previous experiments on quartz and silica have shown that dissolution rates vary as a function of different background electrolyte solutions, however, such experiments are often conducted at elevated temperatures where it is difficult to estimate surface charge along with the dissolution rates. In the present study we measuresurface charge concentrations for silica in different electrolyte solutions at 298 K in order to quantify the extent to which the different counterions could affect the dissolution rates through their influence on the surface charge concentrations. The experimental solutions in the electrolyte series: LiCl, NaCl, KCl, RbCl, CaCl₂, SrCl₂ and BaCl₂ were prepared to maintain a constant metal concentration of 1.0 M. For the alkali-metal chlorides, the surface charge concentrations correlate with the size of the hydrated alkali metal, consistent with the idea that these counterions affect charge via outer-sphere coordination that shield proton surface complexes from one another. The reactivity trend for alkaline-earth cations is less clear, but the data demonstrate distinct differences in the acid-base propertiesof the silica surface in these different electrolytes. We then discuss how these trends are manifested in the rate equations used to interpret dissolution experiments.     

Whole-basin,mass-balance approach for identifying critical phosphorus-loading thresholds in shallow lakes

Lake Lochloosa, Florida (USA) recently underwent a shift from macrophyte to phytoplankton dominance, offering us the opportunity to use a whole-basin, mass-balance approach to investigate the influence of phosphorus loading on ecosystem change in a shallow, sub-tropical lake. We analyzed total phosphorus (TP) sedimentation in the basin to improve our understanding of the forcing factor responsible for the recent shift to phytoplankton dominance. We measured ²¹⁰Pb activity, organic matter (OM), organic carbon (OC) and TP in short sediment cores from 20 locations to develop a comprehensive, whole-basin estimate of recent mass sedimentation rates (MSR) for bulk sediment, OM, OC and TP. The whole-basin sedimentation models provided insights into historic lake processes that were not evident from the limited, historic water quality data. We used Akaike’s Information Criteria to differentiate statistically between constant MSR and exponentially increasing MSR. An eightfold, exponential increase in TP accumulation over the past century provided evidence for the critical role of increased P loading as a forcing factor in the recent shift to phytoplankton dominance. Model results show increased TP retention and decreased TP residence time were in-lake responses to increased TP loading and the shift from macrophyte to phytoplankton dominance in Lake Lochloosa. Comparison of TP loading with TP retention and historic, diatom-inferred limnetic TP concentrations identified the TP loading threshold that was exceeded to trigger the shift to phytoplankton dominance.     

Differentiation of clay resources on a limestone plain: The analysis of clay utilization during the Maya Formative at K'axob Belize

Differentiating clay resources in a uniform limestone plain, such as occurs in northern Belize, offers special challenges for the archaeologist. Combining data from soil mapping with petrographic and neutron activation analysis provides a mechanism for distinguishing possible resource areas. This study employed each of these differing avenues of analysis to determine possible clay resource areas used during the Maya Formative in northern Belize Central America. The results indicate that clay usage changed significantly from the Middle Formative period to the end of Late Formative period. These changes suggest a move to increased localized production and resource exploitation by the end of the period. © 2000 John Wiley & Sons, Inc.     

Stone artifact scatters in western NSW,Australia: Geomorphic controls on artifact size and distribution

Surface scatters of Aboriginal stone artifacts have been exposed in many parts of inland Australia by accelerated erosion that followed the introduction of pastoralism by European settlers in the 19th century. This paper reports on a set of techniques developed to investigate and quantify the effects of these post‐discard disturbance processes in Sturt National Park in northwest NSW, Australia. Backwards, stepwise, linear regression showed the influence of geomorphic parameters such as slope gradient, elevation, landform, and contemporary surface processes on artifact distribution, with artifact maximum dimension as the dependent variable. The results indicate that, even at low gradients, artifact size and slope angle are significantly related, but that the variance in maximum dimension explained by gradient is very low. Similar results were found for the other geomorphic variables. We conclude that artifact movement by surface wash across these surfaces is unlikely to significantly affect artifact distribution. While vertically conflated surface scatters do not preserve “living floors” in a short‐term, functional sense, their apparent horizontal integrity allows investigation of the long‐term use of place by hunter‐gatherer people in the past. Insofar as assemblage integrity is important for assessing site significance in the heritage management industry, our methods provide a means for assessing the degree to which a site has been damaged by water flow. © 2001 John Wiley & Sons, Inc.