A field evaluation of enhanced reductive dechlorination of chlorinated solvents in groundwater,New York Metropolitan Area

An initial assessment of an old manufacturing site with groundwater impacted by trichloroethene (TCE) contamination in the metropolitan New York area showed that the TCE was being removed naturally by reductive dechlorination. However, complete dechlorination was not expected at the site because the process was progressing too slowly under transitional to aerobic conditions at a degradation constant of –0.0013 and a TCE half life of 533 days. A pilot test was conducted at the site in which a carbohydrate substrate (molasses) was injected into the groundwater to create an In-Situ Reactive Zone (IRZ). Post-pilot test groundwater sampling and analysis indicated that an IRZ was created successfully as the total organic carbon (TOC) content and conductivity increased significantly while oxidation-reduction (REDOX) potential and dissolved oxygen (DO) decreased. The created IRZ caused enhanced reductive dechlorination of TCE at the site, found to proceed with a degradation constant of –0.0158 and a TCE half life of 44 days.     

The role of the intra-daily SST variability in the Indian monsoon variability and monsoon-ENSO–IOD relationships in a global coupled model

The impact of diurnal SST coupling and vertical oceanic resolution on the simulation of the Indian Summer Monsoon (ISM) and its relationships with El Ni?o-Southern Oscillation (ENSO) and Indian Ocean Dipole (IOD) events are studied through the analysis of four integrations of a high resolution Coupled General Circulation Model (CGCM), but with different configurations. The only differences between the four integrations are the frequency of coupling between the ocean and atmosphere for the Sea Surface Temperature (SST) parameter (2 vs. 24?h coupling) and/or the vertical oceanic resolution (31 vs. 301 levels) in the CGCM. Although the summer mean tropical climate is reasonably well captured with all the configurations of the CGCM and is not significantly modified by changing the frequency of SST coupling from once to twelve per day, the ISM–ENSO teleconnections are rather poorly simulated in the two simulations in which SST is exchanged only once per day, independently of the vertical oceanic resolution used in the CGCM. Surprisingly, when 2?h SST coupling is implemented in the CGCM, the ISM–ENSO teleconnection is better simulated, particularly, the complex lead-lag relationships between the two phenomena, in which a weak ISM occurs during the developing phase of an El Ni?o event in the Pacific, are closely resembling the observed ones. Evidence is presented to show that these improvements are related to changes in the characteristics of the model’s El Ni?o which has a more realistic evolution in its developing and decaying phases, a stronger amplitude and a shift to lower frequencies when a 2-hourly SST coupling strategy is implemented without any significant changes in the basic state of the CGCM. As a consequence of these improvements in ENSO variability, the lead relationships between Indo-Pacific SSTs and ISM rainfall resemble the observed patterns more closely, the ISM–ENSO teleconnection is strengthened during boreal summer and ISM rainfall power spectrum is in better agreement with observations. On the other hand, the ISM–IOD teleconnection is sensitive to both SST coupling frequency and the vertical oceanic resolution, but increasing the vertical oceanic resolution is degrading the ISM–IOD teleconnection in the CGCM. These results highlight the need of a proper assessment of both temporal scale interactions and coupling strategies in order to improve current CGCMs. These results, which must be confirmed with other CGCMs, have also important implications for dynamical seasonal prediction systems or climate change projections of the monsoon.     

Impacts of warm and cold situations in the Mediterranean basins on the West African monsoon: observed connection patterns (1979–2006) and climate simulations

Using both empirical and numerical ensemble approaches this study focuses on the Mediterranean/West African relationship in northern summer. Statistical analyses utilize skin temperature, sea surface temperature, in situ and satellite rainfall, outgoing longwave radiation (OLR) observations and reanalyzed data winds and specific humidity on isobaric surfaces. Numerical investigations are based on a large set of sensitivity experiments performed on four atmospheric general circulation models (AGCM): ARPEGE-Climat3, ECHAM4, LMDZ4 and UCLA7.3. Model outputs are compared to observations, discussed model by model and with an ensemble (multi-model) approach. As in previous studies the anomalous Mediterranean warm events are associated with specific impacts over the African monsoon region, i.e., a more intense monsoon, enhanced flux convergence and ascendances around the ITCZ, a strengthening of low level moisture advection and a more northward location of ascending motion in West Africa. The results show also new features (1) thermal variability observed in the two Mediterranean basins has unalike impacts, i.e. the western Mediterranean covaries with convection in Gulf of Guinea, while the eastern Mediterranean can be interpreted as Sahelian thermal-forcing; (2) although observations show symmetry between warming and cooling, modelling evidences only support the eastern warming influence; (3) anomalous East warm situations are associated with a more northward migration of the monsoon system accompanied by enhanced southwertely flow and weakened northeasterly climatological wind; (4) the multi-model response shows that anomalous East warm surface temperatures generate an enhancement of the overturning circulation in low and high levels, an increase in TEJ (Tropical Eeasterly Jet) and a decrease in AEJ (African Eeasterly Jet).     

Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.     

Subhaloes in scale-free cosmologies

We explore the dependence of the subhalo mass function on the spectral index n of the linear matter power spectrum using scale-free Einstein-de Sitter simulations with   n =−1  and −2.5. We carefully consider finite volume effects that may call into question previous simulations of   n < −2  power spectra. Subhaloes are found using a 6D friends-of-friends algorithm in all haloes originating from high-σ peaks. For   n =−1  , we find that the cumulative subhalo mass function is independent of the parameters used in the subhalo finding algorithm and is consistent with the subhalo mass function found in Λ cold dark matter (ΛCDM) simulations. In particular, the subhalo mass function is well fit by a power-law with an index of  α=−0.9  , that is the mass function has roughly equal mass in subhaloes per logarithmic interval in subhalo mass. Conversely, for   n =−2.5  , the algorithm parameters affect the subhalo mass function since subhaloes are more triaxial with less well-defined boundaries. We find that the index α is generally larger with  α≳−0.75  . We infer that although the subhalo mass function appears to be independent of n so long as   n ≳−2  , it begins to flatten as   n →−3  . Thus, the common practice of using  α≈−1.0  may greatly overestimate the number of subhaloes at the smallest scales in the CDM hierarchy.     

STEREO/SECCHI Observations on 8 December 2007: Evidence Against the Wave Hypothesis of the EIT Wave Origin

Three-dimensional (3D) tomographic analysis of extreme ultraviolet (EUV) images is used to place empirical constraints on the corona’s temperature and density structure. The input data are images taken by the EUVI instrument on STEREO A and B spacecraft for Carrington Rotation 2069 (16 April to 13 May 2008). While the reconstructions are global, we demonstrate the capabilities of this method by examining specific structures in detail. Of particular importance are the results for coronal cavities and the surrounding helmet streamers, which our method allows to be analyzed without projection effects for the first time. During this rotation, both the northern and southern hemispheres exhibited stable polar crown filaments with overlying EUV cavities. These filaments and cavities were too low-lying to be well observed in white-light coronagraphs. Furthermore, due to projection effects, these cavities were not clearly discernible above the limb in EUV images, thus tomography offers the only option to study their plasma properties quantitatively. It is shown that, when compared to the surrounding helmet material, these cavities have lower densities (about 30%, on average) and broader local differential emission measures that are shifted to higher temperatures than the surrounding streamer plasma.     

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.