Speciation of naturally-accumulated uranium in an organic-rich soil of an alpine region (Switzerland)

Very high concentrations of uranium (up to 4000 ppm) were found in a natural soil in the Dischma valley, an alpine region in the Grisons canton in Switzerland. The goal of this study was to examine the redox state and the nature of uranium binding in the soil matrix in order to understand the accumulation mechanism. Pore water profiles collected from Dischma soil revealed the establishment of anoxic conditions with increasing soil depth. A combination of chemical extraction methods and spectroscopy was applied to characterize the redox state and binding environment of uranium in the soil. Bicarbonate extraction under anoxic conditions released most of the uranium indicating that uranium occurs predominantly in the hexavalent form. Surprisingly, the uranium redox state did not vary greatly as a function of depth. X-ray absorption near edge spectroscopy (XANES), confirmed that uranium was present as a mixture of U(VI) and U(IV) with U(VI) dominating. Sequential extractions of soil samples showed that the dissolution of solid organic matter resulted in the simultaneous release of the majority of the soil uranium content (>95%). Extended X-ray absorption fine structure (EXAFS) spectroscopy also revealed that soil-associated uranium in the soil matrix was mainly octahedrally coordinated, with an average of 1.7 axial (at about 1.76 Å) and 4.6 to 5.3 equatorial oxygen atoms (at about 2.36 Å) indicating the dominance of a uranyl-like (UO₂²⁺) structure presumably mixed with some U(IV). An additional EXAFS signal (at about 3.2 Å) identified in some spectra suggested that uranium was also bound (via an oxygen atom) to a light element such as carbon, phosphorus or silicon. Gamma spectrometric measurements of soil profiles failed to identify uranium long-life daughter products in the soil which is an indication that uranium originates elsewhere and was transported to its current location by water. Finally, it was found that the release of uranium from the soil was significantly promoted at very low pH values (pH 2) and increased with increasing pH values (between pH 5 and 9).     

Trophic ecology of Pomatoschistus microps within an intertidal bay (Roscoff,France), investigated through gut content and stable isotope analyses

The diet of Pomatoschistus microps has been studied using both gut content and stable isotope analyses. In the Roscoff Aber Bay (Brittany, France), this fish is commonly found on sandy muddy intertidal flats. Gut content analyses were also interpreted using trophic indices. Owing to the large diversity of prey consumed, these indices emphasised the opportunistic feeding behaviour of P. microps. Here, this species fed mainly on endofauna with meiofauna being of high relative importance. The main biotic components of its trophic habitat, characterized by δ¹³C and δ¹⁵N, provided evidence of a major trophic pathway based on drift Enteromorpha sp. Trophic positions estimated by both diet analyses and isotopic analyses led to similar results. In this bay, P. microps is a first‐order predator with a low degree of omnivory. Despite a preferential consumption of the amphipod Corophium arenarium, we assumed that this goby behaves as a generalist feeding on a uniform variety of endofauna taxa.     

A Comprehensive Framework for Intrinsic OpenStreetMap Quality Analysis

OpenStreetMap (OSM) is one of the most popular examples of a Volunteered Geographic Information (VGI) project. In the past years it has become a serious alternative source for geodata. Since the quality of OSM data can vary strongly, different aspects have been investigated in several scientific studies. In most cases the data is compared with commercial or administrative datasets which, however, are not always accessible due to the lack of availability, contradictory licensing restrictions or high procurement costs. In this investigation a framework containing more than 25 methods and indicators is presented, allowing OSM quality assessments based solely on the data's history. Without the usage of a reference data set, approximate statements on OSM data quality are possible. For this purpose existing methods are taken up, developed further, and integrated into an extensible open source framework. This enables arbitrarily repeatable intrinsic OSM quality analyses for any part of the world.     

Towards a 4D topographic view of the Norwegian sea margin

The present-day topography/bathymetry of the Norwegian mainland and passive margin is a product of complex interactions between large-scale tectonomagmatic and climatic processes that can be traced back in time to the Late Silurian Caledonian Orogeny. The isostatic balance of the crust and lithosphere was clearly influenced by orogenic thickening during the Caledonian Orogeny, but was soon affected by post-orogenic collapse including overprinting of the mountain root, and was subsequently affected by a number of discrete extensional events eventually leading to continental break-up in Early Eocene time. In the mid-Jurassic the land areas experienced deep erosion in the warm and humid climate, forming a regional paleic surface. Rift episodes in the Late Jurassic and Early Cretaceous, with differential uplift along major fault zones, led to more pronounced topographic contrasts during the Cretaceous, and thick sequences of clastic sediments accumulated in the subsiding basins on the shelf. Following renewed extension in the Late Cretaceous, a new paleic surface developed in the Paleocene. Following break-up the margin has largely subsided thermally, but several Cenozoic shortening events have generated positive contraction structures. On the western side of the on-shore drainage divide, deeper erosion took place along pre-existing weakness zones, creating the template of the present day valleys and fjords. In the Neogene the mainland and large portions of the Barents Sea were uplifted. It appears that this uplift permitted ice caps to nucleate and accumulate during the Late Pliocene northern hemisphere climatic deterioration. The Late Pliocene to Pleistocene glacial erosion caused huge sediment aprons to be shed on to the Norwegian Sea and Barents Sea margins. Upon removal of the ice load the landmass adjusted isostatically, and this still continues today.     

Bias in hydraulic head measurements from multilevel vibrating-wire piezometers with excessively permeable backfill

Hydrogeology Journal - An extensive network of multilevel vibrating-wire piezometers (VWP) was recently created to monitor the spatial and temporal variation of pore pressure (and hydraulic head)...     

Assessing the Completeness of Bicycle Trail and Lane Features in OpenStreetMap for the United States

This article assesses the completeness of bicycle trail and on‐street lane features in OpenStreetMap (OSM). Comparing OSM cycling features with reference data from local planning agencies for selected US Urbanized Areas shows that OSM bicycle trails tend to be more completely mapped than bicycle lanes. Manual evaluation of mapped cycling features in OSM and Google Maps for selected test areas within the Central Business Districts of Portland (OR) and Miami (FL) through comparison with governmental datasets, satellite imagery, and Google Street View, shows that the Bicycle layer in Google Maps can help to identify some missing or erroneously mapped OSM cycling links. However, Google Maps was also found to have some gaps in its data layers, suggesting that consultation of current trail and lane data from local planning authorities, if available, should be considered as an additional data source for bicycle related planning projects.     

Measuring the Reliability of Wheelchair User Route Planning based on Volunteered Geographic Information

The development of a wheelchair user friendly route planning application inherits a number of special requirements and details that need to be considered during the generation of the routing graph and the corresponding algorithm, making this task much more complex than car or pedestrian related applications. Each wheelchair type and, more importantly, each individual user might have different needs with regards to the way condition or other criteria. This study proposes a new approach to route planning for wheelchair users tailored for individual and personal requirements provided by the user and the calculation of a reliability factor of the computed wheelchair path. The routing graph is based on the freely available Volunteered Geographic Information (VGI) retrieved from the OpenStreetMap (OSM) project. The newly created algorithm is evaluated and tested for a selected area in Bonn, Germany. A new reliability factor is introduced that gives direct feedback about the quality of the generated path. Similar factor estimations can also be utilized for multiple route planning applications where VGI or other commercial or administrative data is implemented and more detailed factors than a simple geometric representation of a street network are of importance.     

Intraseasonal SST-precipitation relationship and its spatial variability over the tropical summer monsoon region

The SST-precipitation relationship in the intraseasonal variability (ISV) over the Asian monsoon region is examined using recent high quality satellite data and simulations from a state of the art coupled model, the climate forecast system version 2 (CFSv2). CFSv2 demonstrates high skill in reproducing the spatial distribution of the observed climatological mean summer monsoon precipitation along with its interannual variability, a task which has been a conundrum for many recent climate coupled models. The model also exhibits reasonable skill in simulating coherent northward propagating monsoon intraseasonal anomalies including SST and precipitation, which are generally consistent with observed ISV characteristics. Results from the observations and the model establish the existence of spatial variability in the atmospheric convective response to SST anomalies, over the Asian monsoon domain on intraseasonal timescales. The response is fast over the Arabian Sea, where precipitation lags SST by ~5 days; whereas it is slow over the Bay of Bengal and South China Sea, with a lag of ~12 days. The intraseasonal SST anomalies result in a similar atmospheric response across the basins, which consists of a destabilization of the bottom of the atmospheric column, as observed from the equivalent potential temperature anomalies near the surface. However, the presence of a relatively strong surface convergence over the Arabian Sea, due to the presence of a strong zonal gradient in SST, which accelerates the upward motion of the moist air, results in a relatively faster response in terms of the local precipitation anomalies over the Arabian Sea than over the Bay of Bengal and South China Sea. With respect to the observations, the ocean–atmosphere coupling is well simulated in the model, though with an overestimation of the intraseasonal SST anomalies, leading to an exaggerated SST-precipitation relationship. A detailed examination points to a systematic bias in the thickness of the mixed layer of the ocean model, which needs to be rectified. A too shallow (deep) mixed layer enhances (suppress) the amplitude of the intraseasonal SST anomalies, thereby amplifying (lessening) the ISV and the active-break phases of the monsoon in the model.     

High resolution simulation of the South Asian monsoon using a variable resolution global climate model

This study examines the feasibility of using a variable resolution global general circulation model (GCM), with telescopic zooming and enhanced resolution (~35 km) over South Asia, to better understand regional aspects of the South Asian monsoon rainfall distribution and the interactions between monsoon circulation and precipitation. For this purpose, two sets of ten member realizations are produced with and without zooming using the LMDZ (Laboratoire Meteorologie Dynamique and Z stands for zoom) GCM. The simulations without zoom correspond to a uniform 1° × 1° grid with the same total number of grid points as in the zoom version. So the grid of the zoomed simulations is finer inside the region of interest but coarser outside. The use of these finer and coarser resolution ensemble members allows us to examine the impact of resolution on the overall quality of the simulated regional monsoon fields. It is found that the monsoon simulation with high-resolution zooming greatly improves the representation of the southwesterly monsoon flow and the heavy precipitation along the narrow orography of the Western Ghats, the northeastern mountain slopes and northern Bay of Bengal (BOB). A realistic Monsoon Trough (MT) is also noticed in the zoomed simulation, together with remarkable improvements in representing the associated precipitation and circulation features, as well as the large-scale organization of meso-scale convective systems over the MT region. Additionally, a more reasonable simulation of the monsoon synoptic disturbances (lows and disturbances) along the MT is noted in the high-resolution zoomed simulation. On the other hand, the no-zoom version has limitations in capturing the depressions and their movement, so that the MT zone is relatively dry in this case. Overall, the results from this work demonstrate the usefulness of the high-resolution variable resolution LMDZ model in realistically capturing the interactions among the monsoon large-scale dynamics, the synoptic systems and the meso-scale convective systems, which are essential elements of the South Asian monsoon system.     

Impact of climate change on the hydrogeology of two basins in northern France

This study presents an analysis of climate-change impacts on the water resources of two basins located in northern France, by integrating four sources of uncertainty: climate modelling, hydrological modelling, downscaling methods, and emission scenarios. The analysis focused on the evolution of the water budget, the river discharges and piezometric heads. Seven hydrological models were used, from lumped rainfall-discharge to distributed hydrogeological models, and led to quite different estimates of the water-balance components. One of the hydrological models, CLSM, was found to be unable to simulate the increased water stress and was, thus, considered as an outlier even though it gave fair results for the present day compared to observations. Although there were large differences in the results between the models, there was a marked tendency towards a decrease of the water resource in the rivers and aquifers (on average in 2050 about ?14 % and ?2.5 m, respectively), associated with global warming and a reduction in annual precipitation (on average in 2050 +2.1 K and ?3 %, respectively). The uncertainty associated to climate models was shown to clearly dominate, while the three others were about the same order of magnitude and 3–4 times lower. In terms of impact, the results found in this work are rather different from those obtained in a previous study, even though two of the hydrological models and one of the climate models were used in both studies. This emphasizes the need for a survey of the climatic-change impact on the water resource.