Reflections in bumpy terrain: implications of canopy surface variations for the radiation balance of vegetation

Data from an optical imaging sensor and a small-footprint lidar were used to examine the relation between canopy reflectance and outer surface complexity in forest stands in the southern Cascades of Washington state. Albedo was estimated from the Airborne Visible Infrared/Imaging Spectrometer; canopy surface variation (termed "rugosity") was estimated from small-footprint lidar; and stand ages were obtained through U.S. Forest Service records and global information system coverages. Results showed that albedo from Douglas-fir/western hemlock stands decreased, and variation in the outer surface of the canopy increased with age. Estimates of rugosity increased most rapidly in young stands and then more slowly after about 150 years. Albedo declined by 10% across the age sequence, suggesting that older stands of this forest type enjoy a substantial advantage in energy input. The results highlight the impacts of land-cover change on local energy balance and climate.     

Hazard transformation and hazard management issues in the London megacity

Megacities are likely to present the greatest future challenges for hazard management. In them increasingly complex societies are continually modifying responses to dynamic sets of external risks. Although most have proven resilient to past disasters, new types of threat are emerging. London — which is both the world's oldest megacity and one of its most resilient — has long experience of the transformation of hazards in time and space. Although not as hazard-prone as some megacities, this one is increasingly exposed to a wide range of interactive hazards. Here trends of flooding, air pollution and terrorism are discussed together with policy responses. London demonstrates that robust action can be successful in reducing high-intensity hazards but it also shows that contemporary management is characterised by top-down technological fixes whose long-term effectiveness is questionable. In general, anticipatory responses have been limited and present-day London has not capitalised on its rich legacy of successful experience in coping with hazard.     

The extrapolation of elastic moduli to high pressure and temperature

The elastic constants of a crystal under stress, defined as the second derivative of the crystal free energy with respect to strain, require a correction related to the static pressure at non-zero pressures. The corrections required for the elastic constants calculated by the free energy minimisation code PARAPOCS are described and tested by comparison with the elastic constants calculated numerically by applying small stresses in the appropriate orientations to simulated crystals of fluorite, forsterite, α-quartz and albite. The corrected elastic constants are then used to investigate the extrapolation of the bulk and shear moduli (and hence also the seismic wave velocities V _p and V _s) of β-spinel and forsterite to upper mantle pressures. A Murnaghan equation, thirdorder Eulerian finite strain equation, second order polynomial equation and a logistic equation were all fitted to the simulated bulk and shear moduli between 0 and 3 GPa pressure. The parameters derived for these equations are used to extrapolate the bulk and shear moduli to 14 GPa and the results are compared to the simulated high pressure moduli. Over this pressure range, the second order polynomial provides the best extrapolation of the bulk modulus, but the use of the logistic equation results in the best extrapolation of the shear modulus.     

Influence of Casing Materials on Trace-Level Chemicals in Well Water

Four well casing materials — polyvinyl chloride (PVC), polytetrafluoroethylene (PTFE), and stainless steel 304 (SS 304) and 316 (SS 316) — were examined to determine their suitability for monitoring inorganic and organic constituents in well water.
The inorganic study used a factorial design to test the effect of concentration of mixed metals (arsenic [As], chromium [Cr], lead [Pb], and cadmium [Cd]), pH, and organic carbon. Sample times were 0.5, 4, 8, 24, and 72 hours. Except for slow loss of Pb, PTFE well casings had no significant effect on the concentration of metals in solution. For the other casings, changes in analyte concentration often exceeded 10 percent in eight hours or less and, thus, could bias analyses of samples taken from wells constructed with these materials. Specifically, PVC casings sorbed Pb and leached Cd; SS 316 casings sorbed As and Pb and leached Cd; and SS 304 casings sorbed As, Cr, and Pb and leached Cd. Both stainless steel casing materials showed markedly poorer performance than the PVC casings.
The well casings were also tested for sorption/desorption of 10 organic substances from the following classes: chlorinated alkehes, chlorinated aromatics, nitroaromatics and nitramines. Sample times were 0, 1, 8, 24, and 72 hours, seven days, and six weeks. There were no detectable losses of analytes in any of the sample solutions containing stainless steel well casings. Significant loss of some analytes was observed in sample solutions containing plastic casings, although losses were always more rapid with the PTFE casings than with PVC. Chlorinated organic substances were lost most rapidly. For samples containing PTFE casings, losses of some of these compounds were rapid enough (>10 percent in eight hours) to be of concern for ground water monitoring. Losses of hydrophobic organic constituents in samples containing PTFE casings were correlated with the compound's octanol/water partition coefficient.     

Critical issues for long-term climate monitoring

Climatic Change - Even after extensive re-working of past data, in many instances we are incapable of resolving important aspects concerning climate change and variability. Virtually every...     

Models of Earth's main magnetic field incorporating flux and radial vorticity constraints

We describe a new technique for implementing the constraints on magnetic fields arising from two hypotheses about the fluid core of the Earth, namely the frozen-flux hypothesis and the hypothesis that the core is in magnetostrophic force balance with negligible leakage of current into the mantle. These hypotheses lead to time-independence of the integrated flux through certain 'null-flux patches' on the core surface, and to time-independence of their radial vorticity. Although the frozen-flux hypothesis has received attention before, constraining the radial vorticity has not previously been attempted. We describe a parametrization and an algorithm for preserving topology of radial magnetic fields at the core surface while allowing morphological changes. The parametrization is a spherical triangle tesselation of the core surface. Topology with respect to a reference model (based on data from the Oersted satellite) is preserved as models at different epochs are perturbed to optimize the fit to the data; the topology preservation is achieved by the imposition of inequality constraints on the model, and the optimization at each iteration is cast as a bounded value least-squares problem. For epochs 2000, 1980, 1945, 1915 and 1882 we are able to produce models of the core field which are consistent with flux and radial vorticity conservation, thus providing no observational evidence for the failure of the underlying assumptions. These models are a step towards the production of models which are optimal for the retrieval of frozen-flux velocity fields at the core surface.