Himalayan magmatism and porphyry copper–molybdenum mineralization in the Yulong ore belt, East Tibet

Summary ?The NW–SE-trending Yulong porphyry Cu–Mo ore belt, situated in the Sanjiang0 area of eastern Tibet, is approximately 400 km long and 35 to 70 km wide. Complex tectonic and magmatic processes during the Himalayan epoch have given rise to favorable conditions for porphyry-type Cu–Mo mineralization. Porphyry masses of the Himalayan epoch in the Yulong ore belt are distributed in groups along regional NW–SE striking tectonic lineaments. They were emplaced mainly into Triassic and Lower Permian sedimentary-volcanic rocks. K–Ar und U–Pb isotopic datings give an intrusion age range of 57–26 Ma. The porphyries are mainly of biotite monzogranitic and biotite syenogranitic compositions. Geological and geochemical data indicate that the various porphyritic intrusions in the belt had a common or similar magma source, are metaluminous to peraluminous, Nb–Y–Ba-depleted, I-type granitoids, and belong to the high-K calc-alkaline series. Within the Yulong subvolcanic belt a number of porphyry stocks bear typical porphyry type Cu–Mo alteration and mineralization. The most prominent porphyry Co–Mo deposits include Yulong, Malasongduo, Duoxiasongduo, Mangzong and Zhanaga, of which Yulong is one of the largest porphyry Cu (Mo) deposits in China with approximately 8 × 10⁶ tons of contained Cu metal. Hydrothermal alteration at Yulong developed around a biotite–monzogranitic porphyry stock that was emplaced within Upper Triassic limestone, siltstone and mudstone. The earliest alteration was due to the effects of contact metamorphism of the country rocks and alkali metasomatism (potassic alteration) within and around the porphyry body. The alteration of this stage was accompanied by a small amount of disseminated and veinlet Cu–Mo sulfide mineralization. Later alteration–mineralization zones form more or less concentric shells around the potassic zone, around which are distributed a phyllic or quartz–sericite–pyrite zone, a silicification and argillic zone, and a propylitic zone. Fluid inclusion data indicate that three types of fluids were involved in the alteration–mineralization processes: (1) early high temperature (660–420 °C) and high salinity (30–51 wt% NaCl equiv) fluids responsible for the potassic alteration and the earliest disseminated and/or veinlet Cu–Mo sulfide mineralization; (2) intermediate unmixed fluids corresponding to phyllic alteration and most Cu–Mo sulfide mineralization, with salinities of 30–50 wt% NaCl equiv and homogenization temperatures of 460–280 °C; and (3) late low to moderate temperature (300–160 °C) and low salinity (6–13 wt% NaCl equiv) fluids responsible for argillic and propylitic alteration. Hydrogen and oxygen isotopic studies show that the early hydrothermal fluids are of magmatic origin and were succeeded by increasing amounts of meteoric-derived convective waters. Sulfur isotopes also indicate a magmatic source for the sulfur in the early sulfide mineralization, with the increasing addition of sedimentary sulfur outward from the porphyry stock. Received August 29, 2001; revised version accepted May 1, 2002 Published online: November 29, 2002     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.     

Metamorphic decarbonation, silicate weathering and the long-term carbon cycle

The seawater ⁸⁷Sr/⁸⁶Sr curve implies a 50–100 Myr episodicity in weathering rate which requires a corresponding variation in CO₂ degassing from the solid earth to the atmosphere. It is proposed that this is caused by orogenesis, which both produces CO₂ as a result of metamorphic decarbonation reactions, and consumes extra CO₂ as a consequence of erosion-enhanced weathering. Global climate on the geological time-scale is therefore contTolled by the difference between the relatively large and variable orogenic-moderated degassing and weathering CO₂ fluxes.     

Nutrient (P, N) dynamics in the southwestern Kattegat, Scandinavia: sedimentation and resuspension effects

 The yearly nutrient supply from land and atmosphere to the study area in SW Kattegat is 10 900 tons of N and 365 tons of P. This is only few percent of the supply from adjacent marine areas, as the yearly transport through the study area is 218 000 tons of N and 18 250 tons of P. Yearly net deposition makes up 1340 tons of N (on average 2.5 g m^–2 yr^–1) and 477 ton of P (on average 0.9 g m^–2 yr^–1). Shallow-water parts of the study area have no net deposition because of frequent (>35% of the year) resuspension. Resuspension frequency in deep water is <1% of the year. Resuspension rates, as averages for the study area, are 10–17 times higher than net deposition rates. Because of resuspension, shallow-water sediments are coarse lag deposits with small amounts of organic matter (1.1%) and nutrients (0.04% N and 0.02% P). Deep-water sediments, in contrast, are fine grained with high levels of organic matter (11.7%) and nutrients (0.43% N and 0.15% P). Laboratory studies showed that resuspension changes the diffusive sediment water fluxes of nutrients, oxygen consumption, and penetration into the sediment. Fluxes of dissolved reactive phosphate from sediment to water after resuspension were negative in organic-rich sediments (13.2% organic matter) with low porosity (56) and close to zero in coarse sediments with a low organic matter content (2.3%) and high porosity (73). Fluxes of inorganic N after resuspension were reduced to 70% and 0–20% in relation to the rates before resuspension, respectively. Received: 10 July 1995 · Accepted: 19 January 1996     

The Upper Pleistocene to Holocene sediments on the Mediterranean island of Lampedusa (Italy)

The island of Lampedusa lies on the northern edge of the African continental shelf, but during some Quaternary marine lowstands it was joined to the African continent. The study and dating of the aeolian, alluvial, detrital sediments, calcareous crusts and speleothems have established that the climatic–environmental variations recorded on the island can be related chronologically to those known for northern Libya, Tunisia and the Italian peninsula. During the Last Glacial Maximum, phases of Saharan dust accumulation on Lampedusa occurred, and were coeval with dust accumulation in crater lakes and on high mountains in central‐southern Italy, and with phases of glacial advance in the Apennines and in the Alps. During the late Holocene, accumulation of Saharan dust on Lampedusa occurred but there was little accumulation of dust on the northern side of the Mediterranean Sea. With the new data from Lampedusa, it is possible to envisage two different scenarios of atmospheric circulation relating to the Last Glacial Maximum and to the late Holocene. During the Last Glacial Maximum, southerly atmospheric circulation brought rainfall to the southern slopes of the Alps and to the Apennines. During the late Holocene, a prevalent westerly atmospheric circulation became established in the northern Mediterranean. Copyright © 2004 John Wiley & Sons, Ltd.     

Water transport from the North-east Irish Sea to western Scottish coastal waters: Further observations from time-trend matching of Sellafield radiocaesium

Radiocaesium isotopes, discharged into the North-east Irish Sea from the Sellafield (formerly Windscale) nuclear fuel reprocessing plant in Cumbria, have been employed as flow monitors to update and extend the record of coastal water movement from the Irish Sea to the Clyde Sea area and, further north, to Loch Etive. The temporal trends in radiocaesium levels have been used to determine the extent of water mixing en route and to define mean advection rates. Flow conditions from the Irish Sea have changed considerably since the mid-1970s, the residence time of northern Irish Sea waters being ～12 months during 1978–1980 inclusive. Average transport times of four and six months are estimated for the Sellafield to Clyde and Sellafield to Etive transects respectively. Sellafield ¹³⁷Cs levels in seawater were diluted by factors of 27 and 50 respectively during current movement to the Clyde and Etive areas. The decrease in salinity-corrected ¹³⁷Cs concentrations between the Clyde and Etive suggests that dilution by Atlantic water occurs, the latter mainly entering the Firth of Lorne from the west. The majority (～94%) of the radiocaesium supply to Loch Etive enters the Firth of Lorne via the portion of the coastal current circulating west of Islay, only ～6% arriving via the Sound of Jura.     

Nitrogen uptake,ammonium oxidation and nitrous oxide (N2O) levels in the coastal waters of western Cook Strait,New Zealand

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.