A mechanical interpretation of the vein and dyke systems of the S. W. England orefield

Geological plans and sections showing the traces of veins, faults and porphyry dykes associated with the Hercynian batholith, have been used to construct diagrams representing the trajectories of the minimum and intermediate principal stress axes as they were at the time of intrusion of the dykes and as the veinlode fissures formed. The dykes and veins were emplaced during a complicated series of events and the trajectory diagrams represent stress conditions during these overlapping periods of time towards the end of intrusion of the batholith. The mineralizing fluids emanated from the cores of plutons by means of pregranite faults, primary igneous joints, and structures created by intrusion, including faults and extension fissures. The trajectory diagrams indicate that the mapped configuration of veins and porphyry dykes results from fluid pressures, exerted by the mobile cores of granitic cupolas situated within a regional stress field. The stress models also indicate that fugitive dyke magma or hydrothermal fluids, emanating from a cupola, will make the mechanically easiest exit through the flanks of the intrusion. This explains the asymmetrical disposition of belts of mineralization which border the granite cupolas of southwest England.     

Lithium,sodium and potassium abundances in carbonaceous chondrites

Concentrations of lithium, sodium, and potassium in 18 carbonaceous chondrites were determined in the same sample solution by atomic absorption. Mean abundances in carbonaceous Type I chondrites are, in atoms 10⁶ Si: Li = 60.1, Na = 5800, K = 3700. Relative to Type I carbonaceous chondrites, abundances in Type II's are: Li = 0.87, Na = 0.61, K = 0.58; and in Type III's Li = 0.82, Na = 0.49, K = 0.36. Evidently there is a differential depletion of potassium relative to sodium in Type III's, suggesting a fractionation after accretion.     

Talc friction in the temperature range 25°–400 °C: Relevance for Fault-Zone Weakening

Talc is one of the weakest minerals that is associated with fault zones. Triaxial friction experiments conducted on water-saturated talc gouge at room temperature yield values of the coefficient of friction, μ (shear stress, τ/effective normal stress, σ′_N) in the range 0.16–0.23, and μ increases with increasing σ′_N. Talc gouge heated to temperatures of 100°–400 °C is consistently weaker than at room temperature, and μ < 0.1 at slow strain rates in some heated experiments. Talc also is characterized by inherently stable, velocity-strengthening behavior (strength increases with increasing shear rate) at all conditions tested. The low strength of talc is a consequence of its layered crystal structure and, in particular, its very weak interlayer bond. Its hydrophobic character may be responsible for the relatively small increase in μ with increasing σ′_N at room temperature compared to other sheet silicates.Talc has a temperature–pressure range of stability that extends from surficial to eclogite-facies conditions, making it of potential significance in a variety of faulting environments. Talc has been identified in exhumed subduction zone thrusts, in fault gouge collected from oceanic transform and detachment faults associated with rift systems, and recently in serpentinite from the central creeping section of the San Andreas fault. Typically, talc crystallized in the active fault zones as a result of the reaction of ultramafic rocks with silica-saturated hydrothermal fluids. This mode of formation of talc is a prime example of a fault-zone weakening process. Because of its velocity-strengthening behavior, talc may play a role in stabilizing slip at depth in subduction zones and in the creeping faults of central and northern California that are associated with ophiolitic rocks.     

Diel Variation in the Pelagic Fish Assemblage in a Temperate Estuary

The pelagic fish assemblage within a temperate estuary was examined to determine if there were diel differences in species richness, total abundance, biomass, and species composition. These comparisons were made over both seasonal (January–December 1996) and annual (August–November 1995; August–December 1996) scales with pop net collections in a shallow (<2 m MLW) embayment within Great Bay in southern New Jersey, USA. In the complete year of sampling in 1996, more than 335,000 pelagic fish, representing 13 families (23 species), were collected during diel sampling with 12 species constituting over 99.9% of the total catch including Clupea harengus (84%), Menidia menidia (10%), and Anchoa mitchilli (4%). A detailed examination determined that nighttime species richness, total abundance and biomass may have been enhanced during some seasons by using artificial light. Diel variation in species composition was similar regardless of the use of the artificial light in all seasons but fall. Annual comparisons between 1995 and 1996 during late summer and fall found these results to be consistent. In general, these findings point out the importance of sampling during both day and night to understand the movement and abundance patterns of estuarine pelagic fishes and their ecological significance in temperate estuaries.     

Daily discharge estimation at ungauged river sites using remote sensing

A methodology is developed to estimate daily river discharge at an ungauged site using remote sensing data. Use is made of ERS‐2 and ENVISAT satellite altimetry to provide a time series of river channel stage levels and longitudinal channel slope and Landsat satellite imagery to provide a range of channel widths over a 50 km reach of river. The data are substituted into the Bjerklie et al. ( 2003 ) equation, which is based on the Manning's resistance equation and has been developed using a global database of channel hydraulic information and discharge measurements. Our methodology has been applied at three locations on the Mekong and Ob Rivers and validated against daily in situ discharge measurements. The results show Nash–Sutcliffe efficiency values of 0.90 at Nakhon Phanom and 0.86 at Vientiane on the Mekong, and 0.86 at Kalpashevo on the Ob. Copyright © 2012 John Wiley & Sons, Ltd.     

Vadose CO2 gas drives dissolution at water tables in eogenetic karst aquifers more than mixing dissolution

Most models of cave formation in limestone that remains near its depositional environment and has not been deeply buried (i.e. eogenetic limestone) invoke dissolution from mixing of waters that have different ionic strengths or have equilibrated with calcite at different _pCO₂ values. In eogenetic karst aquifers lacking saline water, mixing of vadose and phreatic waters is thought to form caves. We show here calcite dissolution in a cave in eogenetic limestone occurred due to increases in vadose CO₂ gas concentrations and subsequent dissolution of CO₂ into groundwater, not by mixing dissolution. We collected high‐resolution time series measurements (1 year) of specific conductivity (SpC), temperature, meteorological data, and synoptic water chemical composition from a water table cave in central Florida (Briar Cave). We found SpC, _pCO₂ and calcite undersaturation increased through late summer, when Briar Cave experienced little ventilation by outside air, and decreased through winter, when increased ventilation lowered cave CO_2(g) concentrations. We hypothesize dissolution occurred when water flowed from aquifer regions with low _pCO₂ into the cave, which had elevated _pCO₂. Elevated _pCO₂ would be promoted by fractures connecting the soil to the water table. Simple geochemical models demonstrate that changes in _pCO₂ of less than 1% along flow paths are an order of magnitude more efficient at dissolving limestone than mixing of vadose and phreatic water. We conclude that spatially or temporally variable vadose CO_2(g) concentrations are responsible for cave formation because mixing is too slow to generate observed cave sizes in the time available for formation. While this study emphasized dissolution, gas exchange between the atmosphere and karst aquifer vadose zones that is facilitated by conduits likely exerts important controls on other geochemical processes in limestone critical zones by transporting oxygen deep into vadose zones, creating redox boundaries that would not exist in the absence of caves. Copyright © 2014 John Wiley & Sons, Ltd.     

Radiation chemistry of H2O + O2 ices

The chemistry and spectroscopy of proton-irradiated H₂O + O₂ ices have been investigated in relation to the production of oxidants in icy satellite surfaces. Hydrogen peroxide (H₂O₂), ozone (O₃), and the hydroperoxy (HO₂) and hydrogen trioxide (HO₃) radicals have all been observed, and their temperature and dose dependent production trends have been measured. We find that O₂ aggregates form during the growth of H₂O + O₂ ice films, and the presence of these aggregates greatly affects the HO₂ and H₂O₂ yields. In addition, we have found that the position of the spectral maximum of the ν₃ vibration of O₃ shifts with ice composition, giving an indication of the degree of dispersion of O₃ molecules within the ice. We discuss the relevance of these measurements to icy satellite surfaces.     

Implications of Arctic industrial growth and strategies to mitigate future vessel and fishing gear impacts on bowhead whales

The objective of this paper was to investigate and illustrate how insights gained from experience managing human activities in order to protect North Atlantic right whales (Eubalaena glacialis) along the heavily industrialized east coast of North America might be applied in the Arctic, where bowhead whales (Balaena mysticetus) face some of the same risks as right whales. The reduced extent and thickness of sea ice and the resultant longer open-water season have major, complex implications for the Arctic marine ecosystem. Increased maritime ship traffic and commercial fishing in the Arctic are bound to affect bowheads and Native (indigenous) hunting communities who depend on whales for subsistence and cultural identity. Bowheads and right whales were greatly depleted by commercial whaling in the 19th and early 20th centuries. While the Western Arctic bowhead population has been recovering steadily in recent decades, North Atlantic right whales remain highly endangered because of persistent lethal and sublethal vessel strikes and frequent entanglement in commercial fishing gear. Entanglement can be transitory or persistent, with debilitation lasting for months before the animal finally succumbs. Vessel strike and fishing gear trauma has been documented in bowheads, but at a much lower rate than in right whales. Initiatives intended to mitigate the impacts of ship traffic on North Atlantic right whales have included speed limits and routing changes. Those meant to reduce the incidence and severity of entanglements include the modification of gear design and gear deployment practices. Management measures need to be considered in advance in the Arctic in order to minimize the risks to bowhead whales as shipping and industrial fishing expand in the Arctic with ice retreat.     

Combining historical and process perspectives to infer ranges of geomorphic variability and inform river restoration in a wandering gravel‐bed river

Restoration approaches such as dam removal and channel reconstruction have moved beyond the realm of small streams and are being applied to larger rivers. This development has substantial economic and ecological implications but may test gaps in our understanding of larger river systems and of restoration science. We examine how information about historical ranges of geomorphic variability can inform stream restoration in the context of the Clark Fork River, Montana, focusing on a study reach where one of the largest restoration projects to date was implemented, upstream of the recently removed Milltown Dam. Analysis of historical sources and aerial photographs of the Clark Fork River's pre‐mining, mining, and more recent history suggest that a wandering channel pattern has persisted despite variations in sediment supply and transport capacity. Predictive metrics for channel pattern also suggest a wandering pattern, transitional between braided and meandering, in this geomorphic setting. These analyses suggest that the creation of a single‐thread meandering channel, which incorporates structures to limit erosion and channel movement, is inconsistent with the historical range of variability in this reach. The perils of restoring channels to a condition different than the historical range of variability for their geomorphic setting were illustrated on the Clark Fork by flood‐induced avulsions of the restored channel that occurred soon after project construction. Application of an experimental approach to restoration, founded on the method of multiple working hypotheses, provides a means for embracing uncertainty, can maximize the potential for site‐specific restoration success, and can foster advances in restoration science. Copyright © 2012 John Wiley & Sons, Ltd.     

Variations in sediment thickness and type along the northern Philippine Sea Plate at the Nankai Trough

Abstract   We documented regional and local variations in basement relief, sediment thickness, and sediment type in the Shikoku Basin, northern Philippine Sea Plate, which is subducting at the Nankai Trough. Seismic reflection data, tied with ocean drilling program drill cores, reveal that variations in the incoming sediment sequences are correlated with basement topography. We mapped the three-dimensional seismic facies distribution and measured representative seismic sequences and units. Trench-parallel seismic profiles show three regional provinces in the Shikoku Basin that are distinguished by the magnitude of basement relief and sediment thickness: Western (<200–400 m basement relief, >600 m sediment thickness), Central (>1500 m relief, ∼2000 m sediments), and Eastern (<600 m relief, ∼1200 m sediments) provinces. The total thickness of sediment in basement lows is as much as six times greater than that over basement highs. Turbidite sedimentation in the Shikoku Basin reflects basement control on deposition, leading to the local presence or absence of turbidite units deposited during the middle Oligocene to the middle Miocene. During the first phase of sedimentation, most basement lows were filled with turbidites, resulting in smooth seafloor morphology that does not reflect basement relief. A second phase of turbidite deposition in the Eastern Province was accompanied by significant amounts of hemipelagic sediments interbedded with turbidite layers compared to the other provinces because of its close proximity to the Izu–Bonin Island Arc. Both regional and local variations in basement topography and sediment thickness/type have caused lateral heterogeneities on the underthrusting plate that will, in turn, influence lateral fluid flow along the Nankai accretionary prism.