Headwaters drive streamflow and lowland tracer export in a large-scale humid tropical catchment

Headwaters are generally assumed to contribute the majority of water to downstream users, but how much water, of what quality and where it is generated are rarely known in the humid tropics. Here, using monthly monitoring in the data scarce (2,370 km²) San Carlos catchment in northeastern Costa Rica, we determined runoff-area relationships linked to geochemical and isotope tracers. We established 46 monitoring sites covering the full range of climatic, land use and geological gradients in the catchment. Regression and cluster analysis revealed unique spatial patterns and hydrologically functional landscape units. These units were used for seasonal and annual Bayesian tracer mixing models to assess spatial water source contributions to the outlet. Generally, the Bayesian mixing analysis showed that the chemical and isotopic imprint at the outlet is throughout the year dominated by the adjacent lowland catchments (68%) with much less tracer influence from the headwaters. However, the headwater catchments contributed the bulk of water and tracers to the outlet during the dry season (>50%) despite covering less than half of the total catchment area. Additionally, flow volumes seemed to be linearly scaled by area maintaining a link between the headwaters and the outlet particularly during high flows of the rainy season. Stable isotopes indicated mean recharge elevations above the mean catchment altitude, which further supports that headwaters were the primary source of downstream water. Our spatially detailed “snap-shot” sampling enabled a viable alternative source of large-scale hydrological process knowledge in the humid tropics with limited data availability.     

Influence of turbidity and aeration on the albedo of mountain streams

Stream surface albedo plays a key role in the energy balance of rivers and streams that are exposed to direct solar radiation. Most physically based analyses and models have incorporated a constant stream albedo between 0.03 and 0.10, based primarily on measurements from low‐gradient streams with low suspended sediment concentrations. However, albedo should vary with solar elevation angle, suspended sediment concentration, aeration, and fraction of direct versus diffuse radiation. The objective of this study was to quantify the dependence of albedo of mountain streams on the controlling factors and to develop a predictive model for use in physically based analysis and modelling of stream temperature, especially for future climate and land‐use scenarios. Stream surface albedo was measured at nine sites with a variety of gradients and suspended sediment characteristics in the southern Coast Mountains of British Columbia, Canada. As expected, albedo of low‐gradient, non‐white water (flatwater) streams increased with solar elevation angle, suspended sediment concentration, and proportion of diffuse to direct solar radiation, ranging between 0.025 during cloudy periods over clear water to 0.25 for turbid water at elevation angles of less than 20°. Albedo was enhanced in steep reaches or at channel steps and cascades where flow was visibly aerated, with a range of 0.09 to 0.33. In clear weather, albedo exhibited notable diurnal variability at flatwater sampling sites. For example, during late summer, surface albedo typically fluctuated between 0.08 and 0.15 on a daily basis at a flatwater site on the highly turbid, glacier‐fed Lillooet River. Multiple regression models explained approximately 60% and 40% of the variance under cross validation for flatwater and white water data subsets, respectively, with corresponding root mean square errors of approximately 0.02 and 0.06.     

The Tantalite Valley shear zone — a major locus for igneous activity in Southern Namibia (South West Africa)?

The Tantalite Valley Shear Zone is a major Precambrian, southeast-trending tectonic lineament extending for some 500 km (possibly as much as 800 km) along strike in southern Namibia (South West Africa) and the northern Cape Province of South Africa. A minimum right-lateral displacement of 85 km has been estimated for this shear zone, which is one of a number with similar orientations found in southwestern Africa. The shear zones may represent slip-lines produced during continental collision about 1000–1300 m.y. B.P.The shear zones have acted as the locus for the intrusion of high-alumina tholeiitic magmas which have led to the development of a number of mafic to ultramafic complexes situated in or near the zones, and particularly the Tantalite Valley Shear Zone. Igneous activity and tectonism took place over an extended period of time and some bodies have been partly or completely metamorphosed to metagabbro or amphibolite.Three complexes have been studied in detail and they are geochemically distinct from each other, such that they cannot be related to one another by simple processes of fractionation although the rock types within any one complex may be so related. All show broad similarities in that they are depleted in lithophile elements (Ba, Rb, Sr, Nb, Zr) and enriched in nickel relative to similar basalts found elsewhere.     

Trapped solar and cosmogenic noble gas abundances in Apollo 15 and 16 deep drill samples

Abundances and isotopic compositions of all the stable noble gases have been measured in 19 different depths of the Apollo 15 deep drill core, 7 different depths of the Apollo 16 deep drill core, and in several surface fines and breccias. All samples analyzed from both drill cores contain large concentrations of solar wind implanted gases, which demonstrates that even the deepest layers of both cores have experienced a lunar surface history. For the Apollo 15 core samples, trapped⁴He concentrations are constant to within a factor of two; elemental ratios show even greater similarities with mean values of⁴He/²²Ne= 683±44,²²Ne/³⁶Ar= 0.439±0.057,³⁶Ar/⁸⁴Kr= 1.60±0.11·10³, and⁸⁴Kr/¹³²Xe= 5.92±0.74. Apollo 16 core samples show distinctly lower⁴He contents,⁴He/²²Ne(567±74), and²²Ne/³⁶Ar(0.229±0.024), but their heavy-element ratios are essentially identical to Apollo 15 core samples. Apollo 16 surface fines also show lower values of⁴He/²²Ne and²²Ne/³⁶Ar. This phenomenon is attributed to greater fractionation during gas loss because of the higher plagioclase contents of Apollo 16 fines. Of these four elemental ratios as measured in both cores, only the²²Ne/³⁶Ar for the Apollo 15 core shows an apparent depth dependance. No unambiguous evidence was seen in these core materials of appreciable variations in the composition of the solar wind. Calculated concentrations of cosmic ray-produced²¹Ne,⁸⁰Kr, and¹²⁶Xe for the Apollo 15 core showed nearly flat (within a factor of two) depth profiles, but with smaller random concentration variations over depths of a few cm. These data are not consistent with a short-term core accretion model from non-irradiated regolith. The Apollo 15 core data are consistent with a combined accretion plus static time of a few hundred million years, and also indicate variable pre-accretion irradiation of core material. The lack of large variations in solar wind gas contents across core layers is also consistent with appreciable pre-accretion irradiation. Depth profiles of cosmogenic gases in the Apollo 16 core show considerably larger concentrations of cosmogenic gases below ～65 cm depth than above. This pattern may be interpreted either as an accretionary process, or by a more recent deposition of regolith to the upper ～70 cm of the core. Cosmogenic gas concentrations of several Apollo 16 fines and breccias are consistent with ages of North Ray Crater and South Ray Crater of ～50·10⁶ and ～2·10⁶ yr, respectively.     

Multi‐decadal water table manipulation alters peatland hydraulic structure and moisture retention

A peatland complex disturbed by berm construction in the 1950s was used to examine the long‐term impact of water table (WT) manipulation on peatland hydraulic properties and moisture retention at three adjacent sites with increasing depth to WT (WET, INTermediate reference and DRY). Saturated hydraulic conductivity (K_s) was found to decrease with depth by several orders of magnitude over a depth of 1–1.5 m at all sites. The depth dependence of WT response to rainfall was similar across sites: WT response increased from 1 : 1 at the surface, to 5 : 1 at 50 cm depth. While surface specific yield (S_y) values were similar across all sites, it decreased with depth at a rate of 0.014 cm^?1 in hollows and 0.007 cm^?1 in hummocks. Bulk density (ρ_b) exhibited similar depth‐dependent trends as S_y and explains a high amount of variance (r² > 0.69) in moisture retention across a range of pore water pressures (?15 to ?500 cm H₂O). Because of higher ρ_b, hollow peat had greater moisture retention, where site effects were minimal. However, the estimated residual water content for surface Sphagnum samples, while on average lower in hummocks (0.082 m³ m^?3) versus hollows (0.087 m³ m^?3), increased from WET (0.058 m³ m^?3) to INT (0.088 m³ m^?3) to DRY (0.108 m³ m^?3) which has important implications for moisture stress under conditions of persistent WT drawdown. Given the potential importance of microtopographic succession for altering peatland hydraulic structure, our findings point to the need for a better understanding of what controls the relative height and proportional coverage of hummocks in relation to long‐term disturbance‐response dynamics. Copyright © 2014 John Wiley & Sons, Ltd.     

Dissolution in a variably confined carbonate platform: effects of allogenic runoff,hydraulic damming of groundwater inputs,and surface–groundwater exchange at the basin scale

In variably confined carbonate platforms, impermeable confining units collect rainfall over large areas and deliver runoff to rivers or conduits in unconfined portions of platforms. Runoff can increase river stage or conduit heads in unconfined portions of platforms faster than local infiltration of rainfall can increase groundwater heads, causing hydraulic gradients between rivers, conduits and the aquifer to reverse. Gradient reversals cause flood waters to flow from rivers and conduits into the aquifer where they can dissolve limestone. Previous work on impacts of gradient reversals on dissolution has primarily emphasized individual caves and little research has been conducted at basin scales. To address this gap in knowledge, we used legacy data to assess how a gradient of aquifer confinement across the Suwannee River Basin, north‐central Florida affected locations, magnitudes and processes of dissolution during 2005–2007, a period with extreme ranges of discharge. During intense rain events, runoff from the confining unit increased river stage above groundwater heads in unconfined portions of the platform, hydraulically damming inputs of groundwater along a 200 km reach of river. Hydraulic damming allowed allogenic runoff with SI_CAL < ?4 to fill the entire river channel and flow into the aquifer via reversing springs. Storage of runoff in the aquifer decreased peak river discharges downstream and contributed to dissolution within the aquifer. Temporary storage of allogenic runoff in karst aquifers represents hyporheic exchange at a scale that is larger than found in streams flowing over non‐karst aquifers because conduits in karst aquifers extend the area available for exchange beyond river beds deep into aquifers. Post‐depositional porosity in variably confined carbonate platforms should thus be enhanced along rivers that originate on confining units. This distribution should be considered in models of porosity distribution used to manage water and hydrocarbon resources in carbonate rocks. Copyright © 2013 John Wiley & Sons, Ltd.     

Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano,Hawaii

Eighteen basalts and some volcanic gases from the submarine and subaerial parts of Kilauea volcano were analyzed for the concentration and isotope ratios of sulfur. By means of a newly developed technique, sulfide and sulfate sulfur in the basalts were separately but simultaneously determined. The submarine basalt has 700 ± 100 ppm total sulfur with δ³⁴S_Σs of $\text{0.7 ± 0.1 ‰}$. The sulfate/sulfide molar ratio ranges from 0.15 to 0.56 and the fractionation factor between sulfate and sulfide is $\text{+7.5 ± 1.5‰}$. On the other hand, the concentration and δ³⁴S_Σs values of the total sulfur in the subaerial basalt are reduced to 150 ± 50 ppm and $\text{?0.8 ± 0.2‰}$, respectively. The sulfate to sulfide ratio and the fractionation factor between them are also smaller, 0.01 to 0.25 and +3.0‰, respectively. Chemical and isotopic evidence strongly suggests that sulfate and sulfide in the submarine basalt are in chemical and isotopic equilibria with each other at magmatic conditions. Their relative abundance and the isotope fractionation factors may be used to estimate the $\text{?o}{}_2$ and temperature of these basalts at the time of their extrusion onto the sea floor. The observed change in sulfur chemistry and isotopic ratios from the submarine to subaerial basalts can be interpreted as degassing of the SO₂ from basalt thereby depleting sulfate and ³⁴S in basalt.The volcanic sulfur gases, predominantly SO₂, from the 1971 and 1974 fissures in Kilauea Crater have δ³⁴S values of 0.8 to 0.9%., slightly heavier than the total sulfur in the submarine basalts and definitely heavier than the subaerial basalts, in accord with the above model. However, the δ³⁴S value of sulfur gases (largely SO₂) from Sulfur Bank is 8.0%., implying a secondary origin of the sulfur. The δ³⁴S values of native sulfur deposits at various sites of Kilauea and Mauna Loa volcanos, sulfate ions of four deep wells and hydrogen sulfide from a geothermal well along the east rift zone are also reported. The high δ³⁴S values (+5 to +6%._o) found for the hydrogen sulfide might be an indication of hot basaltseawater reaction beneath the east rift zone.     

Throughflow variability on a forested hillslope underlain by compacted glacial till

This study examined the spatial and temporal variability of throughflow in a shallow forest oil in terms of the controls exerted by topography, soil properties and the shape of the water table. Hillslope outflow was measured at nine troughs installed at a road cut, and hydraulic head was measured at 37 piezometers installed to the confining till surface at the base of the soil. At the lowest flows, the distribution of throughflow across the hillslope conformed reasonably to the distribution of upslope contributing area computed from the topography of the confining basal till layer. At higher flows, however, the distribution of throughflow shifted, partly as a result of changes in the orientation in flow tubes as the piezometric surface changed. At high flows, surface topography appeared to provide a reasonable proxy for the shape of the water table. Shunting of water through discrete macropores, however, can apparently overwhelm topographic controls on throughflow, at least for slope widths less than about 10 m. Effective hydraulic conductivities computed at the scale of the troughs varied over two orders of magnitude and displayed no consistent relationship with the thickness of the saturated layer. Estimates at the plot scale (c. 10 m hillslope width) were far less variable, and for higher flows displayed an approximately linear relationship with saturated zone thickness. Copyright © 2000 John Wiley & Sons, Ltd.     

A comparison of plastic and plankton in the north Pacific central gyre

The potential for ingestion of plastic particles by open ocean filter feeders was assessed by measuring the relative abundance and mass of neustonic plastic and zooplankton in surface waters under the central atmospheric high-pressure cells of the North Pacific Ocean. Neuston samples were collected at 11 random sites, using a manta trawl lined with 333 u mesh. The abundance and mass of neustonic plastic was the largest recorded anywhere in the Pacific Ocean at 334 271 pieces km² and 5114 g km², respectively. Plankton abundance was approximately five times higher than that of plastic, but the mass of plastic was approximately six times that of plankton. The most frequently sampled types of identifiable plastic were thin films, polypropylene/monofilament line and unidentified plastic, most of which were miscellaneous fragments. Cumulatively, these three types accounted for 98% of the total number of plastic pieces.     

Spatial variations of the décollement/protodécollement zone and their implications: A 3-D seismic inversion study of the northern Barbados accretionary prism

We conducted a 3‐D seismic inversion study to investigate spatial variations of physical properties of the décollement zone (DZ) and protodécollement zone (PDZ) under the northern Barbados accretionary prism. Significant spatial variations of physical properties were observed in the PDZ seaward of the thrust front from the inversion data. The density generally increases southward with a few localized low‐density patches. A lower density commonly corresponds to a thicker PDZ, suggesting that the paleomorphology may at least partially control the variations of the physical properties. Similar low‐density patches were also found in the DZ. These features may be inherited from those of the PDZ and enhanced after subduction through localized arrested consolidation. Under the prism toe, the density of the DZ increases landward. This trend may mainly result from shear‐induced consolidation of the DZ but may also be related to landward increasing tectonic loading. Significant north–south differences in density and, thus, porosity and strength of the PDZ, are observed and these differences may continue into the DZ. A stronger DZ is likely responsible for a larger prism taper observed in the southern area of the prism toe. The larger taper, thus more horizontal shortening, coupled with a thinner sediment sheet above the PDZ in the southern area, may cause a relative retreat of the thrust front and a pronounced change in strike of the sequence thrusts south of seismic Line 690. The north–south differences may ultimately have originated in the approach of a structurally higher segment of the Tiburon Rise. The Tiburon Rise affects regional morphology and, thus, it controls the sedimentation and physical properties of the PDZ. It may also control sediment accumulation above the PDZ. Therefore, the sedimentational change induced by the structural high of the Tiburon Rise, in turn, resulted in structural change of the prism in the southern area.