ICP-AES双向测定土壤中铜、锰、钒、锌金属元素的对比研究

本文采用电感耦合等离子体发射光谱法(ICP-AES)轴向和径向测定土壤中铜、锰、钒、锌四种金属元素的含量,比较分析了在不同三酸[硝酸(HNO3)、氢氟酸(HF)、高氯酸(HCLO4)]用量(配比)下对5种国家标准物质的消解性差异和对四种元素轴向和径向测定结果的影响。结果表明:(1)消解过程中f、g、h配比的三酸消解速度较快,d、e次之,a、b、c相对较慢。(2)对于低含量试样径向观测对轴向观测灵敏度较高;同时三酸消解用量不同,其结果差异性不明显,而发现中高含量范围内横向观测比径向观测相对偏差较小,说明了轴向观测效果较好。(3)通过采用f配比的三酸经过前处理进行稳定性分析,结果可知标准偏差(SD)均小于10,相对标准偏差(RSD)均小于5%,对于高含量锰元素横向观测较径向观测稳定性高,其余元素差异性不明显。     

基于连续损伤的水平井射孔-近井筒三维破裂模拟

射孔作为井筒与储层之间的液流通道,是水力压裂过程中的重要可控性参数。为研究水平井射孔-近井筒破裂机制,采用岩层变形-流体渗流方程描述应力状态变化,应用连续损伤破裂单元表征三维破裂位置与形态演化,并开发有限元求解程序模拟分析了射孔对水平井初始破裂压力、破裂位置及近井筒裂缝复杂性的调控作用。通过与解析模型及射孔压裂物理模型试验结果对比,验证了模型及有限元程序的有效性;水平井破裂压力数值分析结果与现场测试数据吻合较好。研究表明：射孔可调控水平井破裂压力与初始破裂位置,同时对近井筒区域裂缝扩展形态影响显著。通过优化射孔参数可以引导初始破裂向最优破裂面扩展、有效降低破裂压力,减小由于螺旋射孔空间排布引起的水平井近井筒裂缝迂曲与复杂程度,提高致密油气藏压裂改造效果。     

珠江三角洲平原区土壤Pb元素地球化学特征及其影响因素研究

以珠江三角洲平原为研究区域,对其7个区县102件水稻根系土样品进行土壤理化参数及Pb形态分析,探讨在第四系分布区土壤Pb全量及Pb活动态含量的特征及影响因素。结果表明:全部供试土壤样品中Pb元素平均含量为46.47mg/kg,略高于广东省土壤Pb含量背景值(36mg/kg),表现出一定的累积趋势。研究区自西北陆相沉积区至南部海陆交互相沉积区,元素含量增高。Pb元素主要以残渣态和铁锰氧化物形态赋存在土壤中,迁移能力弱。影响土壤Pb全量的因素主要有Al2O3、K2O、Tl、Mo;影响土壤Pb活动态的因素有Pb全量、pH、有机质、CEC、P、TFe2O3、Mn;其中,p H是控制Pb元素活动性的最主要因素。     

A Quantitative Evaluation of Shale Gas Content in Different Occurrence States of the Longmaxi Formation: A New Insight from Well JY-A in the Fuling Shale Gas Field,Sichuan Basin

Comprehensive quantitative evaluation of shale gas content and the controlling factors in different occurrence states is of great significance for accurately assessing gas-bearing capacity and providing effective well-production strategies. A total of 122 core samples from well JY-A in the Fuling shale gas field were studied to reveal the characteristics of S_1 l shale,15 of which were selected to further predict the shale gas content in different occurrence states, which are dependent on geological factors in the thermal evolution process. Geological parameters were researched by a number of laboratory programs, and the factors influential in controlling shale gas content were extracted by both PCA and GRA methods and prediction models were confirmed by the BE method using SPSS software. Results reveal that the adsorbed gas content is mainly controlled by TOC, Ro, SSA, PD and pyrite content, and the free gas content is mainly controlled by S_2, quartz content, gas saturation and formation pressure for S_1 l in well JY-A. Three methods, including the on-site gas desorption method, the empirical formula method, and the multiple regression analysis method were used in combination to evaluate the shale gas capacity of well JY-A, all of which show that the overall shale gas content of well JY-A is in the range of 2.0–5.0 m~3/t and that the free gas ratio is about 50%, lower than that of well JY-1. Cause analysis further confirms the tectonics and preservation conditions of S_1 l in the geological processes, especially the influence of eastern boundary faults on well JY-A, as the fundamental reasons for the differences in shale gas enrichment in the Jiaoshiba area.     

白云凹陷第三系储层中铁白云石的成因机理及与CO2活动的关系

白云凹陷第三系储层中发育大量的铁白云石,受研究区热流背景的影响,铁白云石主要见于高地温梯度地区埋深1000～3000m、地层温度60～130℃的浅—中部地层中及CO_2热流体活动区域。铁白云石的δ~(13)C值(-2.83‰～-1.83‰)具有无机成因的特征,与研究区气藏中幔源岩浆成因CO_2的δ~(13)C值较为一致,铁白云石的δ~(18)O值(-9.45‰～-5.37‰)和~(87)Sr/~(86)Sr值(0.7101～0.7161)也反映了其沉淀受到深部热流体活动的影响。以两口典型CO_2气井为例,储层中流体包裹体均一温度及蒙脱石向伊利石的演化特征证明储层经历了热流体侵入;CO_2热流体活动区域不仅是铁白云石集中分布地带,并出现片钠铝石+铁白云石+菱铁矿等示踪CO_2运移、聚集的自生矿物组合。地层中铁白云石、高岭石含量与气藏中CO_2的含量呈正相关关系,绿泥石含量与CO_2、铁白云石含量呈反消长关系。高地温梯度地区丰富的CO_2热流体活动是该地区储层中铁白云石沉淀与含量高的重要原因,无机岩浆成因CO_2是铁白云石沉淀的主要碳源,CO_2热流体充注造成绿泥石等黏土矿物异常转化,为铁白云石沉淀提供了所需的Fe~(2+)、Mg~(2+)离子。     

广西锑矿成矿规律研究

广西锑矿资源丰富,为研究其成矿规律,在前人工作的基础上,较为全面地总结了广西锑矿的勘查开发、资源分布、矿床成因、空间分布特征、主要成矿时代及成矿规律等,并划分出了岩浆热液型、浅成中-低温热液型和风化型3个三级矿床成因类型,其中岩浆热液型为广西主要的锑矿床类型.在三级矿床成因类型的基础上共划分出7个四级成因类型,其中复合...     

黄土高原植被恢复潜力研究

黄土高原从1999年开始大规模退耕还林（草）,植被覆盖发生了较大变化,对黄土高原植被恢复现状和恢复潜力进行评估具有重要意义。本文使用1999-2013年SPOT VEG NDVI数据,采用线性回归、Hurst指数分析法、统计学方法以及地理空间分析技术,对黄土高原植被恢复状况和潜力进行了探讨。结论主要为：① 1999年退耕还林（草）以来,黄土高原植被覆盖度呈显著上升趋势,黄土高原三分之二地区的植被将会持续改善;② 植被响应曲线分析表明,黄土区植被覆盖度和干旱指数呈显著的指数关系,且缓坡相关性大于陡坡。土石山区植被响应函数为线性函数,相关系数下降;③ 整个黄土高原地区平均植被恢复潜力为69.75%。植被恢复潜力值东南高而西北低,黄土高原东南地区植被恢复状况较好,其植被恢复潜力指数较小,而植被恢复潜力指数较高的地区主要为北方风沙区及西部丘陵沟壑区;④ 不同降水量条件下,植被恢复速度差别显著,其中降水量在375~575 mm之间的地区,植被恢复最快。植被恢复措施应该“因水制宜”,避免因造林带来的土壤干化加剧。研究结果以期为黄土高原生态文明建设提供科学支撑。     

汉江上游黄土常量元素地球化学特征及区域对比

本文对汉江上游黄土的常量元素含量及相关地球化学参数CIA、Na/K、淋溶系数、退碱系数、残积系数等进行了系统分析。结果显示：① 汉江黄土的主要化学成分为SiO₂、Al₂O₃和Fe₂O₃,三者含量总和达767.3 g/kg;常量元素含量大小排序为SiO₂>Al₂O₃>Fe₂O₃>K₂O>MgO>Na₂O>CaO。风化成壤过程中Na、Ca、Mg、Si发生不同程度的迁移淋溶,而Fe、Al、K相对富集。② 其风化成壤强度呈现从马兰黄土L₁→过渡性黄土L_t→古土壤S₀逐渐升高、全新世黄土L₀又降低的规律,记录了该区域气候经历了末次冰期（55.0-15.0 ka BP）冷干、早全新世（15.0-8.5 ka BP）增温增湿、中全新世（8.5-3.1 ka BP）达到最暖湿,晚全新世（3.1-0.0 ka BP）降温变干的演变过程。③ 汉江黄土与洛川、巫山、下蜀黄土的元素组合特征高度一致,不同地区常量元素（CaO除外）含量十分接近且UCC标准化值变幅均小于0.25,这暗示了它们风化之初具有相似的风成沉积基础;但不同区域黄土的化学风化强度差异明显,大致呈现洛川黄土<汉江黄土<巫山黄土<下蜀黄土的趋势,与中国现代季风气候的空间变化规律相吻合,即不同地区黄土风化程度差异主要是东亚季风变化影响的结果。     

珠江口盆地的沉积充填与珠江的形成演变

沉积物元素地球化学分析表明,南海北部地区沉积物渐新统与中新统明显不同,两者之间存在物源突变事件。这一沉积地质事件在时间上与南海扩张轴发生跳跃、滇西高原以及东喜马拉雅构造结的快速隆升等一系列地质构造事件十分吻合,是珠江以及珠江口盆地搬运—沉积—充填演化史上一次重大的转变。Ca/Si、CIA以及Al₂O₃等参数变化显示,珠江侵蚀区极有可能由渐新世近源硅酸盐为主的华南沿海地区拓展为中新世远达青藏高原东麓的云贵高原碳酸盐为主的地区,流域范围突然扩大。同时伴随沉积物供给增大,造成珠江口盆地从渐新世富砂为主的沉积堆积体系转变为中新世以来以泥为主的沉积堆积体系,显示出珠江的发育演化以及中新世以来的青藏高原隆升在南海北部的沉积充填演变中扮演了重要角色,对南海北部地区油气藏的形成影响深远。     

Structure of the Potential Vorticity of an Explosive Cyclone over the Eastern Asian Region in Late November 2013

An explosive extratropical cyclone(EC)over the Eastern Asian region that caused two shipwrecks is analyzed using ERA-Interim reanalysis data from the European Center for Medium-Range Weather Forecasts.Analyses of the evolution of the EC reveal that the positive potential vorticity(PV)at the upper-tropospheric level displays a hook-shaped structure during the mature period of the cyclone.The PV distribution forms a vertically coherent PV structure called a PV tower.The vertical distribution of the PV can induce and strengthen cyclonic circulation from the lower-to upper-levels of troposphere,which is an important deepening mechanism of explosive cyclone.The PV tower occurs approximately ten hours prior to the development of surface occlusion in the cyclone.The evolution of surface fronts closely follows the development of the horizontal upper-tropospheric PV.This tandem development is largely attributed to the ability of the positive upper-tropospheric PV and the PV tower to induce cyclonic circulation simultaneously.The kinematic wrap-up process of cyclonic circulation also accelerates the formation of warm occlusion.A conceptual model of the distributions of positive PV and potential temperature combining the perspectives of dynamic tropopause folding,PV tower,and atmospheric stability,including westward tilting and baroclinicity,is proposed.This model can illustrate the explosive deepening mechanism of ECs.The regions of convective instability and rainfall determined by this model are consistent with those identified from the actual observation.