Studies on the determination of inorganic iodine in seawater

Existing methods for the determination of the various forms of iodine present in seawater are laborious or unwieldy in use. This paper describes modified forms of the iodate and total iodine methods described by Barkley and Thompson (1960), a spectrophotometric procedure for iodate determination derived from Johannesson's (1958) work, and an automatic method for total iodine determination. Procedures for iodate and total-iodine determination which are suitable for use aboard ship, are recommended. Both procedures for iodate determination returned a standard deviation close to 0.5 μg/l when several replicate samples of a seawater containing approximately 30 μg/l of iodate-iodine were analysed. The automatic method for total iodine determination yielded a standard deviation of 0.8 μg/l by the repeated analysis of a seawater containing a total of approximately 50 μg/l of iodine. Suitable methods for the filtration and storage of seawater are also described.     

Beach accretion and erosion, Burullus-Gamasa coast, Egypt

Several areas of erosion and accretion were observed along the Burullus-Gamasa beach. The accreted sands are coarser and less sorted than the eroded ones. Differentiation between them could be achieved on the basis of their grain-size fractions, shape of grain-size distribution curves and statistical grain-size parameter relationships.     

Influence of structural flexibility and wave interference on dynamic behavior of idealized offshore platform

An approximate method is presented to estimate the hydrodynamic loading and structural response of an idealized offshore platform subjected to a regular train of linear surface waves. The platform is taken to consist of four bottom-mounted, flexible, circular cylinders supporting a rigid deck and is assumed to be aligned parallel to the incident wave direction. The response of each column is assumed to be one-dimensional and to be governed by linear beam theory. The solution technique for the fluid velocity potential involves replacing scattered waves by equivalent plane waves together with non-planar, first-correction terms, and can be shown to be a large spacing approximation.Numerical results are presented which show the effect of hydrodynamic interference and structural flexibility on the platform response.     

The Reproductive Cycle of Ophioderma brevispinum (Echinodermata: Ophiuroidea)

Abstract. .The reproductive cycle of the brittlestar Ophioderma brevispinum is described using histological and organ index data for a population in Massachusetts, U.S.A. The cycle consists of a one month mid-summer spawning phase followed by gametogenesis and gradual gonadal growth during the winter, and greatly accelerated gonadal growth from May to June. At the end of the spawning season, oogonia proliferate near the base of the ovary, and a continuous layer of spermatogonia lines the testis. As oocytes grow to a maximum diameter of 350 um, yolk granules accumulate and the cytoplasm becomes less basophilic. Prior to spawning, the testis becomes branched and sulcate, and a whorl of spermatozoa produced by columns of spermatids accumulates in the lumen. Comparisons between the reproductive cycles of different populations of O. brevispinum and its congeners support the hypothesis that temperature may be a critical exogenous factor, but definitely not the only factor, in the initiation and duration of the growth and spawning phases of the ophiuroid reproductive cycle.     

Kinetic studies of the rate of dissolution of silica and diatom tests in sea water

Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had dissolved.     

Uptake of plutonium from seawater and sediment by a marine polychaete worm

The results of the uptake of plutonium 239 from sediment by a marine polychaete wormNereis diversicolor is reported in the present paper. A comparison is made of the relative importance of two possible uptake pathways, sediment and seawater by which this worm may obtain its plutonium body-burden. Under the laboratory conditions used for the comparison of those two routes it would appear thatNereis obtains greater than 98% of its body activity from seawater.     

Evaporative weathering of petroleum residues: The age of pelagic tar

The rate of evaporative weathering of a component of crude oil residue is assumed to be proportional to its equilibrium vapor pressure and to the amount remaining in the sample. This model is tested using literature data on normal paraffin profiles of crude oil weathered artificially and gas chromatographic data on crude oil residues weathered on rocky shores. Semiquantitative agreement over the time range from 1 to 400 days is demonstrated. Application of the model to gas chromatograms of pelagic tar lumps collected at Station S near Bermuda in 1972 implies that most of these lumps were formed by fragmentation of much larger and older masses, some within less than one day of the time they were collected. The weathering of pelagic tar thus involves a great deal more physical fragmentation than was previously supposed.     

Kirsch problem and the lower natural frequencies of a clamped square-plate

A clamped square-plate is subjected to a uniform state of stress in the x-direction. The present study deals with the basic question of determining the variation of the lower natural frequencies of transverse vibration of a plate as a small diameter, central hole is made in it, introducing a stress concentration field.