The acquisition of thermoremanent magnetization by multidomain single-crystal titanomagnetite

Summary. Large, well-characterized single-crystals of titanomagnetite of approximate composition Fe_2.4Ti_0.6O₄ were ground into spheres and orientated along specific crystallographic axes. The field dependences of the thermoremanent magnetization (TRM) and the temperature dependences of the magnetic hysteresis properties were measured and evaluated against the available theoretical models. The models, of necessity simplifications of real materials, were unable to account for many features of the experimental curves. The discrepancies were partly resolved by consideration of the mode of blocking of each individual coercivity fraction. It was deduced that the domain-walls were pinned by both dislocation lines and by inclusions or voids. A fraction of the walls were not thermally blocked. They could however be thought of as being blocked isothermally as the applied field was relaxed. The proportion of remanence blocked in by each process was found to be dependent on the strength of the inducing field through the field dependence of the blocking temperatures. A simplified model, taking these effects into account, was developed. This predicts the main features of the TRM acquisition curve and of the alternating field and thermal demagnetization spectra.     

The October 4, 1994 Shikotan (Kurile Islands) Tsunamigenic Earthquake: An Open Problem on the Source Mechanism

—On October 4, 1994, an earthquake of magnitude M _w = 8.2 occurred in the western part of the Kurile Islands, generating a tsunami that has been well recorded along the entire coast of Japan. Previous works have shown that this earthquake does not represent a low angle thrust event, normally expected in a subduction zone, rather an intra-plate event rupturing through the slab. On the basis of the accepted mechanism, two fault models, representative of the nodal plane ambiguity, have been suggested. The goal of this work is to verify whether the tsunami simulations are able to rule out one of the two proposed fault models. Taking into account both fault models together with a heterogeneous slip along the fault, we have performed numerical simulations of the tsunami. All source models produce tide-gauge records in agreement with the observed ones. The limit of resolution of the performed simulations, estimated by means of a perturbed bathymetry, does not allow us to distinguish the best source model.     

Mn-oxides and sequestration of heavy metals in a suburban catchment basin of the Chesapeake Bay watershed

The Chesapeake Bay is greatly impacted by numerous pollutants including heavy metals and understanding the controls on the distribution of heavy metals in the watershed is critical to mitigation and remediation efforts in controlling this type of pollution. Clasts from a stormwater catchment basin draining a subdivision near George Mason University, Fairfax VA (38°50.090°N 78°19.204°W) were investigated using X-ray diffraction (XRD), Scanning electron microcopy (SEM) and energy dispersive spectroscopy (EDS) to determine the nature of Mn-oxide coatings and relationship to bound heavy metals. Mn-oxides are poorly crystalline and occur as subhedral to anhedral platy particles and more rarely as euhedral plates. Micronodules are a commonly observed texture. Chemical compositions of coatings are variable with average major constituent concentrations being Mn (33.38 wt%), Fe (11.88 wt%), Si (7.33 wt%), Al (5.03 wt%), and Ba (0.90 wt%). Heavy metals are found in the coatings with Zn being most prevalent, occurring in approximately 58% of analyses with an average concentration of (0.66 wt%). Minor amounts of Co, Ni, Pb, and Cl are observed. Heavy metals and Cl are interpreted as being derived from road pollution. Mn-oxides can serve as a sequestration mechanism for pollution but may also release heavy metals. Field and laboratory observations indicate Mn-oxides occurring on the surface of the clasts can be mechanically mobilized. This is a mechanism for transporting heavy metals into the Chesapeake Bay watershed. Deicing agents may serve as a mechanism to release heavy metals through cation exchange and increased ionic strength. This is the first detailed mineralogical investigation of Mn-oxides and the roles they may play in pollution in the Chesapeake Bay.     

Sedimentary and faunal events revealed by a revised correlation of post‐glacial Hirnantian (Late Ordovician) strata in the Welsh Basin,UK

The discovery of a previously unrecognized unconformity and of new faunas in the type Llandovery area underpins a revised correlation of Hirnantian strata in mid Wales. This has revealed the sedimentary and faunal events which affected the Lower Palaeozoic Welsh Basin during the global rise in sea level that followed the end‐Ordovician glacial maximum and has allowed their interpretation in the context of local and global influences. In peri‐basinal shelfal settings the onset of post‐glacial deepening is recorded by an unfossiliferous, transgressive shoreface sequence (Cwm Clyd Sandstone and Garth House formations) which rests unconformably on Rawtheyan rocks, deformed during an episode of pre‐Hirnantian tectonism. In the deep water facies of the basin centre, this same sequence boundary is now recognized as the contact between fine‐grained, re‐sedimented mudstones and an underlying regressive sequence of turbidite sandstones and conglomerates; it is at a level lower than previously cited and calls into question the established lithostratigraphy. In younger Hirnantian strata, graptolites associated with the newly recognized Ystradwalter Member (Chwefri Formation) demonstrate that this distal shelf unit correlates with the persculptus graptolite‐bearing Mottled Mudstone Member of the basinal succession. Together these members record an important macrofaunal recolonization of the Welsh Basin and mark a key event in the post‐glacial transgression. Further deepening saw the establishment of a stratified water column and the imposition of anoxic bottom water conditions across the basin floor. These post‐glacial Hirnantian events are consistent with the re‐establishment of connections between a silled Welsh Basin and the open Iapetus Ocean. However, a comparison with other areas suggests that each event records a separate deepening episode within a pulsed glacio‐eustatic transgression, while also reflecting changes in post‐glacial climate and patterns of oceanic circulation and associated biotic flux. British Geological Survey © NERC 2009. All rights reserved.     

Anomalous increase in the foF2 critical frequency prior to the Spanish earthquake of May 11, 2011

A study of variations in the critical frequency of the F2 layer (foF2) prior to a shallow-focus eartquake with a magnitude M = 5.1 which occurred in Spain on May 11, 2011, is carried out. The obtained results show that a positive disturbance in the foF2 value was observed at the ionospheric Del’ebre station, which is the closest to the earthquake epicenter. At the same time, no disturbances in foF2 are revealed at ionospheric stations located at a greater distance from the epicenter. This fact makes it possible to conclude that the positive disturbance in the F2 layer observed at the Del’ebre station could have a sesmogenic nature.     

Solar and meteoritic abundance of silicon

Recent lifetime measurements on excited electronic states of neutral silicon (Beckeret al., Phys. Lett. In press, 1980) lead to a reassessment of widely used experimental transition probabilities Garz, Astron. Astrophys., 26, 471–477, 1973 of Si I lines. This translates into a 25% downward revision of the Si abundance determined from the solar spectrum.A solar atomic ratio, Si/Ca = 15.5 is inferred. This value coincides with that found in carbonaceous chondrites, but contrasts with ordinary and enstatite chondrites.     

Tinnunculite,C<Subscript>5</Subscript>H<Subscript>4</Subscript>N<Subscript>4</Subscript>O<Subscript>3</Subscript> · 2H<Subscript>2</Subscript>O: Occurrences on the Kola Peninsula and Redefinition and Validation as a Mineral Species

Based on a study of samples found in the Khibiny (Mt. Rasvumchorr: the holotype) and Lovozero (Mts Alluaiv and Vavnbed) alkaline complexes on the Kola Peninsula, Russia, tinnunculite was approved by the IMA Commission on New Minerals, Nomenclature, and Classification as a valid mineral species (IMA no. 2015-02la) and, taking into account a revisory examination of the original material from burnt dumps of coal mines in the southern Urals, it was redefined as crystalline uric acid dihydrate (UAD), C₅H₄N₄O₃ · 2H₂O. Tinnunculite is poultry manure mineralized in biogeochemical systems, which could be defined as “guano microdeposits.” The mineral occurs as prismatic or tabular crystals up to 0.01 × 0.1 × 0.2 mm in size and clusters of them, as well as crystalline or microglobular crusts. Tinnunculite is transparent or translucent, colorless, white, yellowish, reddish or pale lilac. Crystals show vitreous luster. The mineral is soft and brittle, with a distinct (010) cleavage. D_calc = 1.68 g/cm³ (holotype). Tinnunculite is optically biaxial (–), α = 1.503(3), β = 1.712(3), γ = 1.74(1), 2V_obs = 40(10)°. The IR spectrum is given. The chemical composition of the holotype sample (electron microprobe data, content of H is calculated by UAD stoichiometry) is as follows, wt %: 37.5 О, 28.4 С, 27.0 N, 3.8 H_calc, total 96.7. The empirical formula calculated on the basis of (C + N+ O) = 14 apfu is: C_4.99H₈N_4.07O_4.94. Tinnunculite is monoclinic, space group (by analogy with synthetic UAD) P2₁/c. The unit cell parameters of the holotype sample (single crystal XRD data) are a = 7.37(4), b = 6.326(16), c = 17.59(4) Å, β = 90(1)°, V = 820(5) ų, Z = 4. The strongest reflections in the XRD pattern (d, Å–I[hkl]) are 8.82–84[002], 5.97–15[011], 5.63–24[102?, 102], 4.22–22[112], 3.24–27[114?,114], 3.18–100[210], 3.12–44[211?, 211], 2.576–14[024].     

Light curves of the trans-Neptunian objects 1996 TP66 and 1994 VK8

We have obtained a number of CCD images of two trans-Neptunian objects, 1994 VK8 and 1996 TP66, over two nights. The changes in magnitude of these objects have been examined, in a search for periodic variation. In the case of 1996 TP66, nothing other than random noise can be found to within the errors of ∼0.04 mag. Although a periodic signal is found for 1994 VK8, it appears to be an artefact, as the same frequency appears in the variation of sky brightness and is probably due to the sampling of the data. However, 1994 VK8 does exhibit a variation of ∼0.5 mag. This would suggest either significant non-sphericity or a change in surface composition over a large area. In either case 1994 VK8 warrants further investigation.     

The Use of Geographically Weighted Regression for Spatial Prediction: An Evaluation of Models Using Simulated Data Sets

Increasingly, the geographically weighted regression (GWR) model is being used for spatial prediction rather than for inference. Our study compares GWR as a predictor to (a) its global counterpart of multiple linear regression (MLR); (b) traditional geostatistical models such as ordinary kriging (OK) and universal kriging (UK), with MLR as a mean component; and (c) hybrids, where kriging models are specified with GWR as a mean component. For this purpose, we test the performance of each model on data simulated with differing levels of spatial heterogeneity (with respect to data relationships in the mean process) and spatial autocorrelation (in the residual process). Our results demonstrate that kriging (in a UK form) should be the preferred predictor, reflecting its optimal statistical properties. However the GWR-kriging hybrids perform with merit and, as such, a predictor of this form may provide a worthy alternative to UK for particular (non-stationary relationship) situations when UK models cannot be reliably calibrated. GWR predictors tend to perform more poorly than their more complex GWR-kriging counterparts, but both GWR-based models are useful in that they provide extra information on the spatial processes generating the data that are being predicted.     

Observational maps of the moments of strong line profiles on the solar disk

Using the method of solar bidimensional spectroscopy based on the Universal Birefringent Filter (UBF), we have determined the bidimensional maps of moments of some chromospheric lines. The observational material, referring to a quiet region on the disk center, have been acquired with the UBF of the NSO at Sacramento Peak on Aug. 27,1985. In this note we present the work in progress and the new observational aspects arising from this diagnostic method.Visiting astronomers at the National Solar Observatory/Sacramento Peak, operated by the AURA under contract with the NSF