Partition of arsenic in soils sediments and the origin of naturally elevated concentrations in groundwater of the southern pampa region (Argentina)

Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L⁻¹) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L⁻¹; in 27% As concentrations ranged from 10 to 50 μg L⁻¹ and in 58% it reached 60–500 μg L⁻¹. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r ² = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r ² = 0.85) and As–Cr (p < 0.05; r ² = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.     

Collision of comets with meteoroids

Statistical analysis of the quantity of dust in the cometary atmosphere in relation to the direction of motion of the comet about the Sun suggests an excess of dust for the retrograde comets. This excess is analyzed in the light of Harwit's theory of the cloud of “boulders” and of Öpik's impact theory. A comparison is also made between these excesses and other cometary phenomena such as splittings and outbursts.     

Study of the total lightning activity in a hailstorm

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.     

Predation on the southwestern Atlantic fiddler crab (Uca uruguayensis) by migratory shorebirds (pluvialis dominica, P. squatarola, arenaria interpres, and numenius phaeopus)

In Bahia Samborombon (SW Atlantic; 35°30′–36°22′S; 56°45′–57°23′W) migratory American golden plover (Pluvialis dominica), black-billed plover (P. squatarola), ruddy turnstone (Arenaria interpres), and whimbrel (Numenius phaeopus) forage on fiddler crabs (Uca uruguayensis). These shorebirds have distinct patterns of feeding behavior and capture different proportions of each sex and size. P. dominica made short runs, capturing mostly juvenile crabs, which are eaten whole. P. squatarola use a similar feeding strategy but capture females primarily. A. interpres walks continuously, capturing almost exclusively large male crabs (71%). N. phaeopus walk in the Uca patch and probe burrows by inserting the bill; they primarily capture females. The feeding rate of A. interpres is higher than that of P. dominica, P. squatarola, and N. phaeopus. Handling time shown by P. dominica and A. interpres was greater than the other two species for all categories of crabs. In all cases, handling time of male crabs was greater than those of either females or juveniles. All the evidences suggest that U. uruguayensis is an important food source for all these species and should be accounted in any conservation endeavor. *** DIRECT SUPPORT *** A01BY085 00006     

The origin of Himalayan anatexis and inverted metamorphism: Models and constraints

The key to comprehending the tectonic evolution of the Himalaya is to understand the relationships between large-scale faulting, anatexis, and inverted metamorphism. The great number and variety of mechanisms that have been proposed to explain some or all of these features reflects the fact that fundamental constraints on such models have been slow in coming. Recent developments, most notably in geophysical imaging and geochronology, have been key to coalescing the results of varied Himalayan investigations into constraints with which to test proposed evolutionary models. These models fall into four general types: (1) the inverted metamorphic sequences within the footwall of the Himalayan thrust and adjacent hanging wall anatexis are spatially and temporally related by thrusting; (2) thrusting results from anatexis; (3) anatexis results from normal faulting; and (4) apparent inverted metamorphism in the footwall of the Himalayan thrust is produced by underplating of right-way-up metamorphic sequences. We review a number of models and find that many are inconsistent with available constraints, most notably the recognition that the exposed crustal melts and inverted metamorphic sequences not temporally related. The generalization that appears to best explain the observed distribution of crustal melts and inverted metamorphic sequences is that, due to specific petrological and tectonic controls, episodic magmatism and out-of-sequence thrusting developed during continuous convergence juxtaposing allochthonous igneous and metamorphic rocks. This coincidental juxtaposition has proven to be something of a red herring, unduly influencing attention toward finding a causal relationship between anatexis and inverted metamorphism.     

Crystallization and eruption ages of Breccia Museo (Campi Flegrei caldera,Italy) plutonic clasts and their relation to the Campanian ignimbrite

The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km³ Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km² in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI ⁴⁰Ar/³⁹Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated ⁴⁰Ar/³⁹Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.     

Influence of pore morphology on the durability of sedimentary building stones from Aragon (Spain) subjected to standard salt decay tests

The aim of the present article is to identify the influence of the pore morphology on the physical behaviour and durability of natural stone. Fifteen sedimentary rocks commonly used in the cultural and architectural heritage of Aragon (Spain) were characterized. The petrography, porous structure, fluid transport properties and durability of these rocks were analysed. They were classified into two different groups according to the results of the different tests. For each of these groups the physical behaviour was established. A principal components analysis was used in order to examine the correlation between pore structure, hydric properties and durability. The results show that the percentage of pore throats <0.1 μm control the fluid transport properties, have an important influence on stone durability, and can be used to predict resistance to salt decay while the average pore size does not. Stones with a high percentage of pore throats <0.1 μm are less susceptible to salt decay than stones with higher pore size if their pore network is characterized by high tortuosity and low connectivity.     

Aboveground Biomass Patterns of Dominant Spartina Species and Their Relationship with Selected Abiotic Variables in Argentinean SW Atlantic Marshes

Salt marsh zonation patterns generate different abiotic and biotic conditions that can accentuate species inherent differences in primary production and biomass. In South West Atlantic marshes, there are two Spartina species: Spartina alterniflora in the low intertidal and Spartina densiflora in the high intertidal. These two species are generally found in all marshes but with different dominance: In some marshes, the S. densiflora zone occupies higher extents, and in others, the S. alterniflora zone is the one that prevails. We found through field sampling that, in six studied marshes, there is greater S. densiflora live and total (i.e., dead+live) aboveground biomass (g m^?2) in the marshes dominated by S. densiflora than in the ones dominated by S. alterniflora. Spartina alterniflora had similar aboveground biomass in the six marshes, regardless of the dominance of each species. When comparing the two Spartina species within each marsh, S. densiflora had greater live and total biomass in the marshes it dominates. In the marshes dominated by S. alterniflora, both species had similar live and total biomass. In all marshes, there was greater dead S. densiflora biomass. A multivariate analysis using selected abiotic factors (i.e., salinity, latitude, and tidal amplitude) showed that S. alterniflora aboveground biomass patterns are mainly correlated with salinity, while S. densiflora live biomass is mainly correlated with salinity and latitude, dead biomass with salinity and tidal amplitude, and total biomass with salinity alone. We conclude that in S. densiflora dominated marshes, the main processes of that species zone (i.e., nutrient accumulation) will be accentuated because of its higher biomass. We also conclude that climatic conditions, in combination with specific Spartina biotic and ambient abiotic parameters, can affect marsh ecological functions.