Analysis of the annual mean energy cycle of the Black Sea circulation for the climatic,basin-scale and eddy regimes

Ocean Dynamics - This work presents an analysis of the Lorenz energy cycles derived from the simulation results of the Black Sea circulation. Three numerical experiments are carried out based on an...     

Matching hydrologic response to measured effective hydraulic conductivity

The objective of this study was to test the practicability of defining hydrologic response units as combinations of soil, land use and topography for modelling infiltration at the hillslope and catchment scales. In an experimental catchment in the East African Highlands (Kwalei, Tanzania), three methods of measuring infiltration were compared for their ability to capture the spatial variability of effective hydraulic conductivity: the constant head (CH) method; the tension infiltration (TI) method; and the mini‐rainfall simulation (RS) method. The three methods yielded different probability distributions of effective hydraulic conductivity and suggested different types of hydrologic response units. Independently from these measurements, the occurrence of infiltration‐excess overland flow was monitored over an area of 6 ha by means of overland flow detectors. The observed pattern of overland flow occurrence did not match any of the patterns suggested by the infiltration measurements. Instead, clusters of spots with overland flow were practically independent from field borders. Geostatistical analysis of the overland flow confirmed the absence of spatial correlation for distances over 40 m. The RS method yielded the pattern closest to the observations, probably because the method simulated better the processes that trigger infiltration‐excess overland flow, i.e. soil sealing and infiltration through macroporosity. The RS hydrologic response unit correlated significantly with observed overland flow frequency. However, the location of clusters and ‘hot spots’ of overland flow remained largely unexplained by land use, soil and topographic variables. It is concluded that using such landscape variables to define hydrologic units may create artificial boundaries that do no correspond to physical realities, especially if the stochastic component within hydrologic units is neglected. Copyright © 2005 John Wiley & Sons, Ltd.     

Holocene Treeline History and Climate Change Across Northern Eurasia

Radiocarbon-dated macrofossils are used to document Holocene treeline history across northern Russia (including Siberia). Boreal forest development in this region commenced by 10,000 yr B.P. Over most of Russia, forest advanced to or near the current arctic coastline between 9000 and 7000 yr B.P. and retreated to its present position by between 4000 and 3000 yr B.P. Forest establishment and retreat was roughly synchronous across most of northern Russia. Treeline advance on the Kola Peninsula, however, appears to have occurred later than in other regions. During the period of maximum forest extension, the mean July temperatures along the northern coastline of Russia may have been 2.5° to 7.0°C warmer than modern. The development of forest and expansion of treeline likely reflects a number of complimentary environmental conditions, including heightened summer insolation, the demise of Eurasian ice sheets, reduced sea-ice cover, greater continentality with eustatically lower sea level, and extreme Arctic penetration of warm North Atlantic waters. The late Holocene retreat of Eurasian treeline coincides with declining summer insolation, cooling arctic waters, and neoglaciation.     

Sorption and desorption of mercury(II) in saline and alkaline soils of Bahía Blanca, Argentina

The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (<1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO₃ solutions. Total Hg(II) concentrations ranged from 6.2 × 10^?8 to 6.3 × 10^?3 M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10^?8 to 1.1 × 10^?4 M, and (b) 6.4 × 10^?4 to 6.3 × 10^?3 M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH)₂ was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH)₂ in the interlayer of the interstratified clay minerals can be proposed. Hg(OH)₂ was partially desorbed by repeated equilibrations in 0.1 M NaNO₃ solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10^?5 M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10^?3 M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH)₂ was retained by adsorption on clay mineral surfaces.     

The environment of early Mars and the missing carbonates

Abstract– A model is presented in which the aqueous conditions needed to generate phyllosilicate minerals in the absence of carbonates found in the ancient Noachian crust are maintained by an early CO₂‐rich atmosphere, that, together with iron (II) oxidation, would prevent carbonate formation at the surface. After cessation of the internal magnetic dynamo, a CO₂‐rich primordial atmosphere was stripped by interactions with the solar wind and surface conditions evolved from humid to arid, with ground waters partially dissolving subsurface carbonate and sulfide minerals to produce acid‐sulfate evaporitic deposits in areas with upwelling ground water. In a subsequent geochemical state (Late Noachian to Hesperian), surface and subsurface acidic solutions were neutralized in the subsurface through interaction with basaltic crust, allowing the precipitation of secondary carbonates. This model suggests that, in the early Noachian, the surface waters of Mars maintained acidity because of a drop in temperature. This would have favored increased dissolution of CO₂ and a reduction in atmospheric pressure. In this scenario, physicochemical conditions precluded the formation of surface carbonates, but induced the precipitation of carbonates in the subsurface.     

Very low strengths of interplanetary meteoroids and small asteroids

Abstract– We have assembled data on 13 cases of meteorite falls with accurate tracking data on atmospheric passage. In all cases, we estimate the bulk strength of the object corresponding to its earliest observed or inferred fragmentation in the high atmosphere, and can compare these values with measured strengths of meteorites in the taxonomic class for that fall. In all 13 cases, the strength corresponding to earliest observed or inferred fragmentation is much less than the compressive or tensile strength reported for that class of stony meteorites. Bulk strengths upon atmospheric entry of these bodies are shown to be very low, 0.1 to approximately 1 MPa on first breakup, and maximal strength on breakup as 1–10 MPa corresponding to weak and “crumbly” objects, whereas measured average tensile strength of the similar meteorite classes is about 30 MPa. We find a more random relation between bulk sample strength and sample mass than is suggested by a commonly used empirical power law. We estimate bulk strengths on entry being characteristically of the order of 10^?1–10^?2 times the tensile strengths of recovered samples. We conclude that pre‐entry, meter‐scale interplanetary meteoroids are typically highly fractured or in some cases rubbly in texture, presumably as a result of their parent bodies’ collisional history, and can break up under stresses of a few megapascals. The weakness of some carbonaceous objects may result from very porous primordial accretional structures, more than fractures. These conclusions have implications for future asteroid missions, sample extraction, and asteroid hazard mitigation.     

Cruziana semiplicata from the Furongian (Late Cambrian) of Severnaya Zemlya Archipelago,Arctic Russia,with a review of the spatial and temporal distribution of this ichnospecies

The Furongian (Late Cambrian) Kurchavinskaya Formation of October Revolution Island, Severnaya Zemlya Archipelago, Arctic Russia , contains two distinctive morphotypes of the trace fossil Cruziana, both of which we assign to Cruziana semiplicata. A wider form shows characteristics typical of this ichnospecies with inner and outer lobes and marginal ridges. A narrow form has only an inner lobe with siculate, often interfering scratch‐marks, and rare, narrow marginal ridges. This narrow form, which shows characters in common with Cruziana tortworthi, probably represents burrowing in a strongly head‐down orientation. The record from October Revolution Island provides additional evidence that the palaeogeographical distribution of Cruziana semiplicata is not restricted to Gondwana, but also extend to parts of Baltica and North Kara. Cruziana semiplicata is known from the Furongian and Tremadocian of Gondwana, whereas on Baltica it is known only from the Furongian. Copyright © 2010 John Wiley & Sons, Ltd.     

Origins of Rolling, Twisting, and Non-radial Propagation of Eruptive Solar Events

We demonstrate that major asymmetries in erupting filaments and CMEs, namely major twists and non-radial motions are typically related to the larger-scale ambient environment around eruptive events. Our analysis of prominence eruptions observed by the STEREO, SDO, and SOHO spacecraft shows that prominence spines retain, during the initial phases, the thin ribbon-like topology they had prior to the eruption. This topology allows bending, rolling, and twisting during the early phase of the eruption, but not before. The combined ascent and initial bending of the filament ribbon is non-radial in the same general direction as for the enveloping CME. However, the non-radial motion of the filament is greater than that of the CME. In considering the global magnetic environment around CMEs, as approximated by the Potential Field Source Surface (PFSS) model, we find that the non-radial propagation of both erupting filaments and associated CMEs is correlated with the presence of nearby coronal holes, which deflect the erupting plasma and embedded fields. In addition, CME and filament motions, respectively, are guided towards weaker field regions, namely null points existing at different heights in the overlying configuration. Due to the presence of the coronal hole, the large-scale forces acting on the CME may be asymmetric. We find that the CME propagates usually non-radially in the direction of least resistance, which is always away from the coronal hole. We demonstrate these results using both low- and high-latitude examples.     

Non-monotone spectral projected gradient method applied to full waveform inversion

The seismic inversion problem is a highly non‐linear problem that can be reduced to the minimization of the least‐squares criterion between the observed and the modelled data. It has been solved using different classical optimization strategies that require a monotone descent of the objective function. We propose solving the full‐waveform inversion problem using the non‐monotone spectral projected gradient method: a low‐cost and low‐storage optimization technique that maintains the velocity values in a feasible convex region by frequently projecting them on this convex set. The new methodology uses the gradient direction with a particular spectral step length that allows the objective function to increase at some iterations, guarantees convergence to a stationary point starting from any initial iterate, and greatly speeds up the convergence of gradient methods. We combine the new optimization scheme as a solver of the full‐waveform inversion with a multiscale approach and apply it to a modified version of the Marmousi data set. The results of this application show that the proposed method performs better than the classical gradient method by reducing the number of function evaluations and the residual values.