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131.
The northernmost conifers in the world are located well above the Arctic Circle in the Taymir region of northern Siberia and have been recording the thermal environment for centuries to millennia. The trees respond to temperatures beyond the narrow season of actual cambial cell division by means of root growth, photosynthesis, lignification of cell walls, and other biochemical processes. Data from annual tree-ring widths are used to reconstruct May–September mean temperatures for the past four centuries. These warm-season temperatures correlate with annual temperatures and indicate unusual warming in the 20th century. However, there is a loss of thermal response in ring widths since about 1970. Previously the warmer temperatures induced wider rings. Most major warming and cooling trends are in agreement with other high-latitude temperature reconstructions based on tree-ring analyses with some regional differences in timing of cooling in the late 18th century and of warming in the late 19th century.  相似文献   
132.
Although phytoliths, constituted mainly by micrometric opal, exhibit an important control on silicon cycle in superficial continental environments, their thermodynamic properties and reactivity in aqueous solution are still poorly known. In this work, we determined the solubility and dissolution rates of bamboo phytoliths collected in the Réunion Island and characterized their surface properties via electrophoretic measurements and potentiometric titrations in a wide range of pH. The solubility product of “soil” phytoliths ( at 25 °C) is equal to that of vitreous silica and is 17 times higher than that of quartz. Similarly, the enthalpy of phytoliths dissolution reaction is close to that of amorphous silica but is significantly lower than the enthalpy of quartz dissolution. Electrophoretic measurements yield isoelectric point pHIEP = 1.2 ± 0.1 and 2.5 ± 0.2 for “soil” (native) and “heated” (450 °C heating to remove organic matter) phytoliths, respectively. Surface acid-base titrations allowed generation of a 2-pK surface complexation model. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 2 ? pH ? 12, were found to be intermediate between those of quartz and vitreous silica. The dissolution rate dependence on pH was modeled within the concept of surface coordination theory using the equation:
  相似文献   
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Fossil diatom assemblages in a sediment core from a small lake in Central Kamchatka (Russia) were used to reconstruct palaeoenvironmental conditions of the late Holocene. The waterbody may be a kettle lake that formed on a moraine of the Two-Yurts Lake Valley, located on the eastern slope of the Central Kamchatka Mountain Chain. At present, it is a seepage lake with no surficial outflow. Fossil diatom assemblages show an almost constant ratio between planktonic and periphytic forms throughout the record. Downcore variations in the relative abundances of diatom species enabled division of the core into four diatom assemblage zones, mainly related to changes in abundances of Aulacoseira subarctica, Stephanodiscus minutulus, and Discostella pseudostelligera and several benthic species. Associated variations in the composition and content of organic matter are consistent with the diatom stratigraphy. The oldest recovered sediments date to about 3220 BC. They lie below a sedimentation hiatus and likely include reworked deposits from nearby Two-Yurts Lake. The initial lake stage between 870 and 400 BC was characterized by acidic shallow-water conditions. Between 400 BC and AD 1400, lacustrine conditions were established, with highest contributions from planktonic diatoms. The interval between AD 1400 and 1900 might reflect summer cooling during the Little Ice Age, indicated by diatoms that prefer strong turbulence, nutrient recycling and cooler summer conditions. The timing of palaeolimnological changes generally fits the pattern of neoglacial cooling during the late Holocene on Kamchatka and in the neighbouring Sea of Okhotsk, mainly driven by the prevailing modes of regional atmospheric circulation.  相似文献   
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In order to constrain the origin and fluxes of elements carried by rivers of high latitude permafrost-dominated areas, major and trace element concentrations as well as Sr and U isotopic ratios were analyzed in the dissolved load of two Siberian rivers (Kochechum and Nizhnyaya Tunguska) regularly sampled over two hydrological cycles (2005-2007). Large water volumes of both rivers were also collected in spring 2008 in order to perform size separation through dialysis experiments. This study was completed by spatial sampling of the Kochechum watershed carried out during summer and by a detailed analysis of the main hydrological compartments of a small watershed. From element concentration variations along the hydrological cycle, different periods can be marked out, matching hydrological periods. During winter baseflow period (October to May) there is a concentration increase for major soluble cations and anions by an order of magnitude. The spring flood period (end of May-beginning of June) is marked by a sharp concentration decrease for soluble elements whereas dissolved organic carbon and insoluble element concentrations strongly increase.When the spring flood discharge occurs, the significant increase of aluminum and iron concentrations is related to the presence of organo-mineral colloids that mobilize insoluble elements. The study of colloidal REE reveals the occurrence of two colloid sources successively involved over time: spring colloids mainly originate from the uppermost organic-rich part of soils whereas summer colloids rather come from the deep mineral horizons. Furthermore, U and Sr isotopic ratios together with soluble cation budgets in the Kochechum river impose for soluble elements the existence of three distinct fluxes over the year: (a) at the spring flood a surface flux coming from the leaching of shallow organic soil levels and containing a significant colloidal component (b) a subsurface flux predominant during summer and fall mainly controlled by water-rock interactions within mineral soils and (c) a deep groundwater flux predominant during winter which enters large rivers through unfrozen permafrost-paths. Detailed study of the Kochechum watershed suggests that the contribution of this deep flux strongly depends on the depth and continuous nature of the permafrost.  相似文献   
137.
正1 Introduction The salt lakes of the Crimea contain the practically inexhaustible sources of salts of sodium,magnesium,bromine and other chemical elements(Ponizovskii,1965),being the potential powerful raw materials base for the  相似文献   
138.
The sediment–landform associations of the northern Taymyr Peninsula in Arctic Siberia tell a tale of ice sheets advancing from the Kara Sea shelf and inundating the peninsula, probably three times during the Weichselian. In each case the ice sheet had a margin frozen to its bed and an interior moving over a deforming bed. The North Taymyr ice‐marginal zone (NTZ) comprises ice‐marginal and supraglacial landsystems dominated by thrust‐block moraines 2–3 km wide and large‐scale deformation of sediments and ice. Large areas are still underlain by remnant glacier ice and a supraglacial landscape with numerous ice‐walled lakes and kames is forming even today. The proglacial landsystem is characterised by subaqueous (e.g. deltas) or terrestrial (e.g. sandar) environments, depending on location/altitude and time of formation. Dating results (OSL, 14C) indicate that the NTZ was initiated ca. 80 kyr BP during the retreat of the Early Weichselian ice sheet and that it records the maximum limit of a Middle Weichselian glaciation (ca. 65 kyr BP). During both these events, proglacial lakes were dammed by the ice sheets. Part of the NTZ was occupied by a thin Late Weichselian ice sheet (20–12 kyr BP), resulting in subaerial proglacial drainage. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
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140.
If the dark matter particle is a neutralino, then the first structures to form are cuspy cold dark matter (CDM) haloes collapsing after redshifts   z ≈ 100  in the mass range  10−6–10−3 M  . We carry out a detailed study of the survival of these microhaloes in the Galaxy as they experience tidal encounters with stars, molecular clouds, and other dark matter substructures. We test the validity of analytic impulsive heating calculations using high-resolution N -body simulations. A major limitation of analytic estimates is that mean energy inputs are compared to mean binding energies, instead of the actual mass lost from the system. This energy criterion leads to an overestimate of the stripped mass and an underestimate of the disruption time-scale, since CDM haloes are strongly bound in their inner parts. We show that a significant fraction of material from CDM microhaloes can be unbound by encounters with Galactic substructure and stars; however, the cuspy central regions remain relatively intact. Furthermore, the microhaloes near the solar radius are those which collapse significantly earlier than average and will suffer very little mass-loss. Thus, we expect a fraction of surviving bound microhaloes, a smooth component with narrow features in phase space, which may be uncovered by direct detection experiments, as well as numerous surviving cuspy cores with proper motions of arcminutes per year, which can be detected indirectly via their annihilation into gamma-rays.  相似文献   
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