Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Stable Boundary-Layer Scaling Regimes: The Sheba Data

Turbulent and mean meteorological data collected at five levels on a 20-m tower over the Arctic pack ice during the Surface Heat Budget of the Arctic Ocean experiment (SHEBA) are analyzed to examine different regimes of the stable boundary layer (SBL). Eleven months of measurements during SHEBA cover a wide range of stability conditions, from the weakly unstable regime to very stable stratification. Scaling arguments and our analysis show that the SBL can be classified into four major regimes: (i) surface-layer scaling regime (weakly stable case), (ii) transition regime, (iii) turbulent Ekman layer, and (iv) intermittently turbulent Ekman layer (supercritical stable regime). These four regimes may be considered as the basic states of the traditional SBL. Sometimes these regimes, especially the last two, can be markedly perturbed by gravity waves, detached elevated turbulence (‘upside down SBL’), and inertial oscillations. Traditional Monin–Obukhov similarity theory works well in the weakly stable regime. In the transition regime, Businger–Dyer formulations work if scaling variables are re-defined in terms of local fluxes, although stability function estimates expressed in these terms include more scatter compared to the surface-layer scaling. As stability increases, the near-surface turbulence is affected by the turning effects of the Coriolis force (the turbulent Ekman layer). In this regime, the surface layer, where the turbulence is continuous, may be very shallow (< 5 m). Turbulent transfer near the critical Richardson number is characterized by small but still significant heat flux and negligible stress. The supercritical stable regime, where the Richardson number exceeds a critical value, is associated with collapsed turbulence and the strong influence of the earth’s rotation even near the surface. In the limit of very strong stability, the stress is no longer a primary scaling parameter.     

Absolute Positioning with Single-Frequency GPS Receivers

The use of precise post-processed satellite orbits and satellite clock corrections in absolute positioning, using one GPS receiver only, has proven to be an accurate alternative to the more commonly used differential techniques for many applications in georeferencing. The absolute approach is capable of centimeter accuracy when using state-of-the-art, dual-frequency GPS receivers. When using observations from single-frequency receivers, however, the accuracy, especially in height, decreases. The obvious reason for this degradation in accuracy is the effect of unmodeled ionospheric delay. This paper discusses the availability of some empirical ionospheric models that are publicly available and quantifies their usefulness for absolute positioning using single-frequency GPS receivers. The Global Ionospheric Model supplied by International GPS Service (IGS) is the most accurate one and is recommended for absolute positioning using single-frequency GPS receivers. Using high-quality single-frequency observations, a horizontal epoch-to-epoch accuracy of better than 1 m and a vertical accuracy of approximately 1 m is demonstrated. ? 2002 Wiley Periodicals, Inc.     

Outlier Problem in Evaluating Similarity Functions in the Stable Atmospheric Boundary Layer

The gradient-based similarity approach removes turbulent fluxes as governing parameters and replaces them with vertical gradients of mean wind speed and potential temperature. As a result, the gradient Richardson number, Ri, appears as a stability parameter instead of the Monin–Obukhov stability parameter z/L (L is the Obukhov length). The gradient-based scaling is more appropriate for moderate and very stable conditions when the gradients are large and their errors are relatively small whereas z/L becomes ambiguous in these conditions because turbulent fluxes are small. However, the gradient-based formulation is faced with a problem related to the influence of Ri outliers: outliers with high values of Ri can exist in conditions that are really near-neutral. These outliers are mapped into the very stable range in plots in which Ri is the independent variable and may lead to spurious dependencies for bin-averaged data (spurious bin-averaging). This effect is quite large for functions that are steep for the gradient-based scaling. The present study uses the Surface Heat Budget of the Arctic Ocean (SHEBA) data to examine the problem and proposes two methods, conditional analysis and independent binning, to limit the influence of outliers on bin-averaging. A disadvantage of the conditional analysis is associated with eliminating outliers based on criteria that could be considered as subjective. The independent bin-averaging method does not have this disadvantage, but the scatter of the bin-averaged points is higher than for the conditional analysis, rendering data analysis and interpretation difficult.     

Turbulent measurements in the stable atmospheric boundary layer during SHEBA: ten years after

This paper surveys results of the comprehensive turbulent measurements in the stable boundary layer (SBL) made over the Arctic pack ice during the Surface Heat Budget of the Arctic Ocean experiment (SHEBA) in the Beaufort Gyre from October 1997 through September 1998. Turbulent fluxes and mean meteorological data were continuously measured and reported hourly at five levels on a 20-m main SHEBA tower. Eleven months of measurements during SHEBA cover a wide range of stability conditions, from the weakly unstable regime to very stable stratification, and allow studying the SBL in detail. A brief overview of the SBL regimes, the flux-profile relationships, the turbulent Prandtl number, and other parameters obtained during SHEBA is given. The traditional Monin—Obukhov approach, z-less scaling, and gradient-based scaling are evaluated and discussed based on the data from SHEBA.     

Modelling of the physical behaviour of clay barriers close to water saturation

The physical properties of bentonite-based buffer materials for nuclear waste repositories have been investigated by a number of different laboratory tests. These tests have yielded a material model that is valid for conditions close to water saturation and is useful for describing: (a) the stress, strain and volume change behaviour; (b) the pore pressure and flow of water; and (c) the thermal and thermomechanical response.

The material model is based on the Drucker-Prager Plasticity model and a Porous Elastic Model. The effective stress concept and Darcy's law are applied and the swelling/consolidation and thermomechanical processes are coupled according to the separate mechanical properties of the pore water, the solids and the clay skeleton. The model can be used by the finite-element program ABAQUS.

The model has been tested in several laboratory and field verification tests. Comparison between measured and calculated behaviour shows that the general behaviour is described properly and several calculations of different scenarios have been made for the Swedish KBS 3 concept. However, certain processes, like the hysteresis effect at consolidation/swelling, the curved stress-strain relation at shearing, and the curved failure envelope, are not modelled in a perfectly accurate way and an improved material model is proposed here. It combines the behaviour of the Cam-clay model on the wet side with the more relevant plastic behaviour of a modified Drucker-Prager model with a curved failure envelope and the possibility to introduce strain softening after failure.

The paper presents some laboratory results that are the basis of the first model. It also shows the application of the model to finite-element calculations of some laboratory tests. Comparisons between the calculations and measured results expose some disadvantages of the model and a concept for an improved model is suggested.     

Making journal articles ‘live’: turning academic writing into scientific dialog

Web 2.0 services and social networking offer possibilities to transform academic publishing to facilitate scientific dialogue. We present ‘The Live Paper’ in this editorial as a concept to consider how to leverage existing web technologies to produce rich, omnidirectional, and interactive narratives on research. Following the format of a traditional research report we describe and discuss how to enrich research reports utilizing various types of analytical tools, data, and web services in a published paper embedded in evolving scientific discourse. We also consider how the live papers would influence the practice, culture, and economy of academic research. We conclude that geospatial researchers have an opportunity to lead this development towards richer and more open ways of communicating our findings. The technology and infrastructure to do so exist today, but several barriers remain.     

On the use of the autocorrelation method for estimating the depth to the magnetic basement

The depth to the top of magnetic dykes can be estimated from total field aeromagnetic data using the relation between the depth to magnetic sources and the autocorrelation function of magnetic data. By using synthetic anomalies we show that in the ideal case, depth can be determined to an accuracy of 10% or better, when the anomaly sources are two-dimensional dykes. However, the estimated depths depend on the width of the dykes. The estimated depth is about 0.6 times the actual depth to the top of thin dykes, and around the true depth for thick dykes having width-to-depth ratio around 3. The depth is considerably overestimated for very thick dykes (e.g., contacts, which is a special case of the thick dyke). Thus, the autocorrelation method requires that the width-to-depth ratio of the dyke is estimated independently to correctly estimate the depths. Alternatively, it must be assumed that the width-to-depth ratio for the two-dimensional source body is between 1.5 and 4.     

Geotechnical properties of an attapulgite clay shale in northwestern nigeria

The paper gives a brief review of the geology of the Iullemmeden Basin of northwestern Nigeria and how the stratigraphic sequence produces complex geotechnical problems. Mineralogical analysis showed the clay shale to be predominantly attapulgite. Detailed geotechnical properties of the clay showed the liquid limit to be greater than 200% and it depended significantly on treatment before testing. Very low maximum dry densities of 1137 kg/m³ (71 pcf), a high optimum moisture content of 41%, and a high compression index of 0.23 were obtained. The results presented also indicated that the attapulgite has very critical potential volume change. Results of the shear strength characteristics showed the effective cohesion to be zero in all the tests and a loss of strength of about 50% occurred as a result of decrease in the rate of strain.