Mobility and Transport of Nd Isotopes in the Vadose Zone During Weathering of Granitic Till in a Boreal Forest

There is a broad correlation between the ε_Nd values for rivers (including both the water and the particulate material it carries) and the age of the source terrain. This paper presents Nd isotope distribution data for soil, soil water, groundwater, and stream water samples gathered in a small catchment in northern Sweden. The results show that the release of Nd and Sm from boreal forests into streams and, eventually, into the oceans is more complicated than previously realized. The weathering of till causes changes in both the Nd isotopic composition and Sm/Nd ratios. Both the Sm/Nd ratio and ε_Nd were higher in strongly weathered soils horizons than in less weathered till, since minerals with high Sm/Nd ratios were, on average, more resistant to weathering than those with low Sm/Nd ratios. In contrast to the situation for the main minerals and the major elements, the weathering of rare earth elements (REE) was not restricted to the E-horizon: the measured REE concentrations continued to increase with depth in the C-horizon. In addition, REE released by weathering in the upper parts of the soil profile were partly secondarily retained at deeper levels. Therefore, the dissolved Nd released by weathering in the upper soil horizons was trapped and did not enter the groundwater directly. Rather, the Nd in the groundwater largely originated from weathering within the groundwater zone. However, this was not the only source of Nd in the stream water. The Nd isotope composition and Sm/Nd ratio were determined by the mixing between of Nd and Sm in the groundwater and REE-carrying organic material washed out of the soil profile. The groundwater close to the stream reaches the upper soil horizons during high discharge events such as snowmelts, and organic matter carrying Nd and Sm is washed out of the soils and thus released into the stream. Therefore, the Nd exported from catchment is derived from both the weathering within the groundwater zone, and the organic matter washed out from the soil. If longer timescales with more advanced weathering stages in the groundwater zone are considered, it cannot be ruled out that there will be a shift towards more radiogenic values in the exported Nd. Recorded shifts in the Nd isotopic composition in the ocean may thus not only reflect changed source regions, but also the weathering history of the same source region.     

Assessment of potential seismic hazard and site effect in Antakya (Hatay Province), SE Turkey

Antakya city is at risk because of strong earthquakes occurring in the area, and different soil conditions that can produce variation of the ground motion amplification. Microzonation of cities provides a basis for site-specific hazard analysis in urban settlements. In particular, seismic microzonation can be provided by means of detailed seismic assessment of the area, including earthquake recordings and geological studies. In this paper, we propose a preliminary microzonation map for the city of Antakya, based on the variation of the dominant periods and shear velocities of the sediments covering the area. The periods are retrieved from microtremor measurements conducted at 69 sites, using the horizontal-to-vertical spectral ratio technique. The results of microtremor analysis were compared with data obtained from refraction microtremor (ReMi) measurements at four profiles crossing the studied area. According to the classification of dominant periods, Antakya city can be divided into five zones, probably prone to different levels of seismic hazard. The shorter natural periods are in inner Antakya and both the sides of Asi River (i.e., northern and southern parts). The eastern and western parts of Antakya have maximum dominant periods. The V _s ³⁰ values were calculated by using the ReMi method along the profiles. Antakya city has V _s ³⁰ values in the range of category C of the national earthquake hazard reduction programme site classification.     

Paper II – Dirt,dates and DNA: OSL and radiocarbon chronologies of perennially frozen sediments in Siberia,and their implications for sedimentary ancient DNA studies

Arnold, L. J., Roberts, R. G., MacPhee, R. D. E., Haile, J. S., Brock, F., Möller, P., Froese, D. G., Tikhonov, A. N., Chivas, A. R., Gilbert, M. T. P. & Willerslev, E. 2010: Paper II – Dirt, dates and DNA: OSL and radiocarbon chronologies of perennially frozen sediments in Siberia, and their implications for sedimentary ancient DNA studies. Boreas, Vol. 40, pp. 417–445. 10.1111/j.1502‐3885.2010.00181.x. ISSN 0300‐9483 The sedimentary ancient DNA (sedaDNA) technique offers a potentially invaluable means of investigating species evolution and extinction dynamics in high‐latitude environments. An implicit assumption of the sedaDNA approach is that the extracted DNA is autochthonous with the host deposit and that it has not been physically transported from older source deposits or reworked within the sedimentary profile by postdepositional mixing. In this paper we investigate whether these fundamental conditions are upheld at seven perennially frozen wetland sites across the Taimyr Peninsula and coastal lowlands of north‐central Siberia. Optically stimulated luminescence (OSL) and radiocarbon (¹⁴C) dating are used to constrain the ages of both the inorganic and organic fractions of perennially frozen deposits from which sedaDNA of extinct and extant species have been recovered. OSL and ¹⁴C age/depth profiles, as well as single‐grain equivalent dose (D_e) distribution characteristics, are used to assess the stratigraphic integrity of these sedaDNA sequences by (i) identifying the presence of primary or reworked organic and inorganic material, and (ii) examining the types of depositional and postdepositional processes that have affected specific sedimentary facies. The results of this study demonstrate that even though DNA preservation and stratigraphic integrity are commonly superior in perennially frozen settings, this does not, in itself, guarantee the suitability of the sedaDNA approach. The combined OSL and ¹⁴C chronologies reveal that certain perennially frozen sites may be poorly suited for sedaDNA analysis, and that careful site selection is paramount to ensuring the accuracy of any sedaDNA study – particularly for ‘latest appearance date’ estimates of extinct taxa.     

Clustering current climate regions of Turkey by using a multivariate statistical method

In this study, the hierarchical clustering technique, called Ward method, was applied for grouping common features of air temperature series, precipitation total and relative humidity series of 244 stations in Turkey. Results of clustering exhibited the impact of physical geographical features of Turkey, such as topography, orography, land–sea distribution and the high Anatolian peninsula on the geographical variability. Based on the monthly series of nine climatological observations recorded for the period of 1970–2010, 12 and 14 clusters of climate zones are determined. However, from the comparative analyses, it is decided that 14 clusters represent the climate of Turkey more realistically. These clusters are named as (1) Dry Summer Subtropical Semihumid Coastal Aegean Region; (2) Dry-Subhumid Mid-Western Anatolia Region; (3 and 4) Dry Summer Subtropical Humid Coastal Mediterranean region [(3) West coast Mediterranean and (4) Eastern Mediterranean sub-regions]; (5) Semihumid Eastern Marmara Transition Sub-region; (6) Dry Summer Subtropical Semihumid/Semiarid Continental Mediterranean region; (7) Semihumid Cold Continental Eastern Anatolia region; (8) Dry-subhumid/Semiarid Continental Central Anatolia Region; (9 and 10) Mid-latitude Humid Temperate Coastal Black Sea Region [(9) West Coast Black Sea and (10) East Coast Black Sea sub-regions]; (11) Semihumid Western Marmara Transition Sub-region; (12) Semihumid Continental Central to Eastern Anatolia Sub-region; (13) Rainy Summer Semihumid Cold Continental Northeastern Anatolia Sub-region; and (14) Semihumid Continental Mediterranean to Eastern Anatolia Transition Sub-region. We believe that this study can be considered as a reference for the other climate-related researches of Turkey, and can be useful for the detection of Turkish climate regions, which are obtained by a long-term time course dataset having many meteorological variables.     

Geochemistry, mineralogy and genesis of pyrophyllite deposits in the Pötürge Region (Malatya, Eastern Turkey)

In the Pötürge (Malatya, Turkey) area pyrophyllite occurrences are common in the shear zones, mostly in the form of lenses along faults. Mineralogical investigations (XRD, FTIR and SEM) revealed that pyrophyllite, kaolinite (dickite) and quartz are present in the form of major phases and muscovite (sericite), kyanite, chlorite, and alunite are only present in the form of minor phases. This study revealed that the existence of the kyanite phase points out to high pressure and temperature conditions which the rocks were underwent. On the other hand, the minerals such as pyrophyllite, kaolinite, and alunite are products of a low degree metamorphism (retrograde). The mineral paragenesis in the pyrophyllite deposits suggests that the formation of minerals took place in two ways: (1) the transformation of kyanite into pyrophyllite and quartz through retrograde metamorphism by a high degree temperature, (2) then pyrophyllite and probably muscovite were transformed into kaolinite and alunite through reactions with relatively low temperature hydrothermal fluids. The geochemical data indicate that during the retrograde metamorphism the elements K, Rb, Sr, Ba, S, and Fe were mobile, the elements Si, Al, P moderately mobile to immobile and the HPS elements (Zr, Ti, and Nb) were immobile. It was shown that the formation of pyrophyllite, kaolinite and alunite was associated with depletion in alkalis, Mg, Fe and enrichment of elements including Sr, Ba, and S. Mineralogical and geochemical data suggest that parent rocks (pre-metamorphism) of the Pötürge pyrophyllite were probably kaolinite, Al-rich clays or bauxites.     

Palaeoenvironmental and palaeoecological change on the northern Tethyan carbonate platform during the Late Barremian to earliest Aptian

A major shift from Urgonian oligotrophic carbonate accumulation to orbitolinid‐rich mixed siliciclastic–carbonate deposition is observed near the Barremian–Aptian boundary in many sections both within and outside the shallow‐marine Tethyan Realm. This important facies change in the Swiss Helvetic Alps is documented here and interpreted in the context of general palaeoenvironmental change. To achieve this, a detailed micropalaeontological, sedimentological, mineralogical and geochemical study has been carried out on six sections across the upper part of the lower Schrattenkalk Member (Late Barremian), the Rawil Member (formerly ‘Lower Orbitolina Beds’, earliest Aptian) and the lowermost part of the upper Schrattenkalk Member (Early Aptian). The sediments of the Rawil Member exhibit inner‐platform facies with rudists, miliolids, orbitolinids and dasycladals to outer‐platform facies characterized by small benthic foraminifera, orbitolinids, crinoids and bryozoans. Stratigraphic trends in microfacies environments and the composition of microfossil assemblages, indicate that the Rawil Member includes a transgressive systems tract and the base of a highstand systems tract which are composed of an increasing number of parasequences in distal directions (five to nine in the sections studied here). The sea‐level rise discerned in the Rawil Member is coeval with increased detrital input and phosphorus burial, with maximum values up to 80 times and 21 times the background values in the subjacent part of the lower Schrattenkalk Member, respectively. Furthermore, the Rawil Member records the appearance of kaolinite, indicating a change towards tropical and more humid climate conditions. This change may have led to an increase in continental weathering rates and an associated increase in detrital and nutrient fluxes towards the ocean. The phase of climate change observed near the Barremian–Aptian boundary may have been triggered by a phase of intensified volcanic activity linked with the onset of the Ontong Java large igneous province and the Rawil Member may be the expression of a precursor episode to Oceanic Anoxic Event 1a in the shallow‐marine environment.     

The Manyas fault zone (southern Marmara region,NW Turkey): active tectonics and paleoseismology

The Manyas fault zone (MFZ) is a splay fault of the Yenice Gönen Fault, which is located on the southern branch of the North Anatolian Fault System. The MFZ is a 38 km long, WNW–ESE-trending and normal fault zone comprised of three en-echelon segments. On 6 October 1964, an earthquake (Ms = 6.9) occurred on the Salur segment. In this study, paleoseismic trench studies were performed along the Salur segment. Based on these paleoseismic trench studies, at least three earthquakes resulting in a surface rupture within the last 4000 years, including the 1964 earthquake have been identified and dated. The penultimate event can be correlated with the AD 1323 earthquake. There is no archaeological and/or historical record that can be associated with the oldest earthquake dated between BP 3800 ± 600 and BP 2300 ± 200 years. Additionally, the trench study performed to the north of the Salur segment demonstrates paleoliquefaction structures crossing each other. The surface deformation that occurred during the 1964 earthquake is determined primarily to be the consequence of liquefaction. According to the fault plane slip data, the MFZ is a purely normal fault demonstrating a listric geometry with a dip of 64°–74° to the NNE.     

A new radiocarbon chronology of Baumkirchen,stratotype for the onset of the Upper Würmian in the Alps

The start of the Upper Würmian in the Alps was marked by massive fluvioglacial aggradation prior to the arrival of the Central Alpine glaciers. In 1984, the Subcommission on European Quaternary Stratigraphy defined the clay pit of Baumkirchen (in the foreland of the Inn Valley, Austria) as the stratotype for the Middle to Upper Würmian boundary in the Alps. Key for the selection of this site was its radiocarbon chronology, which still ranks among the most important datasets of this time interval in the Alps. In this study we re‐sampled all available original plant specimens and established an accelerator mass spectrometry chronology which supersedes the published 40‐year‐old chronology. The new data show a much smaller scatter and yielded slightly older conventional radiocarbon dates clustering at ca. 31 ¹⁴C ka BP. When calibrated using INTCAL13 the new data suggest that the sampled interval of 653–681 m in the clay pit was deposited 34–36 cal ka BP. Using two new radiocarbon dates of bone fragments found in the fluvioglacial gravel above the banded clays allows us to constrain the timing of the marked change from lacustrine to fluvioglacial sedimentation to ca. 32–33 cal ka BP, which suggests a possible link to the Heinrich 3 event in the North Atlantic. Copyright © 2013 John Wiley & Sons, Ltd.