Buried palaeosols of the Nevado de Toluca: an alternative record of Late Quaternary environmental change in central Mexico

Buried palaeosols of central Mexico, not previously analysed from a palaeopedological standpoint, have helped to develop a reliable regional model of Late Quaternary climatic change. This paper focuses upon morphological and micromorphological properties, particle‐size distribution, and extractable Fe, Al and Si of seven palaeosols (named PT1–PT7) in the vicinity of the Nevado de Toluca volcano. The characteristics of Andic Cambisol PT1, similar to those of modern soils in semi‐arid environments, indicate a drier climate in the first half of the Holocene. Humic Andosols PT2–PT4 are analogous to modern volcanic soils of humid forest environments. They show evidence that a moist palaeoclimate prevailed during marine oxygen isotope stages (OIS) 2 and 3. Luvisols PT5 and PT6, which are assumed to have formed at the end of marine OIS 5 to marine OIS 4, also indicate humid conditions. We attribute the differences between Andosols PT2–PT4 and Luvisols PT5–PT7 to variations in the duration in the pedogenesis rather than to changes in palaeoclimate. Micromorphological features of Andosol to Luvisol transition confirm that these soils form an evolutionary sequence. Being for the most part consistent with lacustrine records, the palaeosol properties do not reflect the episodes of ‘drier climate’ during the Last Glacial Maximum, however, as shown by diatom and palynological data from lake sediments. Mesoclimate variations and/or incompleteness of ‘soil memory’, reflecting mostly periods of humid pedogenesis, probably provide the reason for this disagreement. Copyright © 2001 John Wiley & Sons, Ltd.     

Deep colour–magnitude diagrams of LMC field stars imaged with HST

We present deep photometry ( V ≲26) in V and I bands obtained with the Wide Field and Planetary Camera 2 on board the Hubble Space Telescope for 7 fields ∼5° away from the Large Magellanic Cloud centre. The fields contain, typically, 2000 stars each. Isochrones were fitted to the colour–magnitude diagrams in order to identify different star populations in these fields. An old population ( τ >10 Gyr) has been found in all fields. Some events of enhanced star formation, with ages between 2 and 4 Gyr, were identified in the fields localized in the north to north-west regions. Luminosity functions of low-mass stars were also obtained for all fields. Kolmogorov Smirnov test results suggest differences smaller than 30 per cent in the mixture of stellar populations contributing to the fields. Finally, density profiles were derived for old and intermediate-age stars. The former shows a slightly steeper decline than the latter.     

Structural localization of Al<Superscript>3+</Superscript> ions in aluminosilicates: application of heteronuclear chemical shift correlation to 2:1 phyllosilicates

The main objective of this paper is to apply an NMR-based methodology to clay minerals that provides resolution enhancement in ²⁷Al NMR spectra, permitting the differentiation of aluminum ions with one same coordination number, but with different chemical environments. For this purpose, we have performed two-dimensional ¹H²⁷Al cross-polarization experiments, which facilitate the identification of the different aluminum crystallographic sites by means of the nature of the proton polarization source. For the development of this methodology, we have carried out a systematic study of a set of well-characterized 2:1 phyllosilicates with aluminum in different crystallographic sites. The structural locations of aluminum in the selected layered silicates have been established unequivocally. Once the correlation between all different aluminum and proton sites in smectite was well established, an unknown material was examined, the utility of this methodology being illustrated. This methodology can be applied to a great variety of materials, such as zeolites, ALPOs and mesoporous aluminosilicates, in which a precise determination of the aluminum location is demanded.     

An inter-comparison of regional climate models for Europe: model performance in present-day climate

The analysis of possible regional climate changes over Europe as simulated by 10 regional climate models within the context of PRUDENCE requires a careful investigation of possible systematic biases in the models. The purpose of this paper is to identify how the main model systematic biases vary across the different models. Two fundamental aspects of model validation are addressed here: the ability to simulate (1) the long-term (30 or 40 years) mean climate and (2) the inter-annual variability. The analysis concentrates on near-surface air temperature and precipitation over land and focuses mainly on winter and summer. In general, there is a warm bias with respect to the CRU data set in these extreme seasons and a tendency to cold biases in the transition seasons. In winter the typical spread (standard deviation) between the models is 1 K. During summer there is generally a better agreement between observed and simulated values of inter-annual variability although there is a relatively clear signal that the modeled temperature variability is larger than suggested by observations, while precipitation variability is closer to observations. The areas with warm (cold) bias in winter generally exhibit wet (dry) biases, whereas the relationship is the reverse during summer (though much less clear, coupling warm (cold) biases with dry (wet) ones). When comparing the RCMs with their driving GCM, they generally reproduce the large-scale circulation of the GCM though in some cases there are substantial differences between regional biases in surface temperature and precipitation.     

Hierarchical clustering of multispectral images using combined spectral and spatial criteria

An agglomerative hierarchical clustering method, which uses both spectral and spatial information for the aggregation decision, is proposed here. The method is suitable for large multispectral images, provided that an unsupervised classification is previously applied. The method is tested on a synthetic image and on a satellite image of the coastal zone.     

Interactions of river discharge and tidal modulation in a tropical estuary, NE Brazil

Observations of thermohaline properties and currents were undertaken in the Curimataú River estuary (6°18′S), Rio Grande do Norte state (RN), Brazil, during consecutive neap–spring tidal cycles in the austral autumn rainy season. Highly asymmetric neap tide along channel velocities (−0.4 to 0.9 m s⁻¹) and highly stratified conditions were generated by an increase of the buoyancy energy from the freshwater input (R _iE≈5.6). During the spring-tidal cycle the river discharge decreased and the longitudinal velocity components were higher, less asymmetrical (−0.8 to 1.1 m s⁻¹) and semidiurnal, associated with moderately stratified conditions (R _iE≈0.1) due to the increase of the kinetic tidal energy forcing mechanism. The overall salinity variation from surface to bottom during two tidal cycles was from 20.5 to 36.3 and 29 to 36.7 in the neap and spring tide experiments, respectively; in the last experiment, the tropical water (TW) mass intrusion was enhanced. The net salt transport reversed from down to up estuary during the neap and spring tide experiments, respectively, varied from 6.0 to –2.0 kg m⁻¹ s⁻¹, an indication of changes in the main forcing of the estuary dynamics. Evaluation of a classical steady analytical model, in comparison with nearly steady experimental vertical profiles of velocity, shows an agreement classifiable as reasonably fair.     

The impact of deforestation on the hydrological cycle in the western Mediterranean: an ensemble study with two regional climate models

 A deforestation experiment is performed over the western Mediterranean, applying two different RCMs with differing domains and an ensemble technique to obtain a measure of their internal variability. The internal variability is used to assign statistical significance to the results, and also to discuss whether the models are sufficiently free to develop internal mesoscale processes. Considerable internal variability values found for hydrological variables even in autumn and winter seem to support the assumption that the models are free enough to be applied to such a sensitivity study. The combined use of two models, with strongly differing domains, and significance assigned through the use of internal variability should highlight responses to deforestation which are of physical origin and not a result dependent on one particular model. The overall significant response from both RCMs to deforestation is a reduction of evaporation (spring and summer, extending over the whole deforested zone) and a decrease in precipitation (late spring and summer, over some regions). A detailed analysis over subzones shows remarkable agreement between the two models over some of these subzones, showing non-local effects in precipitation response. Received: 8 February 2000 / Accepted: 12 January 2001     

Numerical Analysis of Space–Time Finite Element Formulations for Miscible Displacements

A finite element formulation is proposed to approximate a nonlinear system of partial differential equations, composed by an elliptic subsystem for the pressure–velocity and a transport equation (convection–diffusion) for the concentration, which models the incompressible miscible displacement of one fluid by another in a rigid porous media. The pressure is approximated by the classical Galerkin method and the velocity is calculated by a post-processing technique. Then, the concentration is obtained by a Galerkin/least-squares space–time (GLS/ST) finite element method. A numerical analysis is developed for the concentration approximation. Then, stability, convergence and numerical results are presented confirming the a priori error estimates.     

Pulsations at the Onset of the Great Solar Burst of 22 October 1989

The onset phase of the 22 October 1989 great solar burst was observed at 48 GHz using the multiple beam technique, which allows unambiguous flux determination irrespective of spatial angular position changes in time. We found strong quasi-periodic pulsating structures as the flux started to rise. Two significantly different time scales of 2.5–4.5 s and 0.2–0.5 s have been observed. These pulsations might be related to magnetohydrodynamic perturbations in the active region. However the fast component also might be a signature of the acceleration and/or injection of energetic electrons.     

CCD images and long-slit spectroscopy of the ring nebula around θ Mus

We present the first digital CCD images and long-slit spectroscopy of the optical ring nebula around the Wolf–Rayet star θ Mus. The CCD images obtained through narrow-band filters centred at [O  iii ] and Hα show that the nebula has a filamentary structure, similar to supernova remnants, mainly seen in [O  iii ]. A spatial detachment between [O  iii ] and Hα images suggests excitation stratification, or multiple rings. An analysis of the physical conditions in the nebula was performed by means of long-slit CCD spectra. The spectral images show that the nebula is of low density and medium excitation. By means of quotients of recombination and collisional spectral line fluxes we determine that the principal excitation mechanism is photoionization. We have determined the electronic temperature and density, and chemical abundances for the oxygen at different sites within the nebula. Nebular chemical abundances are found to be similar to the Galactic ISM, indicating that the nebula is mainly composed of swept up material.