Comparative hydrochemistry of five nested catchments located in the upper part of the Barcés river watershed (A Coruña,NW Spain)

259 stream water and 21 bulk precipitation samples have been studied between April 2008 and December 2010 in order to assess baseline hydrochemical conditions in a rural area of NW Spain. Stream waters are related to five nested catchments (<10 km²) with apparent low mean residence times. Their hydrochemical characteristics are closely related to bulk precipitation although clear evidences of seasonal (flushing, dilution, sediment desorption, etc.), lithological (schist vs. granite substrate) and anthropogenic (land use, contamination) effects are also described.     

Optical observations of type-IIP supernova 2004dj: Evidence for asymmetry of the <Superscript>56</Superscript>Ni ejecta

Photometric and spectroscopic observations of the nearby type-IIP supernova 2004dj are presented. The ⁵⁶Ni mass in the envelope of SN 2004dj was estimated from the light curve to be ≈0.02M_⊙. This estimate is confirmed by modeling the Hα luminosity. The Hα emission line exhibits a strong asymmetry characterized by the presence of a blue component in the line with a shift of ?1600 km s^?1 at the early nebular phase. A similar asymmetry was found in the Hβ, [O I], and [Ca II] lines. The line asymmetry is interpreted as being the result of asymmetric ⁵⁶Ni ejecta. The Hα profile and its evolution are reproduced in the model of an asymmetric bipolar ⁵⁶Ni structure for a spherical hydrogen distribution. The mass of the front ⁵⁶Ni jet is comparable to that of the central component and twice that of the rear ⁵⁶Ni jet. We point out that the asymmetric bipolar structure of ⁵⁶Ni ejecta is also present in SN 1999em, a normal type-IIP supernova.     

Analysis of petroleum hydrocarbons in mangrove sediments of Red Sea of Yemen

A field work has been carried out to identify the occurrence of oil and oil products pollution in mangrove sediment from Red Sea of Yemen. The concentration of total petroleum hydrocarbons is from 700 ng/g at Kamaran Island station to 400 ng/g at Al-Hodiedah station, and the total organic carbon ( TOC) in samples ranges from 0.07% at Dhubab station to 0.03% at Kamaran Island station. This pollution is as a result of localized oil pollution and /or heavy ship traffic in the Red Sea and Gulf of Aden.     

Trace elements in organic- and iron-rich surficial fluids of the boreal zone: Assessing colloidal forms via dialysis and ultrafiltration

On-site size fractionation of about 40 major and trace elements (TE) was performed on waters from boreal small rivers and their estuaries in the Karelia region of North-West Russia around the “Vetreny Belt” mountain range and in Paanajärvi National Park (Northern Karelia). Samples were filtered in the field using a progressively decreasing pore size (5 μm, 2.5 (3) μm, 0.22 (0.45) μm, 100 kDa, 10 and 1 kDa) by means of frontal filtration and ultrafiltration (UF) techniques and employing in-situ dialysis with 10 and 1 kDa membranes followed by ICP-MS analysis. For most samples, dialysis yields a systematically higher (factor of 2-3) proportion of colloidal forms compared to UF. Nevertheless, dialysis is able to provide a fast and artefact-free in-situ separation of colloidal and dissolved components.Similar to previous studies in European subarctic zones, poor correlation of iron concentration with that of organic carbon (OC) in (ultra)filtrates and dialysates reflect the presence of two pools of colloids composed of organic-rich and Fe-rich particles. All major anions and silica are present as dissolved species (or solutes) passing through the 1-kDa membrane. Size-separation ultrafiltration experiments show the existence of larger or smaller pools of colloidal particles different for each of the considered elements.The effect of rock lithology (acidic versus basic) on the colloidal speciation of TE is seen solely in the increase of Fe and some accompanying TE concentrations in catchment areas dominated by basic rocks compared to granitic catchments. Neither the ultrafiltration pattern nor the relative proportions of colloidal versus truly dissolved TE are affected by the lithology of the underlying rocks: within ±10% uncertainty, the two colloidal (10 kDa-0.22 μm and 1-10 kDa) and the truly dissolved (<1 kDa) pools show no difference in percentage of TE distribution between two types of bedrock lithology. The same conclusion is held for organic- and Fe-rich waters. In contrast, landscape context analysis demonstrated slight dominance, for most TE affected by UF, of large-size colloids (10 kDa-0.22 μm) in rivers and streams and small-size colloids and truly dissolved fractions in swamp stagnant surface waters. This supports the existence of two pathways of colloids formation: during the plant litter degradation in wetland zones and at the redox front in river riparian zone.     

Performance analysis of the spaceborne laser ranging system

The Spaceborne Laser Ranging System is a proposed short pulse laser on board an orbiting spacecraft.^1,2,3,4 It measures the distance between the spacecraft and many laser retroreflectors (targets) deployed on the Earth’s surface. The precision of these range measurements is assumed to be about ±2 cm (M. W. Fitzmaurice, private communication). These measurements are then used together with the orbital dynamics of the spacecraft, to derive the relative position of the laser ground targets. Assuming a six day observing period with 50% cloud cover, uncertainties in the baseline for target separations of 50 km to 1200 km were estimated to be on the order of 1 to 3 cm and the corresponding values in the vertical direction, ranged from 1 cm to 12 cm. By redetermining the measurements of the relative target positions, the estimated precision in the baseline for a target separation of 50 km is less than 0.3 cm and for a separation of 1200 km is less than 1 cm. In the vertical direction, the estimated precision ranged from 0.4 cm to 4.0 cm respectively. As a result of the repeated estimation of the relative laser target positions, most of the non-temporal effects of error sources as exemplified by the errors in geopotential are reduced. The Spaceborne Laser Ranging System’s capability of determining baselines to a high degree of precision provides a measure of strain and strain rate as shown byCohen, 1979. These quantities are essential for crustal dynamic studies which include determination and monitoring of strain near seismic zones, land subsidence, and edifice building preceding volcanic eruptions. It is evident that such a system can also be used for geodetic surveys where such precisions are more than adquate.     

Long-term deforestation in NW Spain: linking the Holocene fire history to vegetation change and human activities

The Holocene fire regime is thought to have had a key role in deforestation and shrubland expansion in Galicia (NW Spain) but the contribution of past societies to vegetation burning remains poorly understood. This may be, in part, due to the fact that detailed fire records from areas in close proximity to archaeological sites are scarce. To fill this gap, we performed charcoal analysis in five colluvial soils from an archaeological area (Campo Lameiro) and compared the results to earlier studies from this area and palaeo-ecological literature from NW Spain. This analysis allowed for the reconstruction of the vegetation and fire dynamics in the area during the last ca 11 000 yrs. In the Early Holocene, Fabaceae and Betula sp. were dominant in the charcoal record. Quercus sp. started to replace these species around 10 000 cal BP, forming a deciduous forest that prevailed during the Holocene Thermal Maximum until ～5500 cal BP. Following that, several cycles of potentially fire-induced forest regression with subsequent incomplete recovery eventually led to the formation of an open landscape dominated by shrubs (Erica sp. and Fabaceae). Major episodes of forest regression were (1) ～5500–5000 cal BP, which marks the mid-Holocene cooling after the Holocene Thermal Maximum, but also the period during which agropastoral activities in NW Spain became widespread, and (2) ～2000–1500 cal BP, which corresponds roughly to the end of the Roman Warm Period and the transition from the Roman to the Germanic period. The low degree of chronological precision, which is inherent in fire history reconstructions from colluvial soils, made it impossible to distinguish climatic from human-induced fires. Nonetheless, the abundance of synanthropic pollen indicators (e.g. Plantago lanceolata and Urtica dioica) since at least ～6000 cal BP strongly suggests that humans used fire to generate and maintain pasture.     

Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.