A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

The Role of the Magnetic Field in the Ascension of the 22nd and 23rd Cycles of Activity

The first small active regions of the last two new cycles seem to be formed, in its very first, preparatory stage, close to the equator with uncertain magnetic orientation, and as secondary products at the periphery of equatorial `magnetic bubbles' of the new magnetic flux still belonging to the old cycle. At the real beginning of the new cycle, at the periphery of its higher-latitude `magnetic bubbles', the opposite applies to the secondary regions of the ending cycle. It seems that two modes of magnetic flux supply the visible layers of the photosphere during the cycle transition phase: the emergence of the magnetic flux from the depth of the convective zone, and the mutual interaction of the earlier emerging fluxes, or the action of the `local dynamo', giving rise to the new local magnetic field concentrations.     

Mean crustal velocity: a critical parameter for interpreting crustal structure and crustal growth

Mean crustal velocity is a critical parameter for genesis of continental crystalline crust because it is a function of mean crustal composition and therefore may be used to resolve continental crustal growth in space and time. Although the best values of mean crustal velocity are determined from wide-angle reflection measurements, most studied here necessarily come from vertical averages in crustal refraction determinations. The mode of 158 values of mean crustal velocity is 6.3 km/s, a velocity which corresponds to a mean crustal composition of granodiorite to felsic quartz diorite; Archean crust may be slightly more mafic. Mean crustal velocities range from 5.8 to 7.0 km/s. The lowest values invariably are found in thermally disturbed rift zones and the highest values correspond to velocities in gabbro. Velocities in island arcs may be as low as 6.0 km/s but are typically 6.5–6.9 km/s which corresponds to andesitic composition; estimates of island arc composition are andesitic. If values of mean crustal velocity are not biased, this observation suggests that continental crust did not grow simply by addition of island arc material. Possibilities are that crust formed from fusion of island arcs and was later changed to more felsic composition by addition of material from the mantle or that the late Archean episode of major crustal growth did not involve processes similar to younger island arcs. Some crustal blocks might be changed in composition and thickness by such processes as underplating, interthrusting, necking and sub-crustal erosion. Specially designed experiments are suggested to determine this parameter so critical for understanding genesis of continental crust.     

Landslide triggering scenarios in homogeneous geological contexts: The area surrounding Acri (Calabria, Italy)

The paper describes a methodology to detect landslide triggering scenarios in geological homogeneous areas and for some specific landslide categories. In these scenarios, the rainfall–landslide relationship as well as the pluviometric load conditions influencing slope instability have to be investigated.The methodology is applied to an area located in northern Calabria (Italy) and affected by widespread and different slope instability phenomena. Outcropped, fractured, and deeply weathered crystalline rock masses, determining geologic homogeneous conditions, are present. In the same area, suitable and homogeneous climatic features have also been found.According to the methodology adopted, the hydrologic analysis of rainfall time-series is initially carried out notwithstanding historical data concerning landslide mobilization, but using simple models to determine critical pluviometric scenarios for the three landslide categories: shallow, medium-deep, and deep. Landslide-triggering scenarios individualized according to this procedure are less significant as compared to the landslide mobilization detected in the study area by means of historical research and ascribed to the three landslide categories according to geomorphologic analysis.Subsequently, the possible landslide triggering scenarios are outlined by carefully investigating the hydrologic analysis limited to the periods identified according to the historical data.In the study area and approximately for all the areas characterized by the outcrop of fractured and deeply weathered crystalline rocks, significant triggering scenarios can be outlined. In particular, shallow landslide triggers could be activated by rainfall events with intensities exceeding 90 mm/day and/or with amounts exceeding 160 mm. As for medium-deep and deep landslides, triggering mechanisms are more complicated; and effective rainfall contribution must be taken into account compared to groundwater storage. Moreover, a more complex link between deep landslides and precipitation is confirmed.The results obtained to date highlight the potential of this methodology, which enables us to define and progressively improve the knowledge framework by means of a work sequence integrating different disciplinary tools and results.     

The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

A Search for a Globular Cluster whose Passage Through the Galactic Disk Could Induce the Formation of the Gould Belt

The distribution of sites where globular clusters have crossed the Galactic disk during the last 100 million years has been analyzed using the most recent kinematic data for 133 globular clusters (GCs). ThreeGCs (NGC 6341, NGC 7078, and ω Cen) whose distances between the positions where they crossed the Galactic disk and trajectories of the Gould Belt are less than 20% of their heliocentric distances at the crossing time (82, 98, and 96 million years ago, respectively) have been identified. For each of the clusters, this was their next to last, rather than their last, crossing of the Galactic disk. The passage of any one of these three GCs through the disk could potentially have initiated the formation of the Gould Belt.     

Spatial analysis of linguistic data with GIS functions

Abstract

During the 1980s techniques for analysis of geographical patterns have been refined to the point that they may be applied to data from many fields. Quantitative spatial analysis and existing functions available in geographical information systems (GIS) enable computerized implementations of these spatial analysis methods. This paper describes the application of quantitative spatial analysis and GIS functions to analysis of language data, using the extensive files of the Linguistic Atlas of the Middle and South Atlantic States (LAMSAS). A brief review of recent development of using quantitative and statistical methods for analysing linguistic data is also included.     

Winter Temperature Variability During Warming and Cooling Periods in the Conterminous United States, 1947–1992

Summary  Much literature has reported on the concept of increased surface temperature variability during cool periods, although analyses on temperature records have rendered inconsistent results. In addition, temperature variability during transition periods has been rarely investigated. This study examines temperature variability during wintertime cooling (1947–1977) and warming (1978–1992) periods for the conterminous United States to determine both whether temperature variability is different during warming or cooling periods, and whether the change in variability is supported by midtropospheric circulation conditions. Our results indicate that regions with high temperature variability are mostly found below the troughs in the midtropospheric pressure fields. The direction of change in temperature variability corresponding to cooling or warming conditions, however, varied spatially. For the southeastern and northeastern United States, winter temperatures were more variable during the cooling period than during the warming period, while the northern and central Great Plains had greater temperature variability during the warming period than the cooling period. Similar spatial patterns are also found for the changes in the variability of geopotential height fields. Such spatial patterns in the temperature and height variability during warming and cooling periods may be related to the dominant midtropospheric circulation patterns, such as the different phases of the Pacific-North American teleconnection pattern, and the El Ni?o/Southern Oscillation events. It is concluded that the response of interannual temperature variability to climatic changes is determined by the variation in circulation patterns, and therefore, not spatially uniform. Received September 26, 1996 Revised April 2, 1998     

Stellar Tomography

I review recent progress in the field of stellar surface imaging, with particular reference to advanced methods for mapping surface-brightness inhomogeneities and the surface vector magnetic field on magnetically active late-type stars. New signal enhancement techniques, utilising profile information from hundreds or thousands of photospheric lines simultaneously, allow images to be derived for stars several magnitudes fainter than was previously possible. For brighter stars, the same techniques make it possible to map features as small as two or three degrees in extent on the stellar surface. This opens up whole new areas of research, such as the ability to use starspot tracking to study surface differential rotation patterns on single and binary stars, and to follow the secular evolution of the magnetic field itself. This revised version was published online in July 2006 with corrections to the Cover Date.