Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

The 1.80–1.74-Ga gabbro–anorthosite–rapakivi Korosten Pluton in the Ukrainian Shield: a 3-D geophysical reconstruction of deep structure

The deep structure of the gabbro–anorthosite–rapakivi granite (“AMCG-type”) Korosten Pluton (KP) in the northwestern Ukrainian Shield was studied by 3-D modelling of the gravity and magnetic fields together with previous seismic data. The KP occupies an area of ca. 12,500 km² and comprises several layered gabbro-anorthositic intrusions enveloped by large volumes of rapakivi-type granitoids. Between 1.80 and 1.74 Ga, the emplacement of mafic and associated granitoid melts took place in several pulses. The 3-D geophysical reconstruction included: (a) modelling of the density distribution in the crust using the observed Bouguer anomaly field constrained by seismic data on Moho depth, and (b) modelling of the magnetic anomaly field in order to outline rock domains of various magnetisation, size and shape in the upper and lower crust. The density modelling was referred to three depth levels of 0 to 5, 5 to 18, and 18 km to Moho, respectively. The 3-D reconstruction demonstrates close links between the subsurface geology of the KP and the structure of the lower crust. The existence of a non-magnetic body with anomalously high seismic velocity and density is documented. Most plausibly, it represents a gabbroic stock (a parent magma chamber) with a vertical extent of ca. 20 km, penetrating the entire lower crust. This stock has a half-cylindrical shape and a diameter of ca. 90 km. It appears to be connected with a crust–mantle transitional lens previously discovered by EUROBRIDGE seismic profiling. The position of the stock relative to the subsurface outlines of the KP is somewhat asymmetric. This may be due to a connection between the magmatism and sets of opposite-dipping faults initially developed during late Palaeoproterozoic collisional deformation in the Sarmatian crustal segment. Continuing movements and disturbances of the upper mantle and the lower crust during post-collisional tectonic events between 1.80 and 1.74 Ga may account for the long-lived, recurrent AMCG magmatism.     

Neotectonic deformation in the transition zone between the Dead Sea Transform and the East Anatolian Fault Zone, Southern Turkey: a palaeomagnetic study of the Karasu Rift Volcanism

In southern Turkey ongoing differential impingement of Arabia into the weak Anatolian collisional collage resulting from subduction of the Neotethyan Ocean has produced one of the most complex crustal interactions along the Alpine–Himalayan Orogen. Several major transforms with disputed motions, including the northward extension of the Dead Sea Fault Zone (DSFZ), meet in this region. To evaluate neotectonic motion on the Amanos and East Hatay fault zones considered to be northward extensions of the DSFZ, the palaeomagnetism of volcanic fields in the Karasu Rift between these faults has been studied. Remanence carriers are low-Ti magnetites and all except 5 of 51 basalt lavas have normal polarity. Morphological, polarity and K–Ar evidence show that rift formation occurred largely during the Brunhes chron with volcanism concentrated at 0.66–0.35 Ma and a subsidiary episode at 0.25–0.05. Forty-four units of normal polarity yield a mean of D/I=8.8°/54.7° with inclination identical to the present-day field and declination rotated clockwise by 8.8±4.0°. Within the 15-km-wide Hassa sector of the Karasu Rift, the volcanic activity is concentrated between the Amanos and East Hatay faults, both with left lateral motions, which have rotated blocks bounded by NW–SE cross faults in a clockwise sense as the Arabian Block has moved northwestwards. An average lava age of 0.5 Ma yields a minimum cumulative slip rate on the system bounding faults of 0.46 cm/year according with the rate deduced from the Africa–Arabia Euler vector and reduced rates of slip on the southern extension of the DSFZ during Plio-Quaternary times. Estimates deduced from offsets of dated lavas flows and morphological features on the Amanos Fault Zone [Tectonophysics 344 (2002) 207] are lower (0.09–0.18 cm/year) probably because they are limited to surface fault breaks and do not embrace the seismogenic crust.Results of this study suggest that most strike slip on the DSFZ is taken up by the Amanos–East Hatay–Afrin fault array in southern Turkey. Comparable estimates of Quaternary slip rate are identified on other faults meeting at an unstable FFF junction (DSFZ, East Anatolian Fault Zone, Karatas Fault Zone). A deceleration in slip rate across the DSFZ and its northward continuation during Plio-Quaternary times correlates with reorganization of the tectonic regime during the last 1–3 Ma including tectonic escape within Anatolia, establishment of the North and East Anatolian Fault Zones bounding the Anatolian collage in mid–late Pliocene times, a contemporaneous transition from transpression to transtension and concentration of all basaltic magmatism in this region within the last 1 Ma.