Condensation of combustion products in the exhaust plumes of rocket engines in the upper atmosphere

The condensation process of water vapors in the exhaust plume of a rocket engine in the upper atmosphere is considered. We take into account the processes of particle heating during the release of latent heat of condensation, radiative heating, and energy losses to emission. From the solution of the equations of thermal balance and mass balance of condensing particles, we obtained the time dependences of variations in temperature and particle sizes. In the process of condensation, the thickness of the ice layer on particles may reach >70 Å.     

Spectroscopic studies on soil organic fractions—II. IR and 1H-NMR spectra of methylated and unmethylated fulvic acids

The IR and ¹H-NMR spectra of fulvic acids (FA) are discussed. The FA, extracted by traditional methods, were fractionated on the basis of molecular weight (m.w.). Three fractions were obtained labelled FA I (m.w. > ～ 2000), FA II (m.w. > ～ 12000) and FA III (～2000 < m.w. < ～ 12000). Fraction FA II was methylated with CH₃I-Ag₂O. The ¹H-NMR spectra of unmethylated FA fractions show some signals common to all three fractions and some differences in the 3–5 ppm range due to the resonances of OCH₃ and O-CH₂ groups. The proton spectrum of the methylated fraction shows absorption areas for OCH₃ groups of phenols and carboxyls. The results confirm that NMR spectroscopy is a convenient technique which can contribute to defining the chemical structure of humic substances.     

Enzymatic and cellular responses in relation to body burden of PAHs in bivalve molluscs: A case study with chronic levels of North Sea and Barents Sea dispersed oil

Mytilus edulis and Chlamys islandica were exposed to nominal dispersed crude oil concentrations in the range 0.015–0.25 mg/l for one month. Five biomarkers (enzymatic and cellular responses) were analysed together with bioaccumulation of PAHs at the end of exposure. In both species, PAH tissue residues reflected the exposure concentration measured in the water and lipophylicity determined the bioaccumulation levels. Oil caused biomarker responses in both species but more significant alterations in exposed C. islandica were observed. The relationships between exposure levels and enzymatic responses were apparently complex. The integrated biomarker response related against the exposure levels was U-shaped in both species and no correlation with total PAH body burden was found. For the monitoring of chronic offshore discharges, dose- and time-related events should be evaluated in the selection of biomarkers to apply. From this study, cellular damages appear more fitted than enzymatic responses, transient and more complex to interpret.     

Generalization of TOPMODEL for a power law transmissivity profile

A generalization of the TOPMODEL equations for a power law vertical profile of hydraulic conductivity is introduced. The exponential profile of TOPMODEL is obtained as a limit case of the new general form. © 1997 John Wiley & Sons, Ltd.     

Mineralogy of the Ibitira eucrite and comparison with other eucrites and lunar samples

Ibitira meteorite is interpreted as a strongly metamorphosed, unbrecciated, vesicular eucrite with a primary variolitic and secondary hornfelsic texture dominated by 60% pyroxene (bulk composition En₃₇Fs₄₈Wo₁₅ exsolved into lamellae several micrometers wide of augite En₃₂Fs₂₇Wo₄₁ and pigeonite En₄₀Fs₅₆Wo₄) and 30% plagioclase An₉₄ (mosaic extinction and variable structural state). Minor phases are 5% tridymite plates one-quarter occupied by plagioclase (An₉₄) inclusions; several percent intergrowths of ilmenite and Ti-chromite with trace kamacite Fe₉₉Co_0.5Ni_0.2 and narrow olivine (Fa₈₃) rims; one grain of low-Ti-chromite enclosed in tridymite; trace troilite with kamacite Fe₉₈Co_1.0Ni_0.9. Euhedral ilmenite, Ti-chromite, plagioclase and merrillite in vesicles indicate vapor deposition. These properties can be explained by a series of processes including at least the following: (1) igneous crystallization under pressure low enough to allow vesiculation, (2) prolonged metamorphism, perhaps associated with vapor deposition and reduction, to produce the coarse exsolution of the pyroxene and the coarse ilmenite-chromite intergrowths, (3) strong shock which affected the plagioclase and tridymite but not the pyroxene, (4) sufficient annealing to allow recrystallization of the plagioclase and tridymite, and partial conversion to the low structural state of the former.     

New Find of Cuticular Coal in the Franz Josef Land

Coal pebbles found in 1994 in the Greham Bell Island (Franz Josef Land Archipelago) are made up of the Barzas-type cuticular liptobiolith. The coal belongs to the initial stage of catagenesis and is characterized by high content of cutinite (up to 70%) with very low reflectance (R_o= 0.1%). Maceration products show some tegillate elements of Arthropodaand individual Devonian spores. It is supposed that plant cuticle and Arthropoda exocuticle are present in this coal. The obtained data suggest the presence of Paleozoic rocks in the sedimentary sequence, although they are not yet recovered. These data complement the available information on the distribution of specific Devonian coals and allow us to have a new insight into the zoogenic material involved in the coal formation.     

Nonlinear and 3D effects in leaky infragravity waves

In this paper, infragravity (IG) waves, forced by normally and obliquely incident wave groups, are studied using the quasi-3D (Q3D) nearshore circulation model SHORECIRC [Van Dongeren, A.R., I.A. Svendsen, 1997b. Quasi 3-D modeling of nearshore hydrodynamics. Research report CACR-97-04. Center for Applied Coastal Research, University of Delaware, Newark, 243 pp.], which includes the Q3D effects. The governing equations that form the basis of the model, as well as the numerical model and the boundary conditions, are described. The model is applied to the case of leaky IG waves. It is shown that the Q3D terms have a significant effect on the cross-shore variation of the surface elevation envelope, especially around the breakpoint and in the inner surf zone. The effect of wave groupiness on the temporal and spatial variation of all Q3D terms is shown after which their contribution to the momentum equations is analyzed. This reveals that only those Q3D coefficients, which appear in combination with the largest horizontal velocity shears make a significant contribution to the momentum equations. As a result of the calculation of the Q3D coefficients, the IG wave velocity profiles can be determined. This shows that in the surf zone, the velocity profiles exhibit a large curvature and time variation in the cross-shore direction, and a small — but essential — depth variation in the longshore direction.     

Negative correlations of variations in near-water wind and surface wind waves

The relationship between the intensity of surface wind waves and near-water wind is analyzed. The data of measuring wind waves and near-water wind under natural conditions in the Black Sea (July 2004) and Norwegian Sea (June 2003, 16th cruise of the R/V Akademik Sergei Vavilov) are used. A phenomenon of negative correlations has been found between the intensity of wind waves and near-water wind in regions of substantial restructuring of wind waves in the field of inhomogeneous flows: wind-wave amplification during wind decay and vice versa. Examples of such observations are presented, a theoretical model is constructed for the observed phenomenon, and a good agreement is obtained between theory and experiment.     

Oceanographic Change and Terrestrial Human Impacts in a Post A.D. 1400 Sediment Record from the Southwest Iceland Shelf

Environmental proxies of soil erosion on Iceland, and oceanographic conditions on the adjacent shelf, were measured on a 50 cm box core taken from the southwest Iceland shelf in 1993 during cruise 93030 of the Canadian ship, CSS Hudson. These data, covering the last several centuries, are compared with the documentary record of sea-ice changes around Iceland since A.D. 1600. The site is under the influence of the Irminger Current, which carries warm, saline, Atlantic water northward along the shelf. Because of the relative warmth of this current, sea ice rarely occurs off southwest Iceland, even during the most severe sea-ice intervals of the historical record. In severe sea-ice years, however, the ice drifts clockwise around Iceland from the northeast and east and, in rare cases, reaches the southern coasts (Ogilvie, 1992). The chronology of the core was established by converting the basal radiocarbon date to calendar years and assuming a linear sedimentation rate from the base of the core to the year of collection, 1993. Organic carbon, stable C and O isotope ratios, planktonic foraminiferal assemblages, and sediment magnetic parameters were measured on samples from the core, plotted against calendar years and compared to the Icelandic sea-ice index. The environmental proxies suggest that increased soil erosion, reduced salinity, and, possibly, decreased marine productivity prevailed during the severe sea-ice interval lasting from the last quarter of the eighteenth century to around 1920. Such a situation could develop with climatic cooling, increased storminess, and loss of vegetation cover to stabilise the soil. Although the core site generally lies outside the sea-ice limits, the evidence clearly shows the influence of sea ice and fresh water, and is sensitive to the overall climatic deterioration manifested by the sea-ice record.     

Influence of source region properties on scaling relations forM<0 events

Excavation induced seismic events with moment magnitudesM<0 are examined in an attempt to determine the role geology, excavation geometry, and stress have on scaling relations. Correlations are established based on accurate measurements of excavation geometry and methodology, stress regime, rock mass structure, local tectonics, and seismic locations. Scaling relations incorporated seismic moments and source radii obtained by spectral analysis, accounting for source, propagation, and site effects, and using Madariaga's dynamic circular fault model. Observations suggest that the interaction of stresses with pre-existing fractures, fracture complexity and depth of events are the main factors influencing source characteristics and scaling behaviour. Self-similar relationships were found for events at similar depths or for weakly structured rock masses with reduced clamping stresses, whereas a non-similar behaviour was found for events with increasing depth or for heavily fractured zones under stress confinement. Additionally, the scaling behaviour for combined data sets tended to mask the non-similar trends. Overall, depth and fracture complexity, initially thought as second order effects, appear to significantly influence source characteristics of seismic events withM<0 and consequently favour a non-similar earthquake generation process.