Time varying rotary spectra

A method for computing and displaying the temporal variation of rotary spectral estimates is described. The method is applied to time series measurements of highly nonstationary winds and currents. The results indicate approximately fortnightly modulation of diurnal wind energy and inertial current energy.     

Confidence regions in ternary diagrams based on the power-divergence statistics

Watson and Nguyen (1985) and Watson (1987) consider the problem of plotting confidence regions in a ternary diagram, for a trinomial probability vector , based on Pearson's x². Their results are extended to the power-divergence family of statistics resulting in confidence regions of diverse shapes and sizes. The members of the family with the most accurate coverage probabilities are =2/3 and =1/2.     

Genesis of Re-rich Molybdenite in the Baishan Mo deposit,Eastern Tianshan,Xinjiang, Northwest China

The Baishan molybdenum deposit is located in the central part of the Eastern Tianshan-Beishan tectonic belt, NW China. The deposit is hosted in early Carboniferous Gandun Formation biotite-rich hornfels and is genetically related to unexposed granodiorite porphyry beneath the orebodies. The molybdenite occurs in three different types from early to late stage: Molybdenite - Fe-Cu-sulfides - K-feldspar - quartz veins (Group 1); Molybdenite - Fe-Cu-sulfides - quartz veins (Group 2); and disseminated molybdenite in the wall rock (Group 3). Rhenium concentrations in the molybdenite grains range from 108 to 277 ppm in Group 1, 69–121 ppm in Group 2 and 46–135 ppm in Group 3. The Re concentrations of molybdenite in the Baishan Mo deposit decrease from early to late and from the center to periphery, and molybdenite types vary from the 2H₁ poly-type in Groups 1 and 2 to the 2H₁ + 3R2H₁ poly-type in Group 3, based on X-ray diffraction results. The Re-enriched molybdenite probably formed from an oxidized magmatic fluid that separated from a highly oxidized and H₂O- and volatile-enriched adakitic intrusion generated in the lower crust.     

Mineralogical, fluid inclusion, and stable isotope constraints on mechanisms of ore deposition at the Samgwang mine (Republic of Korea)—a mesothermal, vein-hosted gold–silver deposit

The Samgwang mine is located in the Cheongyang gold district (Cheonan Metallogenic Province) of the Republic of Korea. It consists of eight massive, gold-bearing quartz veins that filled NE- and NW-striking fractures along fault zones in Precambrian granitic gneiss of the Gyeonggi massif. Their mineralogy and paragenesis allow two separate vein-forming episodes to be recognized, temporally separated by a major faulting event. The ore minerals occur in quartz and calcite of stage I, associated with fracturing and healing of veins. Hydrothermal wall-rock alteration minerals of stage I include Fe-rich chlorite (Fe/(Fe+Mg) ratios 0.74-0.81), muscovite, illite, K-feldspar, and minor arsenopyrite, pyrite, and carbonates. Sulfide minerals deposited along with electrum during this stage include arsenopyrite, pyrite, pyrrhotite, sphalerite, marcasite, chalcopyrite, galena, argentite, pyrargyrite, and argentian tetrahedrite. Only calcite was deposited during stage II. Fluid inclusions in quartz contain three main types of C–O–H fluids: CO₂-rich, CO₂–H₂O, and aqueous inclusions. Quartz veins related to early sulfides in stage I were deposited from H₂O–NaCl–CO₂ fluids (1,500–5,000 bar, average 3,200) with T _htotal values of 200°C to 383°C and salinities less than about 7 wt.% NaCl equiv. Late sulfide deposition was related to H₂O–NaCl fluids (140–1,300 bar, average 700) with T _htotal values of 110°C to 385°C and salinities less than about 11 wt.% NaCl equiv. These fluids either evolved through immiscibility of H₂O–NaCl–CO₂ fluids as a result of a decrease in fluid pressure, or through mixing with deeply circulated meteoric waters as a result of uplift or unloading during mineralization, or both. Measured and calculated sulfur isotope compositions (δ³⁴S_H2S = 1.5 to 4.8‰) of hydrothermal fluids from the stage I quartz veins indicate that ore sulfur was derived mainly from a magmatic source. The calculated and measured oxygen and hydrogen isotope compositions (δ¹⁸O_H2O = −5.9‰ to 10.9‰, δD = −102‰ to −87‰) of the ore-forming fluids indicate that the fluids were derived from magmatic sources and evolved by mixing with local meteoric water by limited water–rock exchange and by partly degassing in uplift zones during mineralization. While most features of the Samgwang mine are consistent with classification as an orogenic gold deposit, isotopic and fluid chemistry indicate that the veins were genetically related to intrusions emplaced during the Jurassic to Cretaceous Daebo orogeny.     

Robust estimation of the variogram: I

It is a matter of common experience that ore values often do not follow the normal (or lognormal) distributions assumed for them, but, instead, follow some other heavier-tailed distribution. In this paper we discuss the robust estimation of the variogram when the distribution is normal-like in the central region but heavier than normal in the tails. It is shown that the use of a fourth-root transformation with or without the use of M-estimation yields stable robust estimates of the variogram.Visiting Scientist, NRIMS, during the period in which this work was carried out.