Cross-Validation of Open-Path and Closed-Path Eddy-Covariance Techniques for Observing Methane Fluxes

Methane ( ${\mathrm {CH}}_{4}$ ) fluxes observed with the eddy-covariance technique using an open-path ${\mathrm {CH}}_{4}$ analyzer and a closed-path ${\mathrm {CH}}_{4}$ analyzer in a rice paddy field were evaluated with an emphasis on the flux correction methodology. A comparison of the fluxes obtained by the analyzers revealed that both the open-path and closed-path techniques were reliable, provided that appropriate corrections were applied. For the open-path approach, the influence of fluctuations in air density and the line shape variation in laser absorption spectroscopy (hereafter, spectroscopic effect) was significant, and the relative importance of these corrections would increase when observing small ${\mathrm {CH}}_{4}$ fluxes. A new procedure proposed by Li-Cor Inc. enabled us to accurately adjust for these effects. The high-frequency loss of the open-path ${\mathrm {CH}}_{4}$ analyzer was relatively large (11 % of the uncorrected covariance) at an observation height of 2.5 m above the canopy owing to its longer physical path length, and this correction should be carefully applied before correcting for the influence of fluctuations in air density and the spectroscopic effect. Uncorrected ${\mathrm {CH}}_{4}$ fluxes observed with the closed-path analyzer were substantially underestimated (37 %) due to high-frequency loss because an undersized pump was used in the observation. Both the bandpass and transfer function approaches successfully corrected this flux loss. Careful determination of the bandpass frequency range or the transfer function and the cospectral model is required for the accurate calculation of ${\mathrm {CH}}_{4}$ fluxes with the closed-path technique.     

Statistical downscaling of sea-surface wind over the Peru�CChile upwelling region: diagnosing the impact of climate change from the IPSL-CM4 model

The key aspect of the ocean circulation off Peru?CChile is the wind-driven upwelling of deep, cold, nutrient-rich waters that promote a rich marine ecosystem. It has been suggested that global warming may be associated with an intensification of upwelling-favorable winds. However, the lack of high-resolution long-term observations has been a limitation for a quantitative analysis of this process. In this study, we use a statistical downscaling method to assess the regional impact of climate change on the sea-surface wind over the Peru?CChile upwelling region as simulated by the global coupled general circulation model IPSL-CM4. Taking advantage of the high-resolution QuikSCAT wind product and of the NCEP reanalysis data, a statistical model based on multiple linear regressions is built for the daily mean meridional and zonal wind at 10?m for the period 2000?C2008. The large-scale 10?m wind components and sea level pressure are used as regional circulation predictors. The skill of the downscaling method is assessed by comparing with the surface wind derived from the ERS satellite measurements, with in situ wind observations collected by ICOADS and through cross-validation. It is then applied to the outputs of the IPSL-CM4 model over stabilized periods of the pre-industrial, 2?×?CO₂ and 4?×?CO₂ IPCC climate scenarios. The results indicate that surface along-shore winds off central Chile (off central Peru) experience a significant intensification (weakening) during Austral winter (summer) in warmer climates. This is associated with a general decrease in intra-seasonal variability.     

Characterization of polychlorinated biphenyls and brominated flame retardants in sediments from riverine and coastal waters of Surabaya, Indonesia

A total of 33 surficial sediments from riverine and coastal waters from Surabaya, Indonesia were analyzed for PCBs and BFRs. Concentrations of PCBs (62 congeners), PBDEs (14 congeners) and HBCDs (3 isomers) varied from <DL-420, <DL-35 and <DL-5.4 ng g⁻¹ dw, respectively. Higher concentrations of these compounds were found in riverine than coastal sediments. Their levels and distribution were influenced by proximity to the point sources and TOC. The predominant congeners were CB-153, -28, -138, -149, -180, -33 and BDE-209, -207, -206, -197, -196, -183, -99, -47 for PCBs and PBDEs, respectively, and γ-isomer for HBCDs. Debromination of BDE-209 might be taking place producing lower toxic congeners in sediment. Levels of PCBs in riverine sediments were comparable with some polluted areas worldwide, but PBDEs and HBCDs were lower. Hazard assessment of PCBs indicated possible toxic potential, particularly in areas close to point sources.     

Long-term diatom fluxes in response to oceanographic conditions at Stations AB and SA in the central subarctic Pacific and the Bering Sea, 1990–1998

Long-term monitoring of diatom fluxes during 1990–1998 was conducted at Station AB in the Bering Sea and Station SA in the central subarctic Pacific in order to decipher the relationships between sinking diatom and the upper water mass environments. The total diatom flux at Station AB was generally twice as high as that at Station SA. The dominant species in the sinking flora was primarily Neodenticula seminae at both stations, which was a significant contributor to organic carbon flux. The flora at Station AB was represented by relatively abundant coastal taxa including Chaetoceros resting spores. These results suggest more favorable conditions for diatom production at Station AB compared with those at Station SA. The possible influences of oligotrophic and temperate water masses were discerned from the positive SST anomaly and the occurrence of a few specimens of temperate species. The cumulative annual fluxes of total diatoms at Stations AB and SA are apparently related to the variation in the mean annual depth of mixed layer. At Station SA, annual mean of total diatom flux showed a negative correlation with the Pacific Decadal Oscillation (PDO) Index, which suggests a significant relationship between surface water turbidity and diatom production. At Station AB, the annual change of coastal diatom flux was correlated with the PDO and the winter value of the Arctic Oscillation, which may suggest a significant influence of Alaskan Stream waters via the Aleutian Islands and intensity of surface water mixing.     

Lessons Learned from the 2011 Great East Japan Tsunami: Performance of Tsunami Countermeasures, Coastal Buildings, and Tsunami Evacuation in Japan

In 2011, Japan was hit by a tsunami that was generated by the greatest earthquake in its history. The first tsunami warning was announced 3 min after the earthquake, as is normal, but failed to estimate the actual tsunami height. Most of the structural countermeasures were not designed for the huge tsunami that was generated by the magnitude M = 9.0 earthquake; as a result, many were destroyed and did not stop the tsunami. These structures included breakwaters, seawalls, water gates, and control forests. In this paper we discuss the performance of these countermeasures, and the mechanisms by which they were damaged; we also discuss damage to residential houses, commercial and public buildings, and evacuation buildings. Some topics regarding tsunami awareness and mitigation are discussed. The failures of structural defenses are a reminder that structural (hard) measures alone were not sufficient to protect people and buildings from a major disaster such as this. These defenses might be able to reduce the impact but should be designed so that they can survive even if the tsunami flows over them. Coastal residents should also understand the function and limit of the hard measures. For this purpose, non-structural (soft) measures, for example experience and awareness, are very important for promoting rapid evacuation in the event of a tsunami. An adequate communication system for tsunami warning messages and more evacuation shelters with evacuation routes in good condition might support a safe evacuation process. The combination of both hard and soft measures is very important for reducing the loss caused by a major tsunami. This tsunami has taught us that natural disasters can occur repeatedly and that their scale is sometimes larger than expected.     

Phytoplankton and ice-algal communities in the seasonal ice zone during January (Southern Ocean,Indian sector)

Journal of Oceanography - In the seasonal ice zone (SIZ), sea-ice algae have been hypothesized to influence phytoplankton species composition in seawater after melting from sea ice. However,...     

Ore‐forming Ages and Sulfur Isotope Study of Hydrothermal Deposits in Kamchatka,Russia

In Kamchatka, Central Koryak, Central Kamchatka and East Kamchatka metallogenic belts are distributed from northwest to southeast. K–Ar age, sulfur isotopic composition of sulfide minerals, and bulk chemical compositions of ores were analyzed for 13 ore deposits including hydrothermal gold‐silver and base metal, in order to elucidate the geological time periods of ore formation, relationship to regional volcanic belts, type of mineralization, and origin of sulfur in sulfides. The dating yielded ore‐forming ages of 41 Ma for the Ametistovoe deposit in the Central Koryak, 17.1 Ma for the Zolotoe deposit and 6.9 Ma for the Aginskoe deposit in the Central Kamchatka, and 7.4 Ma for the Porozhistoe deposit and 5.1 Ma for the Vilyuchinskoe deposit in the East Kamchatka metallogenic belt. The data combined with previous data of ore‐forming ages indicate that the time periods of ore formation in these metallogenic belts become young towards the southeast. The averaged δ³⁴S_CDT of sulfides are ?2.8‰ for the Ametistovoe deposit in Central Koryak, ?1.8‰ to +2.0‰ (av. ?0.1‰) for the Zolotoe, Aginskoe, Baranievskoe and Ozernovskoe deposits in Central Kamchatka, and ?0.7 to +3.8‰ (av. +1.7‰) for Bolshe‐Bannoe, Kumroch, Vilyuchinskoe, Bystrinskoe, Asachinskoe, Rodnikovoe, and Mutnovskoe deposits in East Kamchatka. The negative δ³⁴S_CDT value from the Ametistovoe deposit in Central Koryak is ascribed to the contamination of ³²S‐enriched sedimentary sulfur in the Ukelayat‐Lesnaya River trough of basement rock. Comparison of the sulfur isotope compositions of the mineral deposits shows similarity between the Central Koryak and Magadan metallogenic belts, and East Kamchatka and Kuril Islands belts. The Central Kamchatka belt is intermediate between these two groups in term of sulfur isotopic composition.