Distribution of titanium atoms in oxy-kaersutite

The distribution of Ti atoms in oxy-kaersutite has been studied by the neutron diffraction method. The cation distribution over the three octahedral sites determined by the x-ray method (Kitamura and Tokonami, 1971) is as follows; M1∶0.40MG+0.60 FE, M2∶0.75 MG+0.25 FE, M3∶0.50 MG+0.50 FE, where MG and FE represent (Mg+Al) and (Fe+Ti), respectively. The neutron diffraction study indicates that Ti atoms are enriched in the M1 site more than M2 and M3 sites as follows; M1∶0.40 MG+0.33 Fe+0.27 Ti, M2∶ 0.75 MG+0.23 Fe+0.02 Ti, M3∶0.50 MG+0.46 Fe+0.04 Ti. This distribution agrees with the result based on the Madelung energy of oxy-kaersutite by Whittaker (1972).     

A lower trophic ecosystem model including iron effects in the Okhotsk Sea

We applied a three-dimensional ecosystem-physical coupled model including iron the effect to the Okhotsk Sea. In order to clarify the sources of iron, four dissolved iron compartments, based on the sources of supply, were added to Kawamiya et al.'s [1995, An ecological-physical coupled model applied to Station Papa. Journal of Oceanography, 51, 635-664] model (KKYS) to create our ecosystem model (KKYS-Fe). We hypothesized that four processes supply iron to sea water: atmospheric loadings from Northeastern Asia, input from the Amur River, dissolution from sediments and regeneration by zooplankton and bacteria. We simulated one year, from 1 January 2001 to 31 December 2001, using both KKYS-Fe and KKYS. KKYS could not reproduce the surface nitrate distribution after the spring bloom, whereas KKYS-Fe agreed well with observations in the northwestern Pacific because it includes iron limitation of phytoplankton growth. During the spring bloom, the main source of iron at the sea surface is from the atmosphere. The contribution of riverine iron to the total iron utilized for primary production is small in the Okhotsk Sea. Atmospheric deposition, the iron flux from sediment and regeneration of iron in the water column play important roles in maintaining high primary production in the Okhotsk Sea.     

Application of Continuous 222Rn Monitor with Dual Loop System in a Small Lake

To estimate the spatial distribution of groundwater discharge from the bottom of a small lake of Kumamoto in Japan, we applied continuous radon measurements with a dual loop system and verified the results obtained using the radon method by visual diving surveys. Time‐shifting correction in the dual‐loop system is reasonable to obtain the true radon activity in water. Distributions of radon activity and water temperature in the study area reveal the effects on groundwater discharge and mixing situation of lake water. The estimated discharge zone ascertained using the radon method agrees with the groundwater discharge distribution observed through diving surveys. Although the data resolution of the radon method is much greater than the width of observed discharge zones, the general distribution of groundwater discharge is recognizable. The dual loop system of radon measurement is useful for smaller areas.     

Comparison of stable isotopes,ratios of Cl/Cl and I/I in brine and deep groundwater from the Pacific coastal region and the eastern margin of the Japan Sea

Fifty-three samples, including brines associated with oil and natural gas reservoirs and groundwater samples from deep boreholes, were collected from the Pacific and Japan Sea coastal regions in Japan. The ¹²⁹I/¹²⁷I and ³⁶Cl/Cl ratios, and stable isotopes (δD and δ¹⁸O) are compared to investigate differences related to the geotectonic settings of the two regions. The δD and δ¹⁸O data indicate that brine and groundwater from the Pacific coastal region reflect mixing of meteoric water with connate seawater in the pores of sedimentary rocks. On the other hand, brine and groundwater from the Japan Sea coastal region have been hydrothermally altered. In particular, brines associated with petroleum accumulations at Niigata and Akita showed the same isotopic characteristics as fluids found in the Kuroko deposits of the Green Tuff region in northeastern Japan. There is little difference in the ³⁶Cl/Cl ratios in brine and groundwater from the Pacific and Japan Sea coasts. Most brine and some deep groundwater, except those from the Pleistocene Kazusa Group, have already reached the average secular equilibrium ratio of 9.9 ± 2.7 × 10⁻¹⁵ for their mudstone and sandstone reservoirs. There was no correlation between the ³⁶Cl/Cl ratios and differences in geotectonic setting between the Pacific and the Japan Sea coast. The molar I/Br ratio suggests that the I in all of water samples was of biogenic origin. The average ¹²⁹I/¹²⁷I ratio was 290 ± 130 × 10⁻¹⁵ to 294 ± 105 × 10⁻¹⁵ in both regions, showing no relationship to the different geotectonic settings. The uncontaminated brine and groundwater samples are likely to have retained the original ¹²⁹I/¹²⁷I ratios of marine I released from the old organic matter stored in sedimentary rock.     

Assessment of rainfall-induced shallow landslides in Phetchabun and Krabi provinces,Thailand

Shallow landslides are a common type of rainfall-induced landslide, and various methods are currently used to predict their occurrence on a regional scale. Physically based models, such as the shallow landslide instability prediction (SLIP) model, have many advantages because these models can assess the hazards of shallow landslides dynamically, based on physical stability equations that consider rainfall as a triggering factor. The main objective of this research is to test the SLIP model’s potential to predict shallow landslide hazards in Thailand. To achieve this goal, the SLIP model was applied to two massive landslide events in Thailand. The results predicted by the SLIP model for the two study areas are outlined, and the model prediction capabilities were evaluated using the receiver operating characteristic plot. The Phetchabun results showed that the western part of the catchment had the lowest factor of safety (F _S) value, whereas the Krabi results showed that the slopes surrounding the peak of Khao Panom Mountain had the lowest F _S value, explaining the highest potentials for shallow landslides in each area. The SLIP model showed good performance: The global accuracies were 0.828 for the Phetchabun area and 0.824 for the Krabi area. The SLIP model predicted the daily time-varying percentage of unstable areas over the analyzed periods. The SLIP model simulated a negligible percentage of unstable areas over all considered periods, except for expected dates, suggesting that the prediction capability is reasonably accurate.     

A Simulation Study of the Plasma Wave Enhancements in the Earth’s Equatorial Plasmasphere

In the equatorial plasmasphere, plasma waves are frequently observed. To improve our understanding of the mechanism generating plasma waves from instabilities, a comparison of observations, linear growth-rate calculations, and simulation results is presented. To start the numerical experiments from realistic initial plasma conditions, we use the initial parameters inferred from observational data obtained around the plasma-wave generation region by the Akebono satellite. The linear growth rates of waves of different modes are calculated under resonance conditions, and compared with simulation results and observations. By employing numerical experiments by a particle code, we first show that upper hybrid-, Z-, and whistler-mode waves are excited through instabilities driven by a ring-type velocity distribution. The simulation results suggest a possibility that energetic electrons with energies of some tens of keV confined around the geomagnetic equator are responsible for the observed enhancements of Z- and whistler-mode waves. While the comparison between linear growth-rate calculations and observations shows the different tendency of wave amplitude of Z-mode and whistler-mode waves, the wave amplitude of these wave modes in the simulation results is consistent with the observation.     

Effects of low pCO2 conditions on sea urchin larval size

Ocean acidification results from an increase in the concentrations of atmospheric carbon dioxide (CO₂) impacts on marine calcifying species, which is predicted to become more pronounced in the future. By the end of this century, atmospheric pCO₂ levels will have doubled relative to the pre‐industrial levels of 280 ppm. However, the effects of pre‐industrial pCO₂ levels on marine organisms remain largely unknown. In this study, we investigated the effects of pre‐industrial pCO₂ conditions on the size of the pluteus larvae of sea urchins, which are known to be vulnerable to ocean acidification. The larval size of Hemicentrotus pulcherrimus significantly increased when reared at pre‐industrial pCO₂ level relative to the present one, and the size of Anthocidaris crassispina larvae decreased as the pCO₂ levels increased from the pre‐industrial level to the near future ones after 3 days' exposure. In this study, it is suggested that echinoid larvae responded to pre‐industrial pCO₂ levels. Ocean acidification may be affecting some sensitive marine calcifiers even at the present pCO₂ level.     

Particle-tracking simulation for the drift/diffusion of spilled oils in the Sea of Okhotsk with a three-dimensional, high-resolution model

To conduct the simulation of oil spills in the Sea of Okhotsk, we developed a three-dimensional, high-resolution ocean circulation model. The model particularly improved the reproducibility of velocity field during the strong stratification period. Particle-tracking experiments with the effects of evaporation and biodegradation were performed using the combined data of daily ocean currents from the present model and the hourly diurnal tidal currents from the tidal model. The results are shown by the relative concentration of the particles averaged over the 8 years of 1998–2005 based on the ensemble forecast idea. For the case of particles released from the Sakhalin II oil field, the particles deployed in September–January are carried southward by the East Sakhalin Current, finally arriving at the Hokkaido coast, after 60–90 days. The particles deployed in March–August are diffused offshore by the synoptic wind drift, and hardly transported to regions south of Sakhalin. For the case of particles released from the region off Prigorodnoye, the oil export terminal, after the diffusion by the synoptic wind drift, a part of them are carried offshore of Hokkaido by the Soya Warm Current. The particles released in November–April flow out to the Japan Sea through the Soya Strait, mainly by the synoptic wind drift and secondly by the diffusion due to strong tidal currents around the Soya Strait. By considering the effects of evaporation and biodegradation, the relative concentration of the particles is considerably decreased before arriving at the Hokkaido coast, particularly in the case of drift from the Sakhalin II oil field.     

初夏热带西太平洋对流云团周期性西北传播与梅雨带的变动

为了了解来自低纬度的气象因素对梅雨带季节内变化的影响,文中对1985年和1986年6～7月份的个例进行了细致诊断,并针对有关问题用历史资料做了统计和合成.发现(1)梅雨雨带的向北位移与10～15°N/140°E附近的热带对流云团向西移动有连带关系,当热带对流云团向西北移动时副热带高压也向西北扩张,顺次由东向西影响梅雨带北抬.(2)低纬度向西北方向移动的对流云团具有准8,18以及30 d周期.(3)中国江淮梅雨的入梅也与6月份第一次出现这种对流云团周期性(8,18以及30 d)西北移动有密切关系.