Coronal electron density maps for 7 March, 1970, derived from Mgx λ625 spectroheliograms

We have analyzed daily Mgx 625 spectroheliograms acquired by the Harvard College Observatory experiment on OSO-6 for a 28-day period centered on 7 March, 1970, the date of a well-observed total solar eclipse. These data are used to construct maps of the variation across the solar disk of the electron density at the base of the corona. The correspondence of high and low density regions with regions of enhanced and reduced emission in white light and Mgx pictures made during or near the time of the eclipse are described.     

Anomalous strontium and lead isotope signatures in the off-rift Öræfajökull central volcano in south-east Iceland: Evidence for enriched endmember(s) of the Iceland mantle plume?

The currently active off-rift central volcano Öræfajökull in south-east Iceland sits unconformably on much older (10–12 Ma) and eroded crust. The composition of recent volcanics ranges from basalt to rhyolite, but the series is more sodic alkaline than the common rift zone tholeiitic suites. In this study we present Sr, Nd, Pb and O isotopic data for a suite of Öræfajökull samples. The complete suite shows typical mantle values for oxygen isotopes. The ⁸⁷Sr/⁸⁶Sr ratios (average of 15 SAMPLES=0.703702) of the modern Öræfajökull rocks (basalts as well as rhyolites) are much higher than observed so far for any other Icelandic rocks. The ¹⁴³Nd/¹⁴⁴Nd ratios (average=0.512947; n=15) are lower than for rift rocks, but similar to rocks of the off-rift Snæfellsnes volcanic zone. Furthermore, the Öræfajökull rocks are enriched in the ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb isotope ratios compared to Icelandic rift basalts. The enriched nature of the suite indicates that Öræfajökull samples a source component that has characteristics common with EM2 type mantle. Furthermore, it is concluded that the silicic rocks of Öræfajökull formed by fractional crystallization from mafic melts rather than by partial melting of older crust.     

Petrophysical characterization and natural fracturing in an olivine-dolerite aquifer

As part of a study investigating the naturally-occurring fractures in mafic rocks, two holes were drilled 450 m apart through the Palisades dolerite sill in New York. Well-2 is 229 m deep and Well-3 was drilled to 305 m, both penetrating through the sill and into the underlying Triassic sediments of the Newark Basin. Both holes were logged with downhole geophysical tools, including the BHTV, which acoustically images fractures intersecting the well. Understanding the fracture pattern, density, and porosity in the sill is essential for identifying possible zones of active fluid flow and high permeability. Using the BHTV logs, 96 and 203 fractures were digitally mapped within the sill in Well-2 and Well-3, respectively. Most fractures appear to dip steeply (76-78°). There is a shift in fracture orientation, however, and these fractures may or may not be continuous over the short lateral distance between Well-2 and Well-3. The lithology of the sill as identified by drill chips is nevertheless continuous between the holes. Both intersect a 7 m thick olivine-rich layer about 15 m above the bottom of the sill. Several fractures identified in Well-2 have large apparent aperture (>6cm) which correspond to high porosity zones (6-14%) observed in the logs. Resistivity logs were used to compute porosity using Archie's law and match well with the neutron porosity log in Well-2. We use the relationship between porosity and fracture aperture within the sill at Well-2 to infer the porosity in Well-3. High-porosity, large-aperture zones, including the target olivine layer, are identified in both holes. Changes in the temperature gradient log indicate active fluid flow in the sill, although flow appears to be most active in the sediments. Direct field measurements of bulk permeability, hydrologic modeling of fluid flow and calibration of fracture and log porosity will be undertaken in the future.     

Isotopic composition of formation waters from deep drillings in southern Israel

Formation water samples from deep drillings in southern Israel fall into three regional groups, each of which shows distinct chemical and isotopic characteristics. Waters from the Mediterranean coastal plain appear to be of marine lagoonal origin; some of these brines are associated with occurrences of oil. In the mountain region the top part of the sedimentary sequence has been flushed by fresher waters, apparently during Pleistocene time. In Jurassic and deeper-lying formations one encounters concentrated brines of seawater origin, with low Na/Ca ratios, which have undergone a process of ultrafiltration. In the Rift Valley proper, magnesium-rich brines have invaded the deeper formations, and are evidently of continental lake origin.The absence of oil occurrences in association with the CaCl₂ brines of the inland locations is interpreted as being due mainly to loss of oil as a result of the tectonic events associated with the formation of the Jordan Rift Valley.     

Asphalts, heavy oils, ozocerite and gases in the Dead Sea Basin

Solid, liquid and gaseous hydrocarbons occur throughout the Dead Sea Basin (Israel and Jordan) both in surface exposures and in drillings. The unaltered asphalts and heavy oils are characterized by very high sulfur content (ca. 11%) with δ³⁴S = +5% and δ¹³C = −28% to −29%, low content of n-paraffins, pristane to phytane ratio of 0.5 and by containing almost exclusively VO-porphyrins. The distribution of n-paraffins in samples from deep sources shows a smooth enveloped miximizing at C_15–20. Surface and shallow samples show clear evidence of biodegradation. The ozokerite, known only from the east side of the basin, is composed primarily of long chain n-paraffins with a maximum at C₃₉. The gases known from the southern margin of the basin are composed mostly of methane.The source for the bitumens is unknown. Two hypotheses are discussed. The first is that the asphalts and heavy oils represent an alteration products of crude oil which migrated into the basin or which might have been generated in the basin itself. The second hypothesis favors an origin from low temperature alteration of organic matter from a thermally immature source.     

Trace organic contamination in the Americas: An overview of the US National Status & Trends and the International ‘Mussel Watch’ programmes

The National Status & Trends (NS&T, 1986–1993) and the International Mussel Watch (IMW, 1991–1992) programmes provide a good coverage of a broad range of environmental conditions along the North, Central and South American coasts. Total concentrations of DDTs, chlordane-related compounds, PCBs and PAHs present fairly homogeneous distributions along the northern Gulf of Mexico coast, with very few sites showing extremely high or low concentrations. In contrast, a larger variability in the geographical distribution of some of these organic contaminants was observed for IMW sites. For example, high concentrations of DDT and its metabolites, DDD and DDE, were generally found in tropical and subtropical areas as compared to more temperate zones of South America. ‘Industrial’ contaminants, such as PCBs and PAHs, have similar distributions with the highest concentrations encountered generally along the southern South Atlantic coast. An overall comparison of the concentrations of these organic contaminants measured at NS&T and IMW sites indicates that contamination is significantly higher along the northern coast of the Gulf of Mexico.