Boron metasomatism and behaviour of rare earth elements during formation of tourmaline rocks in the eastern Arunta Inlier,central Australia

Tourmaline rocks of previously unclear genesis and spatially associated with W- (Cu)-bearing calc-silicate rocks occur in Palaeoproterozoic supracrustal and felsic intrusive rocks in the Bonya Hills in the eastern Arunta Inlier, central Australia. Tourmalinisation of metapelitic host rocks postdates the peak of regional low-pressure metamorphism (M₁/D₁, ~500 °C, ~0.2 GPa), and occurred synkinematically between the two main deformation events D₁ and D₂, coeval with emplacement of Late Strangways (~1.73 Ga) tourmaline-bearing leucogranites and pegmatites. Tourmaline is classified as schorl to dravite in tourmaline–quartz rocks and surrounding tourmaline-rich alteration zones, and as Fe-rich schorl to foitite in the leucogranites. Boron metasomatism resulted in systematic depletion of K, Li, Rb, Cs, Mn and enrichment of B, and in some samples of Na and Ca, in the tourmaline rocks compared to unaltered metasedimentary host rocks. Whole-rock REE concentrations and patterns of unaltered schist, tourmalinised schist and tourmaline–quartz veins—the latter were the zones of influx of the boron-rich hydrothermal fluid—are comparable to those of post-Archaean shales. Thus, the whole-rock REE patterns of these rocks are mostly controlled by the metapelitic precursor. In contrast, REE concentrations of leucogranitic rocks are low (10 times chondritic), and their flat REE patterns with pronounced negative Eu anomalies are typical for fractionated granitic melts coexisting with a fluid phase. REE patterns for tourmalines separated from metapelite-hosted tourmaline–quartz veins and tourmaline-bearing granites are very different from one another but each tourmaline pattern mirrors the REE distribution of its immediate host rock. Tourmalines occurring in tourmaline–quartz veins within tourmalinised metasediments have LREE-enriched (La_N/Yb_N=6.3–55), shale-like patterns with higher REE (54–108 ppm). In contrast, those formed in evolved leucogranites exhibit flat REE patterns (La_N/Yb_N=1.0–5.6) with pronounced negative Eu anomalies and are lower in REE (5.6–30 ppm). We therefore conclude that REE concentrations and patterns of tourmaline from the different tourmaline rocks studied are controlled by the host rock and not by the hydrothermal fluid causing boron metasomatism. From the similarity of the REE pattern of separated tourmaline with the host rock, we further conclude that incorporation of REEs in tourmaline is not intrinsically controlled (i.e. by crystal chemical factors). Tourmaline does not preferentially fractionate specific REEs or groups of REEs during crystallisation from evolved boron- and fluid-rich granitic melts or during alteration of clastic metasediments by boron-rich magmatic-hydrothermal fluids.Editorial responsibility: J. Hoefs     

A hybrid coordinate ocean model for shelf sea simulation

The general circulation in the North Sea and Skagerrak is simulated using the hybrid coordinate ocean model (HYCOM). Although HYCOM was originally developed for simulations of the open ocean, it has a design which should make it applicable also for coastal and shallow shelf seas. Thus, the objective of this study has been to examine the skills of the present version of HYCOM in a coastal shelf application, and to identify the areas where HYCOM needs to be further developed. To demonstrate the capability of the vertical coordinate in HYCOM, three experiments with different configurations of the vertical coordinate were carried out. In general, the results from these experiments compares quite well with in situ and satellite data, and the water masses and the general circulation in the North Sea and Skagerrak is reproduced in the simulations. Differences between the three experiments are small compared to other errors, which are related to a combined effect of model setup and properties of the vertical mixing scheme. Hence, it is difficult to quantify which vertical coordinate configuration works best for the coastal region. It is concluded that HYCOM can be used for simulations of coastal and shelf seas, and further suggestions for improving the model results are given. Since HYCOM also works well in open ocean and basin scale simulations, it may allow for a realistic modelling of the transition region between the open ocean and coastal shelf seas.     

Simulating the effects of land use changes on soil erosion using RUSLE model

The aim of this paper is to evaluate the impacts of land use change on soil loss. Soil loss was quantified using the revised universal soil loss equation model in Darabkola catchment. Land use maps of 1992, 1998 and 2012 were derived from Landsat Thematic Mapper data. The mean annual soil loss was therefore determined for these years. The results showed open-canopy forest area decreased by 36% between 1992 and 1998. Likewise, the decreasing trend of forest lands which are near to residential areas has continued from 1795 ha in 1998 to 1765 ha in 2012. Also the results indicate that the maximum annual soil loss ranged from 5.06, 6.19 and 15.23 ton h^?1 y^?1 in 1992, 1998 and 2012, respectively. Also, by assuming that all watershed conditions and land uses be constant in the future, then the area of close- and open-canopy forest and dry agricultural lands will be 23.23, 2.88 and 29.89 ha in 2040, respectively.     

The Nature of Decision Making in the Practice of Dwelling: A Practice Theoretical Approach to Understanding Maintenance and Retrofitting of Homes in the Context of Climate Change

In order to make existing private housing more energy efficient, various policies aim at influencing decisions made by homeowners regarding renovation and retrofitting in Scandinavia. Presenting two case studies from Denmark and Norway, we take one step back and observe the whole process of keeping a home habitable. Inspired by theories of Tim Ingold and Elizabeth Shove, we suggest calling this process “the practice of dwelling.” Rather than focusing on decisions and acts pertaining to retrofitting alone, we observe how maintenance and retrofitting are parts of an ongoing practice of dwelling. The cases demonstrate how decisions can be understood as embedded in the practice of dwelling, and how a readiness for decisions regarding retrofitting is created, or not, in this practice. We suggest shifting focus from the outcome of decisions, to attention toward the process that leads to readiness for making the decision in the first place.     

Inhomogeneities in the circumstellar envelope of the A0E herbig star AB aur

Simultaneous high-resolution spectroscopy in H andUBVRI polarimetric observations are proposed as an effective method for the search for circumstellar inhomogeneities in A0-type Herbig stars. The new results for AB Aur are presented as a successful example of the use of this method. The analysis of about 100 CCD H profiles (R = 30 000) and more than 150 polarimetric measurements obtained in January, 1994 allowed to discover a long-lived stream-like inhomogeneity in the circumstellar gaseous envelope.     

Anaerobic oxidation of methane (AOM) in marine sediments from the Skagerrak (Denmark): I. Geochemical and microbiological analyses

The organic rich sediments of the Skagerrak contain high quantities of shallow gas of mostly biogenic origin that is transported to the sediment surface by diffusion. The sulfate methane transition zone (SMTZ), where anaerobic oxidation of methane (AOM) and sulfate reduction occur, functions as a methane barrier for this upward diffusing methane.To investigate the regulation of AOM and sulfate reduction rates (SRR) and the controls on the efficiency of methane consumption, pore water concentrations, and microbial rates of AOM, sulfate reduction and methanogenesis were determined in three gravity cores collected along the slope of the Norwegian Trench in the Skagerrak. SRR occurred in two distinct peaks, at the sediment surface and the SMTZ, the latter often exceeding the peak AOM rates that occurred at the bottom of the SMTZ. Highest rates of both AOM and SRR were observed in a core from a pockmark, where advective methane transport occurred, generating high methane and sulfate fluxes. But even at this site with a shallow SMTZ, the entire flux of methane was oxidized below the sediment surface. AOM, SRR and methanogenesis seem to be closely associated and strongly regulated by sulfate concentrations, which were, in turn, regulated by the methane flux. Rate measurements of SRR, AOM and methanogenesis revealed a tight coupling of these processes. Bicarbonate-based methanogenesis occurred at moderate sulfate concentrations (>5 mM) above the AOM zone but seemed to be inhibited in the depth where AOM occurred. The unbalanced stoichiometry of AOM and SRR in the SMTZ was more pronounced in rate measurements than in methane and sulfate fluxes, and seemed more likely be related to enhanced SRR in this zone than an underestimation of methane fluxes.     

Bioactive compounds of sea cucumbers and their therapeutic effects

Sea cucumbers belong to the Class Holothuroidea of marine invertebrates. They are commercially valuable and prized as a food and folk medicine in Asia. Nutritionally, sea cucumbers have an impressive profile of valuable nutrients such as vitamins, minerals and amino acids. A number of unique biological and pharmacological activities/properties, including anticancer, anticoagulant/antithrombotic, antimicrobial, antioxidant, antihyperlipidemic, antihyperglycemic, anti-inflammatory, antihypertension and radioprotective, have been ascribed to various compounds isolated from sea cucumbers. The therapeutic properties and medicinal benefits of sea cucumbers can be linked to the presence of a wide array of bioactives, especially triterpene glycosides, acid mucopolysaccharide, sphingoid bases, glycolipids, fucosylated chondroitin sulfate, polysaccharides, phospholipids, cerebrosides, phosphatidylcholines, and other extracts and hydrolysates. This review highlights the valuable bioactive components as well as the multiple therapeutic properties of sea cucumbers with a view to exploring their potential uses as functional foods and a natural source of new multifunctional drugs.     

Cyclic shakedown of piles subjected to two‐dimensional lateral loading

Pile foundations are frequently subjected to cyclic lateral loads. Wave and wind loads on offshore structures will be applied in different directions and times during the design life of a structure. Therefore, the magnitude and direction of these loads in conjunction with the dead loads should be considered. This paper investigates a loading scenario where a monotonic lateral load is applied to a pile, followed by two‐way cycling in a direction perpendicular to the initial loading. This configuration is indicative of the complexity of loading that may be considered and is referred to in the paper as ‘T‐shaped’ loading. The energy‐based numerical model employed considers two‐dimensional lateral loading in an elasto‐plastic soil, with coupled behaviour between the two perpendicular directions by local yield surfaces along the length of the pile. The behaviour of the soil–pile system subjected to different loading combinations has been divided into four categories of shakedown previously proposed for cyclic loading of structures and soils. A design chart has been created to illustrate the type of pile behaviour for a given two‐dimensional loading scenario. Copyright © 2009 John Wiley & Sons, Ltd.     

Lost and found

Consulting type specimens is a necessary element of taxonomic research in palaeontology. Every taxonomist from time to time has to examine the types to make sure that the identifications are correct. This can be a difficult proposition when the fossils in question were collected in the early nineteenth century. But just because a historical fossil collection is said to be 'lost', doesn't mean it cannot be found.