Factors influencing methane-derived authigenic carbonate formation at cold seep from southwestern Dongsha area in the northern South China Sea

This paper carried out mineral and geochemical studies on a profile through a diagenetic methane-derived authigenic carbonate sample that was collected from southwestern Dongsha area of the northern South China Sea. Five samples locating in the cross-sectional middle mainly consist of dolomite and quartz, and two samples close to the surface have a small amount of Mg-calcite. The δ¹³C values of the samples vary between ?30.59 and ?0.30 % VPDB, with δ¹⁸O values ranging from 3.07 to 3.59 % VPDB, δ^44/40Ca values ranging from 1.35 to 1.47 % SRM915a, indicating a contribution of methane to the carbon pool where the precipitation of authigenic carbonates occurred. Based on the isotope values alone, it can not be distinguished if the carbon source is thermogenic gas or a mixture of biogenic methane and marine dissolved inorganic carbon. The δ¹⁸O values are in general consistent with dolomite precipitation from a fluid similar to present seawater. The observed small variation might be related to the oxygen isotope composition of seep fluid. The relative small range in calcium isotope values suggests that relatively constant growth conditions and precipitation from seawater. The central part of the carbonate nodule formed under the strong influence of methane seepage, and the external part is less influenced by methane, either due to reduced methane flux to the surface or caused by erosional exhumation of the carbonate nodule from greater depth to the sediment surface.     

Investigating the impact of initial soil moisture conditions on total infiltration by using an adapted double-ring infiltrometer

ABSTRACT

This study presents an adaptation of the double-ring infiltrometer (DRI) device, which allows several infiltration experiments to be conducted at the same location. Hence, it becomes possible to use the DRI method to investigate infiltration behaviour under different initial soil moisture conditions. The main feature is the splitting of the inner ring into two parts. While the lower part remains in the soil throughout the investigation period, the upper part is attached to the lower one just before the infiltration experiment. This method was applied to eight test sites in an Alpine catchment, covering different land-use/cover types. The results demonstrated the applicability of the adapted system and showed correlations between total water infiltration and initial soil moisture conditions on pastures, independent of the underlying soil type. In contrast, no correlation was found at forest sites or wetlands. Thus, the study emphasizes the importance of paying special attention to the impact of initial soil moisture conditions on the infiltration—and consequently the runoff behaviour—at managed areas. Given the differences in the total infiltrated water of between 30 and 1306 mm, consideration of the interplay between initial soil moisture conditions, land-use/cover type, and soil properties in rainfall–runoff models is a prerequisite to predict runoff production accurately.

EDITOR Z.W. Kundzewicz; ASSOCIATE EDITOR not assigned     

Spatial distribution of surface conditions and runoff generation in small arid watersheds, Zin Valley Badlands, Israel

High rill density may be regarded as indicative of frequent and integrated runoff along a drainage network. However, field observations of soil development and rill geometry in small, first-order catchments (0.1 to 1 ha) of the Zin Valley Badlands, northern Negev, Israel, suggest a pattern of partial area contribution and frequent flow discontinuities along hillslopes and channels. Changing soil properties, associated with an increase of slope angle and slope length, appear to be responsible for high infiltration on the slopes, leading to nonuniform runoff generation within small drainage basins. Runoff observation, sprinkling tests, and soil analysis along ridges and sideslopes were carried out to test this hypothesis. The results confirmed that infiltration capacity on the sideslopes is significantly higher than on the ridges. Under current rainfall conditions, only extreme rainfall intensities are sufficient to generate runoff along entire slopes. The discontinuous nature of most runoff events causes erosion on ridges and deposition on slopes, which enhances soil development on the valley sideslopes, creating a positive feedback on infiltration rate and depth. This demonstrates that the links between within-storm rainfall conditions and spatial distribution of soil characteristics have to be incorporated into our understanding of landscape development in badlands.     

Along-strike shear-sense reversal in the Vals-Scaradra Shear Zone at the front of the Adula Nappe (Central Alps,Switzerland)

The Adula Nappe in the Central Alps comprises pre-Mesozoic basement and minor Mesozoic sediments, overprinted by Paleogene eclogite-facies metamorphism. Peak pressures increase southward from ca. 1.2 GPa to values over 3 GPa, which is interpreted to reflect exhumation from a south-dipping subduction zone. The over- and underlying nappes experienced much lower Alpine pressures. To the north, the Adula Nappe ends in a lobe surrounded by Mesozoic metasediments. The external shape of the lobe is simple but the internal structure highly complicated. The frontal boundary of the nappe represents a discontinuity in metamorphic peak temperatures, between higher T in the Adula Nappe and lower T outside. A shear zone with steeply dipping foliation and shallowly-plunging, WSW-ENE oriented, i.e. orogen-parallel stretching lineation overprinted the northernmost part of the Adula Nappe and the adjacent Mesozoic metasediments (Vals-Scaradra Shear Zone). It formed during the local Leis deformation phase. The shear sense in the Vals-Scaradra Shear Zone changes along strike; from sinistral in the W to dextral in the E. Quartz textures also vary along strike. In the W, they indicate sinistral shearing with a component of coaxial (flattening) strain. A texture from the middle part of the shear zone is symmetric and indicates coaxial flattening. Textures from the eastern part show strong, single c-axis maxima indicating dextral shearing. These relations reflect complex flow within the Adula Nappe during a late stage of its exhumation. The structures and reconstructed flow field indicate that the Adula basement protruded upward and northward into the surrounding metasediments, spread laterally, and expelled the metasediments in front towards west and east.     

Late Cretaceous eclogite in the Eastern Rhodopes (Bulgaria): evidence for subduction under the Sredna Gora magmatic arc

International Journal of Earth Sciences - The Rhodopes in Bulgaria and Greece represent a nappe stack of high-grade units with polymetamorphic history. Constraining the time of metamorphism in...     

Die Blei-Zinkerzlagerstätten des Pflerschtals

The stratabound lead zinc ore deposits of the Pflersch Valley (Eastern Alps) are intercalated in pre-Triassic folded and metamorphosed pelitic sediments of the ötztal-Stubaier Masse. The ores (sphalerite, galena, pyrrhotite etc.) are stratigraphically controled by graphitic shists and tuffitic layers. The thickness of the ore bodies varies between some centimeters to some meters. As part of the regional setting these orebearing strata were metamorphosed during several metamorphic episodes together with these metasediments. Field observations, supplimented by microscopic studies, and the calculation of p-T-conditions indicate that now partly mobilized ores probably had their origin during the last pre-Triassic metamorphic events. These ores probably came in part as sulfide melts. There seems also a possibility of an additional alpine ore mobilization process. On the basis of age determinations and petrographic studies carried out in the ötztal-Stubaier Masse by other authors it is possible to say that the ore-bearing former sediments belong to Silurian or even pre-Silurian age (>410my).     

Erodibility of soil and organic matter: independence of organic matter resistance to interrill erosion

The enrichment of organic matter in interrill sediment is well documented; however, the respective roles of soil organic matter (SOM) and interrill erosion processes for the enrichment are unclear. In this study, organic matter content of sediment generated on two silts with almost identical textures, but different organic matter contents and aggregations, was tested. Artificial rainfall was applied to the soils in wet, dry and crusted initial conditions to determine the effects of soil moisture and rainfall and drying history on organic matter enrichment in interrill sediment. While erosional response of the soils varied significantly, organic matter enrichment of sediment was not sensitive to initial soil conditions. However, enrichment was higher on the silt with a lower organic matter content and lower interrill erodibility. The results show that enrichment of organic matter in interrill sediment is not directly related to either SOM content or soil interrill erodibility, but is dominated by interrill erosion processes. As a consequence of the complex interaction between soil, organic matter and interrill erosion processes, erodibility of organic matter should be treated as a separate variable in erosion models. Further research on aggregate breakdown, in particular the content and fate of the organic matter in the soil fragments, is required. Copyright © 2007 John Wiley & Sons, Ltd.     

Distribution and origin of lead in stream sediments from small agricultural catchments draining Miocene molassic deposits (SW France)

Total Pb concentrations and isotopic composition were determined in stream-bed sediments and bedrock from 29 small agricultural or forested catchments in the Gascogne area (SW France). The contribution of Pb from various natural and anthropogenic sources was investigated in this rural area which is very weakly impacted by industrial or urban emissions. Environmental parameters in catchments (importance of forest cover, organic matter and oxide content in sediments) were considered. A combination of geochemical (enrichment calculation, sequential extraction) and isotopic investigations was performed to constrain the origin of Pb and the distribution of anthropogenic Pb in sediments. Most of the sediments have low total Pb content compared to other agricultural regions more impacted by industrial or urban emissions. The results indicated a moderate but significant Pb enrichment, particularly for catchments draining forested areas. This enrichment was positively related to organic C content in sediment and catchment forest cover, whereas in entirely cultivated catchments it was related to Fe-oxide content.     

Dissolved silica in the Garonne River waters: changes in the weathering dynamics

 The major ion chemistry of the Garonne River is indicative of seasonal variations in the weathering dynamics of the drainage basin. Using the geochemical model MEGA for calculation of the contribution of atmospheric CO₂ to the total bicarbonate fluxes exported by the Garonne River allows estimations of the concentrations of the major dissolved elements that originate from silicate- and carbonate-rock weathering. The molecular ratio SiO₂/Al₂O₃ was calculated for the 1989–1992 period to identify the main type of weathering in the Garonne River, and montmorillonite was shown to be the major mineral occurring in the weathering products. The seasonal variations of the SiO₂/Al₂O₃ ratio also showed that removal of silica was accelerated during humid periods. Revision received: 14 May 1999 · Accepted: 12 January 2000