Environmental isotopes (18O, 2H, and 87Sr/86Sr) as a tool in groundwater investigations in the Keta Basin, Ghana

Analyses of environmental isotopes (¹⁸O, ²H, and ⁸⁷Sr/⁸⁶Sr) are applied to groundwater studies with emphasis on saline groundwater in aquifers in the Keta Basin, Ghana. The ⁸⁷Sr/⁸⁶Sr ratios of groundwater and surface water of the Keta Basin primarily reflect the geology and the mineralogical composition of the formations in the catchments and recharge areas. The isotopic compositions of ¹⁸O and ²H of deep groundwater have small variations and plot close to the global meteoric water line. Shallow groundwater and surface water have considerably larger variations in isotopic compositions, which reflect evaporation and preservation of seasonal fluctuations. A significant excess of chloride in shallow groundwater in comparison to the calculated evaporation loss is the result of a combination of evaporation and marine sources. Groundwaters from deep wells and dug wells in near-coastal aquifers are characterized by relatively high chloride contents, and the significance of marine influence is evidenced by well-defined mixing lines for strontium isotopes, and hydrogen and oxygen stable isotopes, with isotopic compositions of seawater as one end member. The results derived from environmental isotopes in this study demonstrate that a multi-isotope approach is a useful tool to identify the origin and sources of saline groundwater. Electronic Publication     

A cummingtonite-porphyritic dacite with amphibole-rich xenoliths from the tertiary central volcano at Króksfjördur,NW Iceland

An instrusive dacite and a salic pumice, emplaced late in the evolution of the Miocene (c. 10 m.y.) Króksfjördur volcano, NW Iceland, contain a varied assemblage of xenolithic metaigneous rocks. Mineral and rock chemistry shows that the dacite is very similar to calc-alkaline salic rocks from the SW Pacific. It contains phenocrystic plagioclase, quartz, pyroxene, cummingtonite, hornblende, biotite, two oxides, apatite and zircon in a rhyolitic glass. The rock equilibrated at 700 to 750°C. P ～ 1.6 Kbar and P_H2O ～ 1 Kbar. The xenoliths are layered gabbros, granophyres and various fine-grained hornfelses and show that the dacite magma was residing within a gabbro intrusion capped by granophyre prior to the eruption. The hornfelses are amphibole-plagioclase, amphibole-pyroxene-plagioclase and pyroxene-plagioclase rocks formed during high-temperature metamorphism of basic dykes cutting the gabbro intrusion. The gabbros and hornfelses mostly record higher metamorphic temperatures (850–940°C) than the dacite, and indicate that they were equilibrated during the ascent of a magma body into a hydrous high-level region within the volcano. During a following thermal decline, the hydrated magma cooled to form the first cummingtonite-bearing low-T magma to be recorded from the ocean ridge systems.     

An “ESA-Affordable” Laue-lens

With ESA’s INTEGRAL mission gamma-ray astronomy has advanced to the point where major scientific advances must be expected from detailed studies of the many new point sources. The interest in developing focusing telescopes operating in the soft gamma-ray regime up to 1 MeV is therefore mounting rapidly. Telescopes based on Laue diffraction of gamma-rays from crystals appear as one promising route, although the practical difficulties of realizing a large scale Laue lens are certainly not small. In this paper I have attempted to develop an optimized lens design considering the size and mass constraints of a specific medium size launch vehicle. The introduction of the lens mass as a primary design driver has some surprising effects for the choice of material for the crystals and new tradeoff considerations are introduced.     

Evaluating the salinity distribution of a shallow coastal aquifer by vertical multielectrode profiling (Denmark)

A monitoring system, including five groups of piezometers and five vertical multielectrode profiling probes (VMEP), has been installed in an aquifer beneath a coastal dune in Denmark. In order to assess the salinity distribution within the aquifer, geoelectrical data were gathered in March, June and September 2008, by measuring a dipole-dipole and gradient array using multielectrode profiling. Interpretation of the processed resistivity data was performed by regularized inversion using a one-dimensional, horizontally layered model of formation resistivity. The standard deviation on estimated layer log-resistivity was 0.01–0.03. By estimating two parameters of a power function, observed fluid conductivities derived from samples of porewater were related to corresponding estimated formation resistivities. The conductivity profiles correlate with a winter situation in March with high sea level, active recharge and significant wave activity, causing increased hydraulic heads, a thicker freshwater lens and salt water overlying freshwater close to the sea. In June, the thickness of the freshwater lens is reduced due to less recharge and prevailing offshore winds, imposing density-stable conditions and a sharper transition between fresh and brackish water. During the autumn, aquifer recharge is enhanced and hydraulic heads increase, resulting in a thicker freshwater lens.     

Sediment supply from landslide-dominated catchments: implications for basin-margin fans

The sediment flux from a mountainous catchment can be expressed as a function of a landslide rate constant κ which accounts for the vigour of hillslope erosion. Since the incising drainage network flushes all or a portion of the products of hillslope erosion to a range front where fan deposition takes place, a conservation of solid sediment volume allows the fan area and progradation distance to be calculated. These parameters are related primarily to the discharge of sediment from the catchment and to local tectonic subsidence.
A survey of modern alluvial fans in a wide range of climatic and tectonic settings shows that the effects of climate and bedrock lithology cannot be discriminated in the scatter of data of catchment area vs. fan area. However, by focusing on over 100 fans in the arid and semiarid zone of SW USA, the impact of tectonic subsidence rate is unambiguous. Although further quantitative data on local tectonic subsidence rates are urgently required, our preliminary analysis suggests considerable potential for reconstructing palaeocatchments where basin tectonic subsidence rates can be estimated. The progradation distances of fans from the northern and southern margins of the Middle Devonian Hornelen Basin of Norway, and the western and north-eastern margins of the Mio-Pliocene Ridge Basin, California, allow catchment sizes and denudation rates to be approximated. Although unique solution sets are not possible, an iteration of parameter values allows plausible parameter combinations to be calculated which shed light on the tectonic and sedimentary history of the proximal basin and upland source regions. Model results suggest significant asymmetry in basin subsidence rates, catchment slopes and transport mechanics between the two margins.     

Geochemical Responses to a Major Transgression in Giant African Lakes

Bulk organic matter (OM) in sediments that accumulated in Lakes Victoria, Albert and Tanganyika during the major transgression that transformed these basins from a desiccated or lowstand condition at the time of the Last Glacial Maximum to highstand with overflow in the terminal Pleistocene and early Holocene, show some striking compositional trends. Sediment OM content (TOC) and Rock-Eval Hydrogen Index (HI) both rise markedly, reflecting increasing primary productivity during the transgression and enhanced conditions for the preservation of labile OM, In Lake Victoria rising sedimentary sulphur content tracks the change in HI. Over the same time interval in all three lakes, δ¹³C_OM shows a falling trend of 5–8‰ . Nitrogen isotopic and C/N trends are, in contrast, more variable. Relatively high δ¹⁵N values at an early stage in the transgression may reflect isotopic effects associated with ammonia loss from an alkaline waterbody, while high δ¹⁵N later in the transgression was probably due to periods when stratification-related denitrification had a particularly strong impact upon the lakes' N cycle. The observed changes are attributed to the influence of the landscape drowned during the transgression upon the nutrient budget of the lake, a rise in river-supplied nutrients as the climate became wetter, and an increasing tendency to stable chemical stratification as the water column deepened. In the case of δ¹³C, additional contributory factors were changes in the amount and isotopic composition of river-supplied dissolved inorganic carbon (DIC) as runoff and soil–moisture turnover rates increased, and the replacement of a C4-grassland dominated flora by mixed woodland-grassland and forest with a significant presence of C3 plants. Distinct geochemical changes are also apparent in Lakes Victoria and Albert sediments at the end of the transgression which are consistent with a reduction in nutrient loading. In the case of N this resulted in biological N fixation becoming a major part of the lakes' N cycle, Some of the observed geochemical variations may be generally applicable as proxy indicators of major transgressions in large lakes. IDEAL Contribution No. 152.     

A lateral model parameter correlation procedure for one-dimensional inverse modelling

We present a new, fast and versatile method, the lateral parameter correlation method, of invoking lateral smoothness in model sections of one-dimensional (1D) models. Modern, continuous electrical and electromagnetic methods are capable of recording very large data sets and except for a few cases, standard inversion methodology still relies on 1D models. In environments where the lateral rate of change of resistivity is small, 1D inversion can be justified but model sections of concatenated 1D models do not necessarily display the expected lateral smoothness.
The lateral parameter correlation method has three steps. First, all sounding data are inverted individually. Next, a laterally smooth version of each model parameter, one at a time, is found by solving a simple constrained inversion problem. Identity is postulated between the uncorrelated and correlated parameters and the equations are solved including a model covariance matrix. As a last step, all sounding data are inverted again to produce models that better fit the data, now subject to constraints by including the correlated parameter values as a priori values. Because the method separates the inversion from the correlation it is much faster than methods where the inversion and correlation are solved simultaneously, typically with a factor of 200–500.
Theoretical examples show that the method produces laterally smooth model sections where the main influence comes from the well-determined parameters in such a way that problems with equivalence and poor resolution are alleviated. A field example is presented, demonstrating the improved resolution obtained with the lateral parameter correlation method. The method is very flexible and is capable of coupling models from inversion of different data types and information from boreholes.     

State regulation of agro-industries in developing countries. Governance systems in the vegetable oil industry of Malaysia and Zimbabwe

Some observers of agro-industrial development in the Third World recognize the nation state as an important locus for mediation of conflicts between different social forces but fail to analyze the regulatory mechanisms and their effect on the dynamics of particular agro-industries. This paper proposes an analytical model to study agro-industrial regulation in a national framework. The purpose is to investigate the dynamics between changing forms of state regulation and particular industry governance system in the vegetable oil industry in Malaysia and Zimbabwe. State regulation and industry governance systems differ in a number of ways between the two countries. However, in each country there is a correspondence between the dominant form of state regulation and the industrial governance system. The study confronts some of the basic assumptions within the food regime approach and stress the need to incorporate the properties of the crops in the analysis of (agro-)industry governance systems.