The 3:2 spin-orbit resonant motion of Mercury

Our purpose is to build a model of rotation for a rigid Mercury, involving the planetary perturbations and the non-spherical shape of the planet. The approach is purely analytical, based on Hamiltonian formalism; we start with a first-order basic averaged resonant potential (including J ₂ and C ₂₂, and the first powers of the eccentricity and the inclination of Mercury). With this kernel model, we identify the present equilibrium of Mercury; we introduce local canonical variables, describing the motion around this 3:2 resonance. We perform a canonical untangling transformation, to generate three sets of action-angle variables, and identify the three basic frequencies associated to this motion. We show how to reintroduce the short-periodic terms, lost in the averaging process, thanks to the Lie generator; we also comment about the damping effects and the planetary perturbations. At any point of the development, we use the model SONYR to compare and check our calculations.     

Effects of water and fines contents on the resilient modulus of the interlayer soil of railway substructure

This paper deals with the resilient behavior of the interlayer soil which is created mainly by the interpenetration of ballast and subgrade soils. The interlayer soil studied was taken from a site in the southeast of France. Large-scale cyclic triaxial tests were carried out at three water contents (w = 4, 6 and 12 %) and three fines contents corresponding to 5, 10 % subgrade added to the natural interlayer soil and 10 % fine particles (<80 μm) removed from the natural interlayer soil. Soil specimens underwent various deviator stresses, and for each deviator stress, a large number of cycles was applied. The effects of deviator stress, number of cycles, water content and fines content on the resilient modulus (M _r) were analyzed. It appears that the effects of water content and fines content must be analyzed together because the two effects are closely linked. Under unsaturated conditions, the soil containing high fines content has higher resilient modulus due to the contribution of suction. When the soil approaches the saturated state, it loses its mechanical enhancement with a sharp decrease in resilient modulus.     

Spectral Characterization of Colored Dissolved Organic Matter for Productive Inland Waters and Its Source Analysis

This study examined the spatiotemporal dynamics of colored dissolved organic matter(CDOM) and spectral slope(S), and further to analyze its sources in three productive water supplies(Eagle Creek, Geist and Morse reservoirs) from Indiana, USA. The results showed that he absorption coefficient aCDOM(440) ranged from 0.37 m–1 to 3.93 m–1 with an average of 1.89 ± 0.76 m–1(±SD) for the aggregated dataset, and S varied from 0.0048 nm–1 to 0.0239 nm–1 with an average of 0.0108 ± 0.0040 nm–1. A significant relationship between S and aCDOM(440) can be fitted with a power equation(S = 0.013 × aCDOM(440)–0.42, R2 = 0.612), excluding data from Geist Reservoir during high flow(12 April 2010) and the Morse Reservoir on 25 June 2010 due to a T-storm achieves even higher determination coefficient(R2 = 0.842). Correlation analysis indicated that aCDOM(440) has strong association with inorganic suspended matter(ISM) concentration(0.231 < R2 < 0.786) for each of the field surveys, and this trend followed the aggregated datasets(R2 = 0.447, p < 0.001). In contrast, chlorophyll-a was only correlated with aCDOM(440) in summer and autumn(0.081 < R2 < 0.763), indicating that CDOM is mainly from terrigenous sources in early spring and that phytoplankton contributed during the algal blooming season. The S value was used to characterize CDOM origin. The results indicate that the CDOM source is mainly controlled by hydrological variations, while phytoplankton originated organic matter also closely linked with CDOM dynamics in three productive reservoirs.     

SARAL/AltiKa Global Statistical Assessment and Cross-Calibration with Jason-2

The CNES/ISRO mission SARAL/AltiKa was successfully launched on 25 February 2013. It reached its nominal orbit on 13 March 2013. AltiKa is the first altimeter using the Ka-band frequency. This article presents the results of the calibration and validation activities perfromed on the first year of the SARAL/AltiKa mission. The main objective of the article is to assess the SARAL/AltiKa data quality and to estimate the altimeter system performance using GDR products. To achieve this goal, we present mono-mission metrics and compare them with Jason-2 over the same period. Even if these missions do not have the same ground track, precise comparisons are still possible. They allow assessing parameter discrepancies and SSH consistency between both missions in order to detect geographically correlated biases, jumps or drifts. These results show that SARAL/AltiKa data quality is excellent: ocean data coverage is greater than 99.5%, standard deviation at cross-overs is 5.4 cm. The mission therefore fulfills the requirements of high precision altimetry and can be used (in conjunction with Jason-2) to monitor the global mean sea level, ensuring the continuity of the record over ERS/Envisat historical ground track. Possible improvements and open issues are also identified, foreseeing an even better mission performance.     

A computer simulation study of natural silicate melts. Part II: High pressure properties

The thermodynamic, structural and transport properties of natural silicate melts under pressure are investigated by molecular dynamics simulation with the help of a force field recently introduced by us [Guillot B. and Sator N. (2007) A computer simulation study of natural silicate melts. Part I: low pressure properties. Geochim. Cosmochim. Acta71, 1249-1265]. It is shown that the simulation reproduces accurately the bulk moduli of a large variety of silicate liquids as evaluated from ultrasonic studies. The equations of state (EOS) of the simulated melts are in good agreement with the density data on mid-ocean ridge basalt, komatiite, peridotite and fayalite as obtained either by sink/float experiments or by shock-wave compression. From the structural point of view it is shown that the population of ^[5]Al and ^[6]Al species increases rapidly upon initial compression (0-50 kbar) whereas for Si these highly coordinated species are found in a significant abundance (>5%) only above ∼50 kbar for ^[5]Si and ∼100-150 kbar for ^[6]Si. This increase of the coordination of network formers is not the only response of the melt structure to the densification: there is also a large redistribution of the T-O-T (T = Si, Al) bond angles with the pressure and noticeably upon initial compression in rhyolitic and basaltic liquids. Furthermore, a detailed analysis of the population of bridging oxygens (BO) and nonbridging oxygens (NBO) points out that the polymerization of the melt generally increases when the pressure increases, the magnitude of this polymerization enhancement being all the more important that the melt is depolymerized at low pressure. The role of triclusters (threefold coordinated oxygens to network former cations) is particularly emphasized in acidic and basaltic liquids. The pressure-induced redistribution of the oxygen atoms through the melt structure is also stressed. Finally, the simulation predicts a nonmonotonic behavior of the diffusivity of network former ions when the pressure increases, a feature with depends on the melt composition. This could have a counterpart in the electrical conductivity at sufficiently high temperature when the viscosity of the liquid is low.     

From land to sea: provenance,composition, and preservation of organic matter in a marine sediment record from the North-East Greenland shelf spanning the Younger Dryas–Holocene

The organic matter content of marine sediments is often used to infer past changes in ocean conditions. However, the organic carbon pool preserved in coastal sediments is a complex mixture derived from different sources and may not reflect in situ processes. In this study, we combine taxonomic identification of reworked palynomorphs with pyrolysis organic geochemistry and reflected-light organic petrographic microscopy to investigate the provenance, composition and preservation of organic matter in a marine sediment core retrieved from the NE Greenland shelf. Our study reveals continuous yet variable input of land-derived organic carbon to the marine environment throughout the late Younger Dryas–Holocene, with the highest input of inert carbon in the late Younger Dryas. Although the sediments contain some recent marine palynomorphs, there is no other evidence of fresh marine organic carbon. In contrast, our results indicate that these shelf sediments represent a significant sink of recycled organic carbon. The results of pyrolysis geochemistry revealed that ~90% of the total organic carbon in the sediments is inert. The organic petrography analyses revealed that >70–84% of the organic carbon in the sediment core is terrigenous. Reworked dinoflagellate cysts showed a continuous provenance of Cretaceous land-derived material, most likely from the nearby Clavering Island. Our study points to the importance of constraining the organic matter origin, composition and preservation in marine sediments to achieve more accurate palaeoenvironmental reconstructions based on organic proxies.