Presumed magnetic biosignatures observed in magnetite derived from abiotic reductive alteration of nanogoethite

The oriented chains of nanoscale Fe-oxide particles produced by magnetotactic bacteria are a striking example of biomineralization. Several distinguishing features of magnetite particles that comprise bacterial magnetosomes have been proposed to collectively constitute a biosignature of magnetotactic bacteria (Thomas-Keprta et al., 2001). These features include high crystallinity, chemical purity, a single-domain magnetic structure, well-defined crystal morphology, and arrangement of particles in chain structures. Here, we show that magnetite derived from the inorganic breakdown of nanocrystalline goethite exhibits magnetic properties and morphologies remarkably similar to those of biogenic magnetite from magnetosomes. During heating in reducing conditions, oriented nanogoethite aggregates undergo dehydroxylation and transform into stoichiometric magnetite. We demonstrate that highly crystalline single-domain magnetite with euhedral grain morphologies produced abiogenically from goethite meets several of the biogenicity criteria commonly used for the identi?cation of magnetofossils. Furthermore, the suboxic conditions necessary for magnetofossil preservation in sediments are conducive to the reductive alteration of nanogoethite, as well as the preservation of detrital magnetite originally formed from goethite. The findings of this study have potential implications for the identification of biogenic magnetite, particularly in older sediments where diagenesis commonly disrupts the chain structure of magnetosomes. Our results indicate that isolated magnetofossils cannot be positively distinguished from inorganic magnetite on the basis of their magnetic properties and morphology, and that intact chain structures remain the only reliable distinguishing feature of fossil magnetosomes.     

Back front of seismicity induced by non‐linear pore pressure diffusion

Borehole fluid injections are accompanied by microseismic activity not only during but also after termination of the fluid injection. Previously, this phenomenon has been analysed, assuming that the main triggering mechanism is governed by a linear pressure diffusion in a hydraulically isotropic medium. In this context the so‐called back front of seismicity has been introduced, which allows to characterize the hydraulic transport from the spatiotemporal distribution of post‐injection induced events. However, rocks are generally anisotropic, and in addition, fluid injections can strongly enhance permeability. In this case, permeability becomes a function of pressure. For such situations, we carry out a comprehensive study about the behaviour and parametrization of the back front. Based on a model of a factorized anisotropic pressure dependence of permeability, we present an approach to reconstruct the principal components of the diffusivity tensor. We apply this approach to real microseismic data and show that the back front characterizes the least hydraulic transport. To investigate the back front of non‐linear pore‐fluid pressure diffusion, we numerically consider a power‐law and an exponential‐dependent diffusivity. To account for a post‐injection enhanced hydraulic state of the rock, we introduce a model of a frozen (i.e., nearly unchanged after the stimulation) medium diffusivity and generate synthetic seismicity. We find that, for a weak non‐linearity and 3D exponential diffusion, the linear diffusion back front is still applicable. This finding is in agreement with microseismic data from Ogachi and Fenton Hill. However, for a strong non‐linear fluid–rock interaction such as hydraulic fracturing, the back front can significantly deviate from a time dependence of a linear diffusion back front. This is demonstrated for a data set from the Horn River Basin. Hence, the behaviour of the back front is a strong indicator of a non‐linear fluid–rock interaction.     

Long-term diagnostics of precipitation estimates and the development of radar hardware monitoring within a radar product data quality management system

Abstract

Quality is key to ensuring that the potential offered by weather radar networks is realized. To achieve optimum quality, a comprehensive radar data quality management system, designed to monitor the end-to-end radar data processing chain and evaluate product quality, is being developed at the UK Met Office. Three contrasting elements of this system are described: monitoring of key radar hardware performance indicators; generation of long-term integrations of radar products; and monitoring of radar reflectivity factor using synthesized observations from numerical weather prediction model fields. Examples of each component are presented and ways in which the different types of monitoring information have been used to both identify issues with the radar product data quality and help formulate solutions are given.

Editor Z.W. Kundzewicz; Guest editor R.J. Moore

Citation Harrison, D., Georgiou, S., Gaussiat, N., and Curtis, A., 2013. Long-term diagnostics of precipitation estimates and the development of radar hardware monitoring within a radar product data quality management system. Hydrological Sciences Journal, 59 (7), 1327–1342. http://dx.doi.org/10.1080/02626667.2013.841316     

Analytical description of physical librations of saturnian coorbital satellites Janus and Epimetheus

Janus and Epimetheus are famously known for their distinctive horseshoe-shaped orbits resulting from a 1:1 orbital resonance. Every 4 years these two satellites swap their orbits by a few tens of kilometers as a result of their close encounter. Recently Tiscareno et al. (Tiscareno, M.S., Thomas, P.C., Burns, J.A. [2009]. Icarus 204, 254-261) have proposed a model of rotation based on images from the Cassini orbiter. These authors inferred the amplitude of rotational librational motion in longitude at the orbital period by fitting a shape model to Cassini ISS images. By a quasi-periodic approximation of the orbital motion, we describe how the orbital swap impacts the rotation of the satellites. To that purpose, we have developed a formalism based on quasi-periodic series with long- and short-period librations. In this framework, the amplitude of the libration at the orbital period is found proportional to a term accounting for the orbital swap. We checked the analytical quasi-periodic development by performing a numerical simulation and find both results in good agreement. To complete this study, the results obtained for the short-period librations are studied with the help of an adiabatic-like approach.     

Effect of removing small (<150?μm) chironomids on inferring temperature in cold lakes

Sieving samples for chironomid analysis with a 150 μm mesh was shown to greatly reduce sample preparation time, and use of only larger specimens did not affect chironomid-inferred salinities in African lakes. Here, we tested if this method is suitable for temperature reconstruction in colder lakes at higher latitudes. Removal of specimens <150 μm in two training sets, one from Canada and one from Sweden, had little impact on the performance statistics of the calibration models. Chironomid abundance, however, decreased greatly because more than half of the head capsules in assemblages were <150 μm. This had major impacts on the temperature reconstructions. Inferences were on average 2°C warmer with the modified models (all specimens >150 μm) than those obtained with the full model (all specimens >100 μm). General patterns of temperature change were also altered. For Lake 7 on Southampton Island, Canada, a cooling trend was reconstructed with the full Canadian model while the modified Canadian model yielded a warming trend. When only specimens >150 μm were used, two to three times more wet sediment was needed to obtain a sufficient number of head capsules. These results indicate that, in cold lakes (mean July/August air temperature ≤11°C), large proportions of head capsules are <150 μm, and sieving the samples in a 150 μm mesh leads to altered temperature reconstructions.     

Modeling acid-gas generation from boiling chloride brines

Background  

This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate.     

SMOS reveals the signature of Indian Ocean Dipole events

The tropical Indian Ocean experiences an interannual mode of climatic variability, known as the Indian Ocean Dipole (IOD). The signature of this variability in ocean salinity is hypothesized based on modeling and assimilation studies, on account of scanty observations. Soil Moisture and Ocean Salinity (SMOS) satellite has been designed to take up the challenge of sea surface salinity remote sensing. We show that SMOS data can be used to infer the pattern of salinity variability linked with the IOD events. The core of maximum variability is located in the central tropical basin, south of the equator. This region is anomalously salty during the 2010 negative IOD event, and anomalously fresh during the 2011 positive IOD event. The peak-to-peak anomaly exceeds one salinity unit, between late 2010 and late 2011. In conjunction with other observational datasets, SMOS data allow us to draw the salt budget of the area. It turns out that the horizontal advection is the main driver of salinity anomalies. This finding is confirmed by the analysis of the outputs of a numerical model. This study shows that the advent of SMOS makes it feasible the quantitative assessment of the mechanisms of ocean surface salinity variability in the tropical basins, at interannual timescales.

     

Direct dating of thick‐ and thin‐skin thrusts in the Peruvian Subandean zone through apatite (U–Th)/He and fission track thermochronometry

Although the structure of the central Peruvian Subandean zone is well defined, the timing of thrust‐related exhumation and Cenozoic sedimentation remain poorly constrained. In this study, we report new apatite (U–Th)/He (AHe) and fission track (AFT) ages from thrust‐belt and foreland strata along three published balanced cross sections. AHe data from the northern, thick‐skinned domain (i.e. Shira Mountain, Otishi Cordillera and Ucayali Basin) show young AHe ages (ranging from 2.6 ± 0.2 to 13.1 ± 0.8 Ma) compared with AFT ages (ranging from 101 ± 5 to 133 ± 11 Ma). In the southern Camisea Basin, where deformation is mainly thin‐skinned, AHe and AFT ages have been both reset and show young cooling ages (3.7 ± 0.8 Ma and 8 ± 2 Ma respectively). Using low‐temperature thermochronology data and the latest fission track annealing and He diffusion codes, the thermal history of the study area has been reconstructed using inverse modelling. This history includes two steps of erosion: Early Cretaceous and late Neogene, but only Neogene sedimentation and exhumation varies in the different sectors of the study area. From a methodological point of view, large AHe data dispersion point to the need for refinement of AHe damage and annealing models. The influence of grain chemistry on damage annealing, multiple age components and the possibility of fission tracks as traps for He need further consideration. For the central Peruvian Subandes, AHe and AFT ages combined with balanced cross sections emphasize the dominant control of Paleozoic inheritance rather than climate on Cenozoic infilling and exhumation histories. Finally, our data provide the first field example of how thick‐skinned thrust‐related deformation and exhumation in the Subandes can be directly dated through AHe thermochronology.     

Structure and nuclear density distribution in the cheralite—CaTh(PO4)2: studies of its behaviour under high pressure (36?GPa)

The crystal structure of the cheralite—CaTh(PO₄)₂—has been revisited by neutron diffraction and its behaviour under high pressure investigated by X-ray diffraction up to 36?GPa. The neutron diffraction data at ambient pressure gave a more accurate determination of the Ca/Th cation position than previous XRD data, taking advantage that the neutron scattering lengths of calcium and thorium are of same order of magnitude. The nuclear density distribution was also determined using the maximum entropy method (MEM) confirming that the two cations are not located at the same position in the unit cell but are slightly displaced from one another along a specific direction in order to minimize the electrostatic repulsion with the surrounding phosphorus atoms. At high pressure, the compound did not show any phase transition or amorphization. From the evolution of the unit-cell volume as a function of the pressure, the zero-pressure bulk modulus B₀ and its pressure derivative B₀ ^′ have been determined by fitting the experimental compressibility curve to the Birch–Murnaghan equation of state. The results are B₀?=?140(2) GPa and B ₀ ^′ ?=?4.4(4) GPa.