Geochemical Evaluation of the Permian Ecca Shale in Eastern Cape Province,South Africa: Implications for Shale Gas Potential

Shale gas has been the exploration focus for future energy supply in South Africa in recent time. Specifically, the Permian black shales of the Prince Albert, Whitehill, Collingham, Ripon and Fort Brown Formations are considered to be most prospective rocks for shale gas exploration. In this study,outcrop and core samples from the Ecca Group were analyzed to assess their total organic carbon(TOC), organic matter type, thermal maturity and hydrocarbon generation potential. These rocks have TOC ranging from 0.11 to 7.35 wt%. The genetic potential values vary from 0.09 to 0.53 mg HC/g,suggesting poor hydrocarbon generative potential. Most of the samples have Hydrogen Index(HI) values of less than 50 mg HC/g TOC, thus suggesting Type-Ⅳ kerogen. Tmax values range from 318℃ to601℃, perhaps indicating immature to over-maturity of the samples. The vitrinite reflectance values range from 2.22% to 3.93%, indicating over-maturity of samples. Binary plots of HI against Oxygen Index(OI), and HI versus Tmax show that the shales are of Type II and mixed Type Ⅱ-Ⅲ kerogen.Based on the geochemical data, the potential source rocks are inferred as immature to over-matured and having present-day potential to produce gas.     

Structural uncertainty assessment in a discharge simulation model

Abstract

A major goal in hydrological modelling is to identify and quantify different sources of uncertainty in the modelling process. This paper analyses the structural uncertainty in a streamflow modelling system by investigating a set of models with increasing model structure complexity. The models are applied to two basins: Kielstau in Germany and XitaoXi in China. The results show that the model structure is an important factor affecting model performance. For the Kielstau basin, influences from drainage and wetland are critical for the local runoff generation, while for the XitaoXi basin accurate distributions of precipitation and evapotranspiration are two of the determining factors for the success of the river flow simulations. The derived model uncertainty bounds exhibit appropriate coverage of observations. Both case studies indicate that simulation uncertainty for the low-flow period contributes more to the overall uncertainty than that for the peak-flow period, although the main hydrological features in these two basins differ greatly.

Citation Zhang, X. Y., Hörmann, G., Gao, J. F. & Fohrer, N. (2011) Structural uncertainty assessment in a discharge simulation model. Hydrol. Sci. J. 56(5), 854–869.     

A simple method to help determine landslide susceptibility from spaceborne InSAR data: the Montescaglioso case study

On December 3, 2013, a large complex landslide was triggered SW of the town of Montescaglioso (Southern Italy), causing the destruction of roads, commercial buildings and private dwellings, as well as several direct and indirect economic losses. A set of interferometric ground measurements acquired by the Cosmo-SkyMed satellite constellation and processed by means of the SqueeSAR algorithm was used to study the pre-event slope displacements in the entire Montescaglioso municipal area. Data span from January 30, 2012, to December 2, 2013, and show average line-of-sight velocities of 1–10 mm/year in the slope sector ultimately affected by the collapse. In retrospect, a time series analysis of the radar targets was performed in order to identify and characterize all the slope instabilities in proximity of the town. This was based on the setup of characteristic thresholds of displacement. The procedure permitted to locate several areas which recurrently exceeded these previously established thresholds, in consistency with the amount of precipitation. In particular, the major source of potential hazard in the area was indeed found where the December 3, 2013, landslide eventually occurred. The results of this quick data processing technique were validated through comparison with two independently developed landslide maps. This simple method, which is not supposed to diminish the importance of geomorphologic field surveys, could improve both the accuracy and the update rate of landslide susceptibility maps. Not relying on arbitrary or empirically derived approaches, it has the advantage of computing statistically based thresholds specific for each time series. By indicating the slope sectors in higher need of deeper in situ investigation, more support could be provided to administrative bodies for the processes of risk assessment and management.     

Nephelines from the Somma-Vesuvius volcanic complex (Southern Italy): crystal-chemical,structural and genetic investigations

Sixteen nephelines from different geological occurrences were sampled at the type-locality, the Somma-Vesuvius volcanic complex (southern Italy), and investigated for their chemistry and crystal structure obtained by both single-crystal and powder X-ray diffraction. Nepheline-bearing samples are metamorphic or from magmatic ejecta and pumice deposits. The lower K contents characterize the pumice- and some metamorphic-derived nephelines, whereas the higher ones are found in some samples from magmatic nodules. The amount of the anorthite molecule, quite low on average, can be more variable in the metamorphic nephelines. The crystal-structure investigations on Somma-Vesuvius samples compare well with previous studies of natural nephelines. All 16 nepheline samples adopt space group P6₃. The observed lattice parameters vary between 9.9768–9.9946 Å (for a) and 8.3614–8.3777 Å (for c), respectively. Furthermore, chemical analysis revealed that all specimens exhibit an excess of Si relative the ideal Si:Al ratio of 1:1. The analysis of the T-O distances in our samples clearly indicates a distinct ordering process of aluminium and silicon on the tetrahedral sites which is an agreement with Loewenstein’s rule. A linear correlation between the distance of symmetry equivalent split atoms O(1)-O(1)’ and the T(1)-O(1)-T(2) tilt angle was observed. The average <B-O> (B = Na) distances of all crystals are very similar which is consistent with the outcome of the site population refinement indicating full occupancy with sodium. Oriented precession-type sections of reciprocal space indicated the presence of at least the most intense family of satellite peaks, demonstrating that this group of satellite reflections can occur not only in nephelines from pegmatites and ijolites but also in rocks from completely different petrological settings.     

Terrestrial laser scanner and geomechanical surveys for the rapid evaluation of rock fall susceptibility scenarios

The primary objective of this paper is to present a semiautomatic procedure that, integrated with traditional methods, can be useful for a rapid definition of rock fall susceptibility scenarios with the purpose of civil protection. Due to its morphology (steep slopes and narrow valleys), regional seismicity, and rock mass characteristics, the Nera Valley (Valnerina, Umbria Region, Italy) is characterized by high rock fall risk. With the aim of covering a wide range of features and investigating the main advantages and drawbacks of the proposed approach, data collection (terrestrial laser scanning (TLS) and geomechanical surveys) was carried out at three different slopes. Detailed three-dimensional (3D) models were created to reconstruct the shape and volume of the most unstable blocks, to define the position of the main rock fall source areas, and to precisely distinguish the outcropping materials and the position of the elements at risk for reliable runout analyses. The proposed approach can be useful in supporting proper maintenance and land management programs both in ordinary and in emergency circumstances.     

Predictive modeling for preventive Archaeology: overview and case study

The use of GIS and Spatial Analysis for predictive models is an important topic in preventive archaeology. Both of these tools play an important role in the Support Decision System (SDS) for archaeological research and for providing information useful to reduce archaeological risk. Over the years, a number of predictive models in the GIS environment have been developed and proposed. The existing models substantially differ from each other in methodological approaches and parameters used for performing the analysis. Until now, only few works consider spatial autocorrelation, which can provide more effective results. This paper provides a brief review of the existing predictive models, and then proposes a new methodological approach, applied to the neolithic sites in the Apulian Tavoliere (Southern Italy), that combines traditional techniques with methods that allow us to include spatial autocorrelation analysis to take into account the spatial relationships among the diverse sites.     

GNSS software receiver for the MAGIA (Missione Altimetrica Geofisica GeochImica lunAre) mission

In recent years a number of missions have been conceived to acquire and track signals from GPS satellites at altitudes higher than the GPS constellation itself. The main purpose of SDR is to reduce the number of hardware components, projected for specific unmodifiable uses, and utilize general purpose units: on board CPU, DSP or FPGA. In this paper he study and design of a GNSS Software Receiver for space application, applied to a Lunar Mission, is presented with particular attention on Space Segment device and on Ground Facilities.     

Controls on Sr/Ca and Mg/Ca in scleractinian corals: The effects of Ca-ATPase and transcellular Ca channels on skeletal chemistry

The Sr/Ca of aragonitic coral skeletons is a commonly used palaeothermometer. However skeletal Sr/Ca is typically dominated by weekly-monthly oscillations which do not reflect temperature or seawater composition and the origins of which are currently unknown. To test the impact of transcellular Ca²⁺ transport processes on skeletal Sr/Ca, colonies of the branching coral, Pocillopora damicornis, were cultured in the presence of inhibitors of Ca-ATPase (ruthenium red) and Ca channels (verapamil hydrochloride). The photosynthesis, respiration and calcification rates of the colonies were monitored throughout the experiment. The skeleton deposited in the presence of the inhibitors was identified (by ⁴²Ca spike) and analysed for Sr/Ca and Mg/Ca by secondary ion mass spectrometry. The Sr/Ca of the aragonite deposited in the presence of either of the inhibitors was not significantly different from that of the solvent (dimethyl sulfoxide) control, although the coral calcification rate was reduced by up to 66% and 73% in the ruthenium red and verapamil treatments, respectively. The typical precision (95% confidence limits) of mean Sr/Ca determinations within any treatment was <±1% and differences in skeletal Sr/Ca between treatments were correspondingly small. Either Ca-ATPase and Ca channels transport Sr²⁺ and Ca²⁺ in virtually the same ratio in which they are present in seawater or transcellular processes contribute little Ca²⁺ to the skeleton and most Ca is derived from seawater transported directly to the calcification site. Variations in the activities of Ca-ATPase and Ca-channels are not responsible for the weekly-monthly Sr/Ca oscillations observed in skeletal chronologies, assuming that the specificities of Ca transcellular transport processes are similar between coral genera.