Zircon U-Pb-Hf constraints from Gongga Shan granites on young crustal melting in eastern Tibet

The Gongga Shan batholith is a complex granitoid batholith on the eastern margin of the Tibetan Plateau with a long history of magmatism spanning from the Triassic to the Pliocene. Late Miocene-Pliocene units are the youngest exposed crustal melts within the entire Asian plate of the Tibetan Plateau.Here, we present in-situ zircon Hf isotope constraints on their magmatic source, to aid the understanding of how these young melts were formed and how they were exhumed to the surface. Hf isotope signatures of Eocene to Pliocene zircon rims(ε_Hf(t)=-4 to +4), interpreted to have grown during localised crustal melting, are indicative of melting of a Neoproterozoic source region, equivalent to the nearby exposed Kangding Complex. Therefore, we suggest that Neoproterozoic crust underlies this region of the Songpan-Ganze terrane, and sourced the intrusive granites that form the Gongga Shan batholith. Localised young melting of Neoproterozoic lower or middle crust requires localised melt-fertile lithologies. We suggest that such melts may be equivalent to seismic and magnetotelluric low-velocity and high-conductivity zones or "bright spots" imaged across much of the Tibetan Plateau. The lack of widespread exposed melts this age is due either to the lack of melt-fertile rocks in the middle crust, the very low erosion level of the Tibetan plateau, or to a lack of mechanism for exhuming such melts. For Gongga Shan, where some melting is younger than nearby thermochronological ages of low temperature cooling, the exact process and timing of exhumation remains enigmatic, but their location away from the Xianshuihe fault precludes the fault acting as a conduit for the young melts. We suggest that underthrusting of dry granulites of the lower Indian crust(Archaean shield) this far northeast is a plausible mechanism to explain the uplift and exhumation of the eastern Tibetan Plateau.     

Bioassessment Techniques for Monitoring of Eutrophication and Nutrient Limitation in Coastal Ecosystems

Bioassesment by the use of the macroalga, Ulva lactuca L., was carried out in the Limfjord, Denmark, to assess the significance of nitrogen and phosphorus as limiting factors for primary production during 1985, 1993, 1994 and 1995 and for the detection of changes in eutrophication levels.

Minimum and critical tissue concentrations for nitrogen and phosphorus in macroalgae were identified. The concentrations of nitrogen were generally below the critical concentration level in June–October in 1985, 1993, and 1995 but in 1994 nitrogen was only limiting for primary production in short periods. Only in early spring in 1985 and 1993 were the tissue concentrations of phosphorus below the critical concentration level, whereas in 1994 up to 3–4 months showed phosphorus limited growth, indicating that significant changes in limitation patterns can occur between different years.

It was concluded that the use of biomonitoring techniques is well suited as a bioassessment method for direct detection and for providing a time-integrated measure of nutrient availability in coastal waters, and thus for assessing ecosystem health with regard to eutrophication. It is recommended that biomonitors and the concept of critical tissue concentrations should be used in environmental management and incorporated in future monitoring programmes.     

Seasonal variations in the vertical structure of pelagian water stratum in the Southern Baikal

For the first time, T,S-analysis was used to determine the specifics of seasonal variations in the vertical structure of Lake Baikal active layer. In the under-ice period, the active layer includes the under-ice, top winter, and upper intermediate water masses. The under-ice water mass, unlike other masses, shows an increase in mineralization to 100.74 mg/kg, which corresponds to a release of 71.1 g salt under 1 m² of water surface in a layer 0–40 m in the process of salt freezing out during ice cover formation and accretion. In the phases of mixing (homothermy), the water masses of the active layer transform into a surface homogeneous mass. In summer and autumn, surface and upper intermediate water masses, separated by a water mass of summer thermocline can be identified. A specific feature of the summer thermocline water mass is the increased sum of ions because of an increase in HCO ₃ ^- concentration at the decay of organic matter accumulating in the bottom part of the thermocline. The existence of the under-ice water mass and the water mass of summer thermocline was established in Lake Baikal for the first time. In the deep-water zone (>250 m), except for the bottom parts, the lower water masses (the lower intermediate and the deep) are permanent, their characteristics remaining stable during the year. The changes in the bottom water mass are due to the character of the processes of bottom water renewal.     

Finite Element Solvers for Biot’s Poroelasticity Equations in Porous Media

We study and compare five different combinations of finite element spaces for approximating the coupled flow and solid deformation system, so-called Biot’s equations. The permeability and porosity fields are heterogeneous and depend on solid displacement and fluid pressure. We provide detailed comparisons among the continuous Galerkin, discontinuous Galerkin, enriched Galerkin, and two types of mixed finite element methods. Several advantages and disadvantages for each of the above techniques are investigated by comparing local mass conservation properties, the accuracy of the flux approximation, number of degrees of freedom (DOF), and wall and CPU times. Three-field formulation methods with fluid velocity as an additional primary variable generally require a larger number of DOF, longer wall and CPU times, and a greater number of iterations in the linear solver in order to converge. The two-field formulation, a combination of continuous and enriched Galerkin function space, requires the fewest DOF among the methods that conserve local mass. Moreover, our results illustrate that three out of the five methods conserve local mass and produce similar flux approximations when conductivity alteration is included. These comparisons of the key performance indicators of different combinations of finite element methods can be utilized to choose the preferred method based on the required accuracy and the available computational resources.

     

Multi-scale permeability estimation for a tropical catchment

Physically based and spatially distributed modelling of catchment hydrology involves the estimation of block or whole-hillslope permeabilities. Invariably these estimates are derived by calibration against rainfall–runoff response. Rarely are these estimates rigorously compared with parameter measurements made at the small scale. This study uses a parametrically simple model, TOPMODEL, and an uncertainty framework to derive permeability at the catchment scale. The utility of expert knowledge of the internal catchment dynamics (i.e. extent of saturated area) in constraining parameter uncertainty is demonstrated. Model-derived estimates are then compared with core-based measurements of permeability appropriately up-scaled. The observed differences between the permeability estimates derived by the two methods might be attributed to the role of intermediate scale features (natural soil pipes). An alternative method of determining block permeabilities at the intermediate or hillslope scale is described. This method uses pulse-wave tests and explicitly incorporates the resultant effects of phenomena such as soil piping and kinematic wave migration. The study aims to highlight issues associated with parameterizing or validating distributed models, rather than to provide a definitive solution. The fact that the permeability distribution within the Borneo study catchment is comparatively simple, assists the comparisons. The field data were collected in terrain covered by equatorial rainforest. Combined field measurement and modelling programmes are rare within such environments. © 1998 John Wiley & Sons, Ltd.     

Vertical Distribution of Methane in Baikal Water

Water Resources - Data on the vertical distribution of dissolved methane in Baikal water column are analyzed. The zone of open lake now shows an increase in the concentrations of dissolved methane...     

Preserved organic matter in a fossil Ocean Continent Transition in the Alps: the example of Totalp,SE Switzerland

Evidence from ultraslow spreading mid-ocean ridges and both fossil and present-day Ocean–Continent Transitions (OCT) demonstrates that mantle serpentinization resulting from the interaction of mantle rock and water during tectonic exhumation is widespread. Observations at white smokers in modern ocean settings suggest that methane produced by serpentinization can support methanotrophic bio-systems, which use methane as the only source of carbon. An important question is whether such bio-systems are more generally pervasive in their association with serpentinized mantle in the subsurface. In this study, we examined whether there is evidence for such a methanotrophic system in exhumed serpentinized mantle at a magma-poor rifted continental margin, by probing for characteristic biological markers in these and associated sedimentary rocks in the Totalp unit of SE Switzerland. This unit represents a remnant of the former OCT of the southern Alpine Tethyan margin and was chosen because of its mild Alpine tectonic and low-grade metamorphic overprint during Alpine orogeny, hence giving potential for the preservation of indigenous organic matter (OM). Totalp samples are characterized by low organic carbon contents of 11–647 ppm. The majority of the samples contain hydrocarbons in the form of n-alkanes in the range C₁₇–C₃₆. Some sediments contain isoprenoids, for example pristane and phytane and a suite of steranes that are consistent with a marine origin for the OM preserved in the rocks. Traces of marine planktonic and bacterial OM are preserved in the serpentinized mantle and overlying sediments of this ancient Tethyan OCT, but there is no evidence that the OM has been generated from methanotrophic bio-systems.     

Application of the Ordered Weighted Averaging (OWA) method to the Caspian Sea conflict

This study proposes a promising allocation mechanism of the Caspian Sea natural resources, which are presently shared among five countries. To date, these nations have been unable to reach an allocation agreement. We apply a methodology to propose the most appropriate solution under different risk attitudes of the states. This research is different from other studies regarding the Caspian Sea negotiations in that it employs risk-based fuzzy multi attribute decision making methods for simulating the risk attitudes or optimism/pessimism degrees of the decision makers. The ordered weighted averaging (OWA) approach, which considers the optimism/pessimism degree quantitatively, is used to take into account the effects of different risk attitudes of the negotiators on the final outcome. We demonstrate how one could obtain a range of alternatives under different multi attribute and risk attitudes. The induced OWA (IOWA) method is also used to determine the relative power of these states bordering the Caspian Sea by considering several attributes, including different risk attitudes of agents. Results indicate that taking into account the risk attitude (prone, neutral, averse) of the states can affect the overall ranking of the proposed solutions. The findings from this study may facilitate negotiation regarding the most preferred allocation mechanism for the Caspian Sea.     

Alternative water management options to reduce vulnerability for climate change in the Netherlands

Urbanization, land subsidence and sea level rise will increase vulnerability of the urbanized low-lying areas in the western part of the Netherlands. In this article possibilities are explored to reduce vulnerability of these areas by implementing alternative water management options. Two main water management fields are distinguished, water supply and flood control. A four-component vulnerability framework is presented that includes threshold capacity, coping capacity, recovery capacity, and adaptive capacity. By using the vulnerability framework it is shown that current water supply and flood control strategies in the Netherlands focus on increasing threshold capacity by constructing higher and stronger dikes, improved water storage and delivery infrastructure. A complete vulnerability decreasing strategy requires measures that include all four capacities. Flood damage reduction, backup water supply systems and emergency plans are measures that can contribute to increasing coping capacity. Recovery capacity can be increased by multi-source water supply, insurance, or establishing disaster funds. Adaptive capacity can be developed by starting experiments with new modes of water supply and urbanization. Including all four components of the vulnerability framework enables better understanding of water and climate related vulnerability of urban areas and enables developing more complete water management strategies to reduce vulnerability.     

Estimation of methane fluxes from bottom sediments of Lake Baikal

Methane bubble fluxes in gas flares from bottom sediments in Lake Baikal were estimated for the first time using hydroacoustic methods. Earlier work has demonstrated the occurrence of gas seeps both inside and outside of areas where bottom simulating reflectors were identified in seismic profiles. Fluxes ranged from 14 to 216 tons per year, with the flux for the entire area of the central and southern basins ranging from 1,400 to 2,800 tons per year. Comparison with other water bodies showed that fluxes from the most intensive Baikal flares were similar to those in the Norwegian and Okhotsk seas. Gas hydrates decompose at the lower boundary of the gas hydrate stability zone due to sedimentation. Calculation of the amount of methane produced due to sedimentation gave a total of between 2,600 and 14,000 tons per year for the central and southern basins of the lake. Based on rough estimation, the total flux from shallow- and deep-water gas seeps is similar to the amount of methane produced due to sedimentation. This suggests that gas hydrates possibly occupy much more than 10?% of the pore volume near the base of the gas hydrate stability zone, or that there are other reasons for gas hydrate dissociation and bubble flux from these bottom sediments.