In Situ Remediation of Jet A in Soil and Ground Water by High Vacuum, Dual Phase Extraction

This report summarizes the initial results of subsurface remediation at Terminal 1, Kenneth International Airport, to remediate soil and ground water contaminated with Jet A fuel. The project was driven and constrained In the const ruction schedule of a major new terminal at the facility. The remediation system used a combination of ground water pumping, air injection, and soil vapor extraction. In the first five months of operation, the combined processes of dewatering, volatilization, and biodegradation removed a total of 36,689 pounds of total volatile and semivolatile organic jet fuel hydrocarbons from subsurface soil and ground water. The. results of this case study have shown that 62 percent of the removal resulted from biodegradation, 21 percent occurred as a result of liquid removal, and 11 percent resulted from the extraction of volatile organic compounds (VOC's).     

Surface organic geochemical prospecting for hydrocarbons: multivariate analysis

A database of analyses of C₁ and C₇ hydrocarbons from an oil and gas producing region in Mexico has been assembled from gas samples collected at depths of 3, 15 and 30 meters from surficial holes drilled in traverses over producing and barren structures. The surface consisted of subtropical swamps; depth to structure was 3500 to 5800 meters.Hydrocarbon analysis from six structures (three producing and three barren) selected from the database were subjected to multiple discriminant function analysis to produce a retrospective statistical test of the ability of geochemical prospecting to distinguish producing from non-producing structures. The hydrocarbon spectra from 3 meters depth yielded ambiguous results; those from 30 meters produced clear distinction between barren and producing structures. Further, the discriminant functions established a base of geochemical characteristics, founded on known areas (retrospective), to which additional unknown areas (prospective) may be compared for classification. This suggests a bootstrapping approach to exploration in which an increasing number of “known” results can be used to continually update and refine the predictive power of the discriminant function.This indicates the practical ability of a combined geochemical-multivariate statistical prospecting approach as an exploration tool, particularly within a single geochemical/geological province. Geochemical prospecting, perhaps with relatively deep (30 m) penetration, combined with multivariate data analysis is a rapid, potent and relatively inexpensive additional tool for petroleum exploration.     

Carbonate alteration of the Upper Mount McRae Shale beneath the martite-microplaty hematite ore deposit at Mount Whaleback, Western Australia

The formation of large martite-microplaty hematite ore deposits in northwest Australia remains a contentious topic in part because important evidence supporting a unifying genetic model has not been observed at all deposits. Carbonate replacement of silica has been found along normal faults below ore at the Mount Tom Price and Giles Mini deposits, which suggests an early hypogene process during ore formation. However, such rocks have not been identified at the largest martite-microplaty hematite deposit, Mount Whaleback. In this study, samples of the Mount McRae Shale are examined for their chemistry, mineralogy and petrography. These samples were collected from several key locations, including an area that immediately underlies ore along the Mount Whaleback fault at Mount Whaleback. Compared to unaltered black Mount McRae Shale from Wittenoom Gorge in the north and altered black and red Mount McRae Shale at Mount Whaleback, reddish-green Mount McRae Shale along the Mount Whaleback fault is greatly enriched in MgO and CaO and depleted in SiO₂. This chemistry arises from significant amounts of fine- to medium-grained ferroan-dolomite and ankerite and cross-cutting chlorite and carbonate veins. The composition is distinct from that produced during regional metamorphism, and most likely represents hydrothermal alteration after metamorphism. The lack of carbonate-rich, silica-poor rocks in the overlying Dales Gorge Member at Mount Whaleback is consistent with pervasive oxidation of most rocks in the region during or after ore genesis, a process that removed carbonates. Although several questions remain unanswered, these results support models that invoke an early hypogene stage during the formation of the martite-microplaty hematite deposits in the Hamersley Province.Editorial Handling: B. Lehmann     

Recovering the Neptune files

What exactly went on when Neptune was discovered? Nicholas Kollerstrom can shed new light on this story of scientific logic and heated claims of precedence – not to mention long-lost letters spirited away across continents.     

A detailed palaeointensity and inclination record from drill core SOH1 on Hawaii

A new record of absolute palaeointensity was obtained from drill core Scientific Observation Hole 1 (SOH1) on Kilauea volcano, Hawaii. Kilauea’s high eruption rate resulted in a relatively continuous record and stratigraphic constraints preserved the chronological order. Three hundred and sixty samples were studied with the Thellier-Thellier technique, which gave 195 successful palaeointensity and 271 successful inclination determinations. Three geomagnetic excursions were observed, which exhibited intensity reductions of about 50%. Initial age control from K-Ar and Ar/Ar dating only constrained the total age between 20 and 120 ka. The final age model was obtained by stretching the SOH1 record relative to other Hawaiian palaeomagnetic data. This gave an age range of 0-45 ka for the flows and identified the excursions as the Hilina Pali, Mono Lake and Laschamp events. The SOH1 record of the Hilina Pali event is the most detailed ever, incorporating data from around 40 flows. This age model suggests that Kilauea had a burst of activity at the SOH1 site around 20 ka. All available data was combined to form a composite record of palaeointensity and inclination on Hawaii for 0-45 ka.     

Simulation of braided river flow using a new cellular routing scheme

Results are presented from a numerical simulation of two-dimensional flow patterns in a braided river using a simple cellular routing scheme. The results of the routing scheme are compared with field measurements of discharge per unit width obtained within the study reach at low flow and, for higher flows, with the predictions of a more sophisticated hydraulic model that solves the two-dimensional shallow water form of the Navier–Stokes equations. An assessment is made of the sensitivity of the routing scheme to variations in the values of its main parameters, and appropriate values are determined based on the physical characteristics of the study site and available flow measurements. It is shown that despite the simple approach adopted by the cellular routing scheme to simulate processes of water redistribution, it is able to replicate accurately both the field data and the results of the more sophisticated hydraulic model. These results indicate that the routing scheme outlined here is able to overcome some of the limitations of previous simple cellular automata models and may be suitable for use in modelling bedload transport and channel change in complex fluvial environments. As such this research represents a small and ongoing contribution to the field of numerical simulation of braided river processes.     

Resistance to shallow landslide failure through root-derived cohesion in east coast hill country soils,North Island,New Zealand

Measured shear strength (cohesion and friction) of airfall-derived east coast hill country regolith is insufficient for the maintenance of existing regolith depth/slope angle relationships in the catchment of Lake Waikopiro in northern Hawke's Bay, New Zealand. If these regoliths are attributed with an additional increment of cohesion derived mechanically from a turf mat membrane, existing depth/slope angle distributions are explicable. Sites where failure has occurred have been measured, and back-analysis used to derive a range of values for additional mechanical cohesion. Values are in the range 0·2–7·6 kPa, consistent with earlier findings. This range is narrowed further, to 0·7–6·9 kPa, with assumptions regarding soil moisture status at failure. Copyright © 1999 John Wiley & Sons, Ltd.