1,4-蒽醌衍生物的合成

通过高酞酸酐与2-氯-5-甲基-1,4-苯醌反应,经过最长线性步骤6步和3步反应,分别以16%和47%的总产率合成了2个1,4-蒽醌衍生物12和14。其中,化合物14的合成为首次报道。所有合成的化合物均采用核磁共振波谱和质谱方法对其进行了表征和确证,并对高酞酸酐与苯醌反应生成1,4-蒽醌的反应机理进行了探讨。     

Study on the Stressed Mirror Polishing with a Continuous Polishing Machine for Large Aperture Off-axis Aspheric Mirrors

A special stressed annular polishing technique is proposed to mill the off-axis aspheric sub-mirrors of a large segmented mirror with an annular polishing machine. Based on the basic principle of stressed annular polishing technique, a set of special stressing mechanisms are designed to convert milling the aspheric surfaces of sub-mirrors with different off-axis distances into milling the spherical surfaces with identical radii of curvature, so that they can be pol- ished simultaneously on a continuous polishing machine. It took about contin- uous 40 hours to polish a scaled-down mirror of the planning Chinese Future Giant Telescope (CFGT) using this technique. This mirror has the 330 mm di- ameter, 3.6 m off-axis distance, and the 21.6 m radius of curvature, and its max- imum asphericity is 16 micron. The experiment shows that this method has a high effciency, suits batch manufacturing, especially the batch manufacturing of aspheric sub-mirrors of the segmented primary mirror of an extremely large aperture telescope.     

黄山东镁铁超镁铁杂岩中的辉石化学成分研究

通过对黄山东镁铁超镁铁杂岩的辉石化学成分研究，证明辉石的化学成分受寄主岩石类型的制约，从超镁铁岩相到角闪辉长岩相斜方辉石的化学成分由富ＭｇＯ、ＳｉＯ＿２、Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３到富ＦｅＯ、ＴｉＯ＿２、ＣａＯ、ＭｎＯ；单斜辉石化学成分由富Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３、Ｎａ＿２Ｏ、ＭｇＯ到富ＦｅＯ、ＭｎＯ、ＣｏＯ。在同一寄主岩石中，单斜辉石比斜方辉石富ＴｉＯ＿２、Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３、ＣａＯ和Ｎａ＿２Ｏ，贫ＭｇＯ、ＳｉＯ＿２、ＭｎＯ和ＦｅＯ。根据辉石化学成分特征得出黄山东杂岩形成于岛弧环境，为上地幔石榴二辉檄榄岩部分熔融形成的拉斑玄武岩岩浆结晶分异作用的产物。     

基于EOS/MODIS资料的沙尘遥感监测模型研究

在EOS MODIS资料可见光波段光谱特性的深入分析的基础上，提出了一种完全用MODIS可见光波段监测沙尘信息的技术方法。充分利用MODIS资料可见光范围波段划分细致的特点，构造了不同的光谱特征判别函数作为决策树的分支，最后用决策树法成功地对几次沙尘暴过程进行了沙尘信息遥感监测。结果表明，该方法具有良好的效果和实用性。     

海洋来源羽毛降解菌株的筛选、鉴定及酶学性质研究

微生物降解羽毛既可保护环境又能实现废物的资源化利用,具有显著的经济效益和社会效益。本研究从广西钦州港海鸭养殖淤泥筛选获得一株可高效降解羽毛的菌株Gxun-20,通过对该菌株形态特征、生理生化特性和16S rRNA基因序列进行分析,以确定菌株的分类,并对菌株产角蛋白酶的条件及酶学性质进行研究。结果表明：该菌为副短短芽孢杆菌(Brevibacillus parabrevis);菌株最适产酶条件为：温度34℃,初始pH 6.5,羽毛含量1.5%(质量分数),发酵48 h,角蛋白酶活性可达277.45 U/mL。菌株Gxun-20所分泌的角蛋白酶最适温度为50℃,且热稳定性较好,最适pH为7.5;金属离子Fe³⁺、Cu²⁺、Co²⁺、Fe²⁺和Mn²⁺对酶活性有显著抑制作用,而Ca²⁺、Na⁺对酶活性有明显促进作用;金属螯合剂乙二胺四乙酸(ethylene diamine tetraacetic acid, EDTA)可显著抑制酶的活性,蛋白...     

两次强降水过程雨滴谱特征及差异

利用寿县观测站内的Parsivel激光雨滴谱仪结合观测站雨量数据及雷达基数据,分析了发生在2015年6月26—30日梅雨期间和2015年8月7—10日超强台风"苏迪罗"影响期间2次强降水过程的雨滴谱结构特征及其差异,拟合了雨强与雷达反射率因子之间的关系。结果表明:雨强的大小直接影响雨滴谱的特征参量,且随着雨强增大而增大;梅雨锋暴雨中1.0mm直径≤1.5mm的粒子所占比例最多,雨强贡献率最大;台风雨中0.75mm直径≤1.0mm的粒子所占比例最多,但1.0mm直径≤1.25mm的粒子对雨强的贡献最大,说明较大粒子对强降水的贡献较大。     

Numerical investigation of the uplift performance of prestressed fiber-reinforced polymer floating piles

Finite element analyses of prestressed fiber-reinforced polymer floating piles subjected to uplift force have been conducted in this paper. First, parameters of the modified BPE model (bond–slip model at the fiber-reinforced polymer–concrete interface) were calibrated using existing pullout testing data on fiber-reinforced polymer rebars embedded in concrete. Nonlinear spring elements were used in numerical modeling to characterize the bond–slip behavior at the fiber-reinforced polymer–concrete interface. A parametric study was performed to assess the influence of rebar diameter, fiber-reinforced polymer material, embedment length, and concrete strength on the mobilized bond stress. Upon the successful modeling of the pullout performance of fiber-reinforced polymer rebars in concrete, numerical models were developed to investigate the dependence of the uplift performance of floating piles on the prestress level, uplift force, fiber-reinforced polymer type, and compressive strength of concrete.     

G856磁力仪在地磁台站建设中的应用与实践方法

本文通过泉州地磁台重建工程中的工作实践,阐述了应用G856磁力仪在建筑材料磁性检测、施工过程中磁性跟踪监测的实践方法。     

中国地幔岩包体的研究现状及今后研究对策探讨

在系统回顾地幔岩包体的研究简史及研究现状的基础上,对我国地幔岩包体今后的研究对策进行了探讨。认为我国地幔岩包体今后的研究工作应重视地幔岩包体形成演化过程中压力（ｐ）、温度（Ｔ）、环境（Ｅ）和时代（ｔ）的综合制约作用,定量模拟地幔岩包体的形成过程,最终建立地幔岩包体形成演化的ｐＴＥｔ模式。     

DIAGNOSTIC STUDY FOR INTRASEASONAL OSCILLATION OF THE MIDDLE-HIGH LATITUDES IN A LOW RESOLUTION GLOBAL SPECTRAL MODEL

In this paper, five-year simulated data from a low-resolution global spectral model with triangular trunca-lion at wavenumber 10 are analyzed in order to study dynamical features and propagation characteristics ofintraseasonal oxillations over the mid-latitudes and the tropical atmosphere. The simulations show that thereis the 30-50 day periodic oscillation in the low-resolution spectral model without non-seasonal external forcing,and spatial scale of the intraseasonal oscihations is of the globe .Further analysis finds that propagation charac-ters of intraseasonal oscillations over the mid-latitudes and the tropics are different. The 30-50 day oscillationover the tropics exhibits structure of the velocity potential wave with wavenumber 1 in the latitudinal and thecharacter of the traveling wave eastward at speed of 8 longitudes/day. However, the 30-50 day oscillationsin mid-latitude atmosphere exhibit phase and amplitude oscillation of the standing planetary waves and theyare related to transform of teleconnection patterns over the mid-latitudes. The energy is not only transferredbetween the tropics and the middle-high latitudes, but also between different regions over the tropics. Based on the analysis of 5-year band pass filtered data from a 5-layer global spectral model of Jow-ordetwith truncated wavenumber l0,investigation is done of the source of intraseasonal oscillations in the extratropicalmodel atmosphere and its mechanism. Results show that (1) the convective heat transferred eastward alongthe equator serves as the source of the intraseasonal oxillation both in the tropical and the extratropical atmos--phere; (2) the velocity-potential wave of a zonal structure of wavenumber 1 gives rise to oxillation in divergentand convergent wind fields of a dipole-form as seen from the equatorial Indian Ocean to the western Pacificduring its eastward propagation, thus indicating the oscillation in the dipole-form heat soure:e/sink pattertl; (3)the tropical heat-source oscillation is responsible for the variation in phase and intensity of the extratropicalstationary wave train, and the interaction between the oscillating low-frequency inertial gravity and stationaryRossby modes that are probably mechanisms for the oscillations ip the middle-high latitudes.