Sulfur as a binding agent of aggregates in explosive eruptions

The 2013 eruption of Pavlof Volcano, Alaska began on 13 May and ended 49 days later on 1 July. The eruption was characterized by persistent lava fountaining from a vent just north of the summit, intermittent strombolian explosions, and ash, gas, and aerosol plumes that reached as high as 8 km above sea level and on several occasions extended as much as 500 km downwind of the volcano. During the first several days of the eruption, accumulations of spatter near the vent periodically collapsed to form small pyroclastic avalanches that eroded and melted snow and ice to form lahars on the lower north flank of the volcano. Continued lava fountaining led to the production of clastogenic lava flows that extended to the base of the volcano, about 3–4 km beyond the vent. The generation of fountain-fed lava flows was a dominant process during the 2013 eruption; however, episodic collapse of spatter accumulations and formation of hot spatter-rich granular avalanches was a more efficient process for melting snow and ice and initiating lahars. The lahars and ash plumes generated during the eruption did not pose any serious hazards for the area. However, numerous local airline flights were cancelled or rerouted, and trace amounts of ash fall occurred at all of the local communities surrounding the volcano, including Cold Bay, Nelson Lagoon, Sand Point, and King Cove.     

An XMM-Newton proton response matrix

Soft protons constitute an important source of background in focusing X-ray telescopes, as Chandra and XMM-Newton experience has shown. The optics in fact transmit them to the focal plane with efficiency similar to the X-ray photon one. This effect is a good opportunity to study the environment of the Earth magnetosphere crossed by the X-ray satellite orbits, provided that we can link the spectra detected by the instruments with the ones impacting on the optics. For X-ray photons this link has the form of the so-called response matrix that includes the optics effective area and the energy redistribution in the detectors. Here we present a first attempt to produce a proton response matrix exploiting ray-tracing and GEANT4 simulations with the final aim to be able to analyse XMM-Newton soft proton data and link them to the external environment. If the procedure is found to be reliable, it can be applied to any future X-ray missions to predict the soft particles spectra impacting on the focal plane instruments.     

Probing the Earth’s Interior with the LENA Detector

A future large-volume liquid scintillator detector such as the proposed 50 kton LENA (Low Energy Neutrino Astronomy) detector would provide a high-statistics measurement of terrestrial antineutrinos originating from β-decays of the uranium and thorium chains. Additionally, the neutron is scattered in the forward direction in the detection reaction . Henceforth, we investigate to what extent LENA can distinguish between certain geophysical models on the basis of the angular dependence of the geoneutrino flux. Our analysis is based on a Monte-Carlo simulation with different levels of light yield, considering an unloaded PXE scintillator. We find that LENA is able to detect deviations from isotropy of the geoneutrino flux with high significance. However, if only the directional information is used, the time required to distinguish between different geophysical models is of the order of severals decades. Nonetheless, a high-statistics measurement of the total geoneutrino flux and its spectrum still provides an extremely useful glance at the Earth’s interior.     

The Wild Life of Pesticides: urban agriculture,institutional responsibility,and the future of biodiversity in Sydney's Hawkesbury-Nepean River

Agricultural chemicals are a notoriously intractable source of environmental pollution. Offering enhanced agricultural productivity, they simultaneously risk degrading the ecological basis upon which agriculture depends. This paper considers chemicalisation as a cause of the erosion of aquatic biodiversity and ecosystem resilience, focusing on the Hawkesbury-Nepean River and the small-scale horticulturalists who supply the city's fresh vegetable markets, working under the pressure of urbanisation, retail monopolies, indifferent land-use planning, and often without access to information about pesticide use in the languages they understand. Arguing that standard practices of ‘risk management’ are unable to adequately control chemical contamination, the paper presents findings from interviews with actors within the ‘assemblage’ of institutions with responsibility for agriculture, water quality, and environmental protection, in order to assess the effectiveness of pesticide governance in the Greater Sydney Basin. It appears that pesticide pollution is far from being tamed: it is rarely measured nor monitored, neither is it a priority of any particular agency. Arguing that public health, the long-term viability of local farming and the ecological well-being of the Hawkesbury-Nepean River are mutually consistent goals, we conclude that these vital elements of the common-weal are currently subject to a system of ‘organised irresponsibility’. The paper concludes by proposing several ways forward.     

Mass segregation in young clusters: observational biases

We investigate the validity of the mass-segregation indicators most commonly used in the analysis of young stellar clusters. We construct and analyze synthetic massive clusters with a standard, fully sampled stellar initial mass function and a King density distribution function. We find that the commonly used indicators are highly sensitive to the effects of incompleteness in observational data, and that completeness determinations do not provide satisfactory corrections, leading to results that may be severely biased toward mass segregation.     

Uranium-rich accessory minerals in the peraluminous and perphosphorous Belvís de Monroy pluton (Iberian Variscan belt)

The strongly peraluminous, perphosphorous (<0.85 wt% P₂O₅) and low-Ca granites from the Belvís de Monroy pluton contain the most U-rich monazite-(Ce) and xenotime known in igneous rocks. Along with these accessory minerals, P-rich zircon occurs, reaching uncommon compositions particularly in the more fractionated units of this zoned pluton. Monazite displays a wide compositional variation of UO₂ (<23.13 wt%) and ThO₂ (<19.58 wt%), positively correlated with Ca, Si, P, Y and REE. Xenotime shows a high UO₂ content (2.37–13.34 wt%) with parallel increases of LREE, Ca and Si. Zircon contains comparatively much lower UO₂ (<1.53 wt%) but high P₂O₅ (<14.91 wt%), Al₂O₃ (<6.96 wt%), FeO (<2.93 wt%) and CaO (<2.24 wt%) contents. The main mechanism of incorporating large U and Th amounts in studied monazite and U in xenotime is the cheralite-type [(Th,U)⁴⁺ + Ca²⁺ = 2(Y,REE)³⁺] substitution. Zircon requires several coupled mechanisms to charge balance the P substitution, resulting in non-stoichiometric compositions with low analytical totals. Compositional variations in the studied accessory phases indicate that the substitution mechanisms during crystal growth depend on the availability of non-formula elements. The strong P-rich character of the studied granites increases monazite crystallization, triggering a progressive impoverishment in Th and LREE in the residual melts, and consequently increasing extraordinarily the U content in monazite and xenotime. This is in marked contrast to other peraluminous (I-type or P-poor S-type) granite series. The P-rich and low-Ca peraluminous melt inhibits uraninite crystallization, so contributing to the U availability for monazite and xenotime.     

Assessing the performance of a foraminifera-based transfer function to estimate sea-level changes in northern Portugal

We assessed the performance of a transfer function model for sea-level studies using salt-marsh foraminifera from two estuaries of northern Portugal. An independent data set of 12 samples and 13 sub-fossil samples from a core were used to evaluate if reconstructions and errors derived from current models are adequate. Initial transfer function models provided very strong results as indicated by cross-validation (component 2; r² = 0.80-0.82; RMSEP ranged from 10.7 to 12.3 cm) and improved its performance by ca. 10% when sample size reached ca. 50. Results derived using an independent test data set indicate that cross-validation is a very effective approach and produces conservative errors when compared to observed errors. We additionally explored the possible effect of transforming the concentration data into percent in the error estimations by comparing the results obtained based on the use of both concentration and compositional data. Results indicate that this type of transformation does not affect the performance of the transfer function. Results derived from a reconstruction of sub-fossil samples from a core indicate that high-resolution sea-level reconstructions are possible, but show that depositional environments have to be selected carefully in order to minimize the impact of possible taphonomical loss.     

Cadomian volcanosedimentary complexes across the Ediacaran–Cambrian transition of the Eastern Pyrenees,southwestern Europe

International Journal of Earth Sciences - The volcanism hosted by the Ediacaran–Terreneuvian Canaveilles Group of the Eastern Pyrenees displays two distinct geochemical affinities: (1)...     

Provenance of Neoproterozoic and early Paleozoic siliciclastic rocks of the Teplá-Barrandian unit (Bohemian Massif): Evidence from U–Pb detrital zircon ages

New LA-ICP-MS U–Pb detrital zircon ages from Ediacaran and Paleozoic siliciclastic rocks are used to constrain provenance and paleogeographic affinities of the Teplá-Barrandian unit (TBU) in the centre of the Bohemian Massif (Central Europe, Czech Republic). The samples taken span the period from ≤ 635 Ma to ～ 385 Ma and permit recognition of provenance changes that reflect changes in geotectonic regime. Detrital zircon age spectra of two Ediacaran, one Lower Cambrian and three Upper Ordovician samples resemble the ages known from the NW African proportion of Gondwana, particularly the Trans-Saharan belt, while three rocks from higher Lower Cambrian to Lowermost Ordovician strata contain detritus that may have been derived exclusively from local sources. The age spectrum of the Devonian rock is a combination of the NW Gondwanan and local features. These new findings in combination with a wide range of published data are in agreement with a Neoproterozoic subduction-related setting at the margin of Gondwana followed by a Cambrian/Early Ordovician rifting stage and an Ordovician passive margin setting. Furthermore the data are in favour of a position of the TBU at the Gondwanan margin throughout pre-Variscan times.     

Reply to discussion on “Guidelines on the use of inverse velocity method as a tool for setting alarm thresholds and forecasting landslides and structure collapses” by F. Bozzano,P. Mazzanti,and S. Moretto

■■■The paper “Discussion to: Guidelines on the use of inverse velocity method as a tool for setting alarm thresholds and forecasting landslides and structure collapses by T. Carlà, E. Intrieri, F. Di Traglia, T. Nolesini, G. Gigli and N. Casagli” by Bozzano et al. brings forward new considerations on an issue of extreme concern in landslide risk management. To this day, the ability to predict catastrophic landslide failures from slope surface displacements is a problem dictated more by practical constraints rather than by theoretical uncertainties. In this sense, the development of data interpretation practices is crucial. This short reply provides a few further insights with regard to this subject, also in the context of the recently published literature.